Non-aqueous electrolyte secondary battery and method for producing the same
View Patent ↗Disclosed is a non-aqueous electrolyte secondary battery including a positive electrode including a lithium-containing transition metal composite oxide as a positive electrode active material, a negative electrode including a negative electrode active material, a separator interposed between the positive electrode and the negative electrode, and a non-aqueous electrolyte. The positive electrode contains lithium carbonate and lithium hydrogencarbonate in a total amount of 500 ppm or more and 3000 ppm or less, and exhibits a weight loss by temperature increase from 25° C. to 300° C. at 5° C./min of 70% or less of the total amount and of 1500 ppm or less. The non-aqueous electrolyte includes a non-aqueous solvent and a lithium salt. The non-aqueous solvent may contain a cyclic carbonate and a chain carbonate.
1. A non-aqueous electrolyte secondary battery comprising: a positive electrode including a lithium-containing transition metal composite oxide as a positive electrode active material, a negative electrode including a negative electrode active material, a separator interposed between the positive electrode and the negative electrode, and a non-aqueous electrolyte, wherein
the positive electrode contains lithium carbonate and lithium hydrogencarbonate in a total amount of 500 ppm or more and 3000 ppm or less, and exhibits a weight loss by temperature increase from 25° C. to 300° C. at 5° C./min of 70% or less of the total amount and of 1500 ppm or less.
2. The non-aqueous electrolyte secondary battery according to claim 1 , wherein the total amount of lithium carbonate and lithium hydrogencarbonate in the positive electrode is 1000 ppm or more and 2600 ppm or less, and the weight loss is 300 ppm or more and 1500 ppm or less.
3. The non-aqueous electrolyte secondary battery according to claim 1 , wherein the lithium-containing transition metal composite oxide is represented by the formula (1):
Li x Ni y M 1-y O 2 (1)
where M is at least one element selected from the group consisting of Co, Mn, Cr, Fe, Mg, Ti, and Al; 0.95≦x≦1.1; and 0.3≦y≦1.
4. The non-aqueous electrolyte secondary battery according to claim 3 , wherein in the formula (1), M at least contains Co and at least one selected from the group consisting of Mn and Al.
5. The non-aqueous electrolyte secondary battery according to claim 1 , wherein
the non-aqueous electrolyte includes a non-aqueous solvent and a lithium salt,
the non-aqueous solvent contains a cyclic carbonate and a chain carbonate,
the cyclic carbonate is at least one alkylene carbonate selected from the group consisting of ethylene carbonate, propylene carbonate, and butylene carbonate.
6. The non-aqueous electrolyte secondary battery according to claim 5 , wherein the chain carbonate is at least one dialkyl carbonate selected from the group consisting of dimethyl carbonate, diethyl carbonate, ethyl methyl carbonate, din-propyl carbonate, methyl n-propyl carbonate, ethyl n-propyl carbonate, methyl i-propyl carbonate, and ethyl i-propyl carbonate.
7. The non-aqueous electrolyte secondary battery according to claim 6 , wherein the chain carbonate contains diethyl carbonate and ethyl methyl carbonate in a volume ratio of 25:75 to 75:25.
8. The non-aqueous electrolyte secondary battery according to claim 5 , wherein the non-aqueous electrolyte further contains as an additive, at least one selected from the group consisting of a sulfur compound, and a carbonic acid ester different from the cyclic carbonate and the chain carbonate.
9. The non-aqueous electrolyte secondary battery according to claim 8 , wherein the carbonic acid ester is at least one selected from the group consisting of an unsaturated cyclic carbonate, an alkylene carbonate having a substituent, an aromatic ring-condensed cyclic carbonate, a diaryl carbonate, and a dialkyl dicarbonate.
10. The non-aqueous electrolyte secondary battery according to claim 8 , wherein the sulfur compound is at least one selected from the group consisting of sulfite, trithiocarbonate, sulfolane, sulfolene, sultone, and substituted products thereof.