Bicomponent reactive ink for ink jet printing
View Patent ↗The present invention relates to (i) a reactive ink for ink jet printing comprising a two-component system, the first component comprising a polymerizable monomer, and the second component comprising a polymerization catalyst, wherein the monomer is able to form a polymeric film at low temperature within thirty minutes, preferably within ten minutes, from contacting the catalyst, (ii) a process of making an image on a non-porous substrate using such a reactive ink, and an ink jet print head including a two component ink-system.
1. A reactive ink for ink jet printing comprising:
an organic solvent as a carrier medium; and
a two-component system,
the first component comprising a polymerizable monomer selected from the group consisting of aliphatic epoxy monomers, alicyclic epoxy monomers, aromatic epoxy monomers, and mixtures thereof, and
the second component comprising a polymerization catalyst selected from the group consisting of Lewis and Bronsted acids having a pKa equal to or lower than 4,
wherein the polymerizable monomer is able to form a polymeric film at a temperature equal to or lower than 60° C. within thirty minutes from contacting the catalyst.
2. The reactive ink for ink jet printing according to claim 1 , wherein said polymerizable monomer is able to form a polymeric film at a temperature equal to or lower than 60° C. within ten minutes from contacting the catalyst.
3. The reactive ink for ink jet printing according to claim 1 , wherein said polymerizable monomer is able to form a polymeric film at a temperature equal to or lower than 60° C. within one minute from contacting the catalyst.
4. The reactive ink for ink jet printing according to claim 1 , wherein said polymerizable monomer is able to form a polymeric film at a temperature equal to or lower than 40° C.
5. The reactive ink for ink jet printing according to claim 1 , wherein said polymerizable monomer is able to form a polymeric film at a temperature ranging from 10° to 30° C.
6. The reactive ink for ink jet printing according to claim 1 , wherein said polymerization catalyst is a compound able to promote the acid (cationic) polymerization of the said polymerizable monomer.
7. The reactive ink for ink jet printing according to claim 1 , wherein said polymerization catalyst is selected from the group consisting of mineral acids, organic sulfonic acids, superacids, and mixtures thereof.
8. The reactive ink for ink jet printing according to claim 1 , wherein said first component and said second component are mixed, upon printing, in an amount so as to provide a weight ratio between said polymerizable monomer and said polymerization catalyst ranging from 1:1 to 1:5.
9. The reactive ink for ink jet printing according to claim 8 , wherein said weight ratio ranges from 1:1 to 1:3.
10. The reactive ink for ink jet printing according to claim 1 , wherein said first component and said second component further comprises at least one component selected from the group consisting of colorants, surfactants, defoamers, sequestering agents, and biocides.
11. A process of making an image on a non-porous substrate, the process comprising:
jetting a reactive ink composition onto said non-porous substrate,
wherein said reactive ink composition comprises
an organic solvent as a carrier medium,
a first component comprising a polymerizable monomer selected from the group consisting of aliphatic epoxy monomers, alicyclic epoxy monomers, aromatic epoxy monomers, and mixtures thereof, and
a second component comprising a polymerization catalyst selected from the group consisting of Lewis and Bronsted acids having a pKa equal to or lower than 4,
wherein the polymerizable monomer is able to form a polymeric film at a temperature equal to or lower than 60° C. within thirty minutes from contacting the catalyst.
12. The process according to claim 11 , wherein said first component is jetted separately from said second component.
13. The process according to claim 12 , wherein said first component is jetted simultaneously with said second component.
14. The process according to claim 12 , wherein said first component is jetted after the jetting of said second component.
15. The process according to claim 12 , wherein said first component is jetted before the jetting of said second component.
16. The process according to claim 11 , wherein said polymerizable monomer is able to form a polymeric film at a temperature equal to or lower than 60° C. within ten minutes from contacting the catalyst.
17. The process according to claim 11 , wherein said polymerization catalyst is a compound able to promote the acid (cationic) polymerization of the said polymerizable monomer.
18. An ink jet print head including a two component ink-system, comprising:
a first tank including a first ink component comprising an organic solvent as a carrier medium and a polymerizable monomer selected from the group consisting of aliphatic epoxy monomers, alicyclic epoxy monomers, aromatic epoxy monomers, and mixtures thereof,
a second tank including a second ink component comprising the organic solvent as the carrier medium and a polymerization catalyst selected from the group consisting of Lewis and Bronsted acids having a pKa equal to or lower than 4, and
separate ejection systems for the first and second ink components, wherein the polymerizable monomer is able to form a polymeric film at a temperature equal to or lower than 60° C. within thirty minutes from contacting the catalyst.
19. The reactive ink for ink jet printing according to claim 1 , wherein said first component and said second component are mixed, upon printing, in an amount so as to provide a weight ratio between said polymerizable monomer and said polymerization catalyst ranging from 1:1 to 1:10.