Silicon-aluminum mixed oxide powder
View Patent ↗Silicon-aluminum mixed oxide powder having a weight ratio of (Al 2 O 3 /SiO 2 ) ttl in the total primary particle of from 0.003 to 0.05, a weight ratio (Al 2 O 3 /SiO 2 ) surface of the primary particles in a surface layer having a thickness of about 5 nm which is less than in the total primary particle and a BET surface area of from 50 to 250 m 2 /g. It is prepared by igniting one or more silicon compounds selected from the group consisting of CH 3 SiCl 3 , (CH 3 ) 2 SiCl 2 , (CH 3 ) 3 SiCl and (n-C 3 H 7 )SiCl 3 , a hydrolysable and oxidizable aluminum compound, at least one fuel gas and air and burning the flame into a reaction chamber, subsequently separating the solid from gaseous materials and subsequently treating the solid with water vapor. The silicon-aluminum mixed oxide powder can be used as catalyst.
1. A silicon-aluminum mixed oxide powder, wherein:
the silicon-aluminum mixed oxide powder includes aggregated primary particles,
a weight ratio (Al 2 O 3 /SiO 2 ) ttl in total primary particles is from 0.003 to 0.05,
a weight ratio (Al 2 O 3 /SiO 2 ) surface of primary particles in a surface layer having a thickness of about 5 nm is less than the weight ratio (Al 2 O 3 /SiO 2 ) ttl in the total primary particles, and
a BET surface area is from 50 to 250 m 2 /g.
2. The silicon-aluminum mixed oxide powder of claim 1 ,
wherein
(Al 2 O 3 /SiO 2 ) ttl /(Al 2 O 3 /SiO 2 ) surface is from 1.3 to 20.
3. The silicon-aluminum mixed oxide powder of claim 2 , wherein
a dibutyl phthalate number, measured in g of dibutyl phthalate per 100 g of the silicon-aluminum mixed oxide powder, is from 300 to 350.
4. The silicon-aluminum mixed oxide powder of claim 1 , wherein
a dibutyl phthalate number, measured in g of dibutyl phthalate per 100 g of the silicon-aluminum mixed oxide powder, is from 300 to 350.
5. A process for preparing the silicon-aluminum mixed oxide powder of claim 1 ,
the process comprising:
(i) introducing, either separately or together, via a carrier gas into a mixing chamber, a vapor comprising one or more silicon compounds selected from the group consisting of CH 3 SiCl 3 , (CH 3 ) 2 SiCl 2 , (CH 3 ) 3 SiCl and (n-C 3 H 7 )SiCl 3 , and a vapor comprising a hydrolysable, oxidizable, or both hydrolysable and oxidizable aluminum compound wherein a weight ratio of the aluminum compound, calculated as Al 2 O 3 , to the silicon compounds, calculated as SiO 2 , is from 0.003 to 0.05,
(ii) introducing, separately, at least one fuel gas and air into the mixing chamber, wherein a total amount of oxygen in the air is at least sufficient for complete combustion of the at least one fuel gas, the silicon compounds and the aluminum compound,
(iii) igniting a mixture of the vapor comprising the silicon compounds, the vapor comprising the aluminum compound, the at least one fuel gas, and the air in a burner to obtain a flame, and burning the flame into a reaction chamber, and
(iv) subsequently separating solid from gaseous materials, and subsequently treating the solid with water vapor, thereby obtaining the silicon-aluminum mixed oxide powder.
6. The process of claim 5 ,
wherein
the vapor comprising the silicon compounds comprises up to 40% by weight of SiCl 4 .
7. A catalyst, comprising the silicon-aluminum mixed oxide powder of claim 1 .