Liquid crystal blue phase
View Patent ↗Methods of forming a liquid crystal blue phase from composite materials having a chiral nematic liquid crystal host and a bent-shape molecule are described. The stable temperature range of the liquid crystal blue phase may be improved by controlling the thickness of the composite materials. For example, a given composition may have a maximum stable temperature range for the liquid crystal blue phase at about 1 μm.
1. A composite material comprising:
a chiral nematic liquid crystal host;
at least one bent-shape compound of formula (I):
wherein R 1 and R 2 are each independently selected from halogens and aliphatic hydrocarbons comprising 1 to 15 carbons;
Ar 1 , Ar 2 , Ar 3 , Ar 4 , and Ar 5 , are each independently selected from optionally substituted homocyclic, heterocyclic, and polycyclic aromatics;
X 1 and X 2 are each independently selected from CH 2 , O, NH, and S;
Y 1 and Y 2 are each independently selected from C═O, C═CH 2 , C═NH, and C═S; and
wherein the composite material has a thickness of about 0.25 μm to about 10 μm and wherein the composite material has a liquid crystal blue phase.
2. The composite material of claim 1 , wherein the composite material has a thickness of about 1 μm.
3. The composite material of claim 1 , wherein the liquid crystal blue phase of the composite material has a stable temperature range of at least about 10° C.
4. The composite material of claim 1 , wherein X 1 and X 2 are each O, and wherein Y 1 and Y 2 are each C═O.
5. The composite material of claim 1 , wherein Ar 3 is a five-membered aromatic heterocycle.
6. The composite material of claim 1 , wherein Ar 1 , Ar 2 , Ar 4 , and Ar 5 , are each independently selected from six-membered aromatic heterocycles and homocycles.
7. The composite material of claim 1 , wherein the bent-shape compound has the structure of formula (II):
wherein R 3 and R 4 are each independently selected from halogens and aliphatic hydrocarbons comprising 1 to 15 carbons.
8. The composite material of claim 7 , wherein R 3 is C 7 H 15 and R 4 is F.
9. The composite material of claim 1 , wherein the bent-shape compound is present at about 5 weight percent to about 20 weight percent.
10. The composite material of claim 1 , wherein the chiral nematic liquid crystal host comprises about 60 weight percent to about 70 weight percent eutectic nematic liquid crystals and about 30 weight percent to about 40 weight percent chiral dopant.
11. A method of preparing a liquid crystal blue phase, the method comprising:
providing a thin-film comprising a mixture of a chiral nematic liquid crystal host and at least one bent-shape compound;
heating the thin-film; and
cooling the heated thin-film, wherein the thin-film has a thickness of about 0.25 μm to 10 μm to produce a liquid crystal blue phase.
12. The method of claim 11 , wherein heating the thin-film comprises heating the thin-film having a thickness of about 1 μm.
13. The method of claim 11 , wherein cooling the heated thin-film comprises cooling the heated thin-film to produce the liquid crystal blue phase, wherein the liquid crystal blue phase has a stable temperature range of at least about 10° C.
14. The method of claim 11 , wherein providing the thin-film comprises providing the thin-film comprising the mixture of the chiral nematic liquid crystal host and at least one bent-shape compound having the structure of formula (I):
wherein R 1 and R 2 are each independently selected from halogens and aliphatic hydrocarbons comprising 1 to 15 carbons;
Ar 1 , Ar 2 , Ar 3 , Ar 4 , and Ar 5 , are each independently selected from optionally substituted homocyclic, heterocyclic, and polycyclic aromatics;
X 1 and X 2 are each independently selected from CH 2 , O, NH, and S; and
Y 1 and Y 2 are each independently selected from C═O, C═CH 2 , C═NH, and C═S.
15. The method of claim 14 , wherein providing the thin-film comprises providing the thin-film comprising the mixture of the chiral nematic liquid crystal host and at least one bent-shape compound having the structure of formula (I), wherein Ar 3 is a five-membered aromatic heterocycle.
16. The method of claim 14 , wherein providing the thin-film comprises providing the thin-film comprising the mixture of the chiral nematic liquid crystal host and at least one bent-shape compound having the structure of formula (I), wherein Ar 1 , Ar 2 , Ar 4 , and Ar 5 , are each independently selected from six-membered aromatic heterocycles and homocycles.
17. The method of claim 11 , wherein providing the thin-film comprises providing the thin-film comprising the mixture of the chiral nematic liquid crystal host and at least one bent-shape compound having the structure of formula (II):
wherein R 3 and R 4 are each independently selected from halogens and aliphatic hydrocarbons comprising 1 to 15 carbons.
18. The method of claim 17 , wherein providing the thin-film comprises providing the thin-film comprising the mixture of the chiral nematic liquid crystal host and at least one bent-shape compound having the structure of formula (II), wherein R 3 is C 7 H 15 and R 4 is F.
19. The method of claim 11 , wherein heating the thin-film comprises heating to a temperature above a clearing point of the thin-film; and cooling the heated thin-film comprises cooling at about 1° C. per minute.
20. A display device comprising a composite material, wherein the composite material comprises:
a chiral nematic liquid crystal host;
at least one bent-shape compound of formula (I):
wherein R 1 and R 2 are each independently selected from halogens and aliphatic hydrocarbons comprising 1 to 15 carbons;
Ar 1 , Ar 2 , Ar 3 , Ar 4 and Ar 5 , are each independently selected from optionally substituted homocyclic, heterocyclic, and polycyclic aromatics;
X 1 and X 2 are each independently selected from CH 2 , O, NH, and S;
Y 1 and Y 2 are each independently selected from C═O, C═CH 2 , C═NH, and C═S; and
wherein the composite material is configured as a thin-film having a thickness of about 0.25 μm to about 10 μm, and wherein a liquid crystal blue phase of the composite material has a stable temperature range of at least about 5° C.
21. The composite material of claim 1 , wherein the composite material has a thickness of about 0.5 μm to about 2 μm.
22. The method of claim 11 , wherein providing the thin-film comprises providing the thin-film comprising the mixture of the chiral nematic liquid crystal host and at least one bent-shape compound, wherein the thin-film has a thickness of about 0.5 μm to about 2 μm.
23. The display device of claim 20 , wherein the thin-film has a thickness of about 0.5 μm to about 2 μm.