Organic electroluminescence display panel with tungsten oxide containing hole injection layer that electrically connects electrode to auxiliary wiring, and organic electroluminescence display device
View Patent ↗A hole injection layer and a second electrode are both formed to be continuous above a first electrode and above an auxiliary wiring. The hole injection layer contains a tungsten oxide. An UPS spectrum, obtained from a UPS measurement, has a protrusion appearing near a Fermi surface and within a region corresponding to a binding energy range lower than a top of a valence band, and the tungsten oxide satisfies a condition, determined from an XPS measurement, that a ratio in a number density of atoms other than tungsten atoms and oxygen atoms to the tungsten atoms does not exceed 0.83.
1. An organic EL display panel comprising:
a substrate;
a first electrode on or in the substrate;
auxiliary wiring on or in the substrate at a distance from the first electrode;
a functional layer, including at least a light-emitting layer, above the first electrode;
a hole injection layer for injecting holes to the functional layer, the hole injection layer being between the first electrode and the functional layer; and
a second electrode, above the functional layer, wherein
the hole injection layer and the second electrode are both formed to be continuous above the first electrode and above the auxiliary wiring,
the second electrode and the auxiliary wiring are electrically connected by the hole injection layer, and
the hole injection layer contains a tungsten oxide,
an UPS spectrum, obtained from a UPS measurement, having a protrusion appearing near a Fermi surface and within a region corresponding to a binding energy range lower than a top of a valence band,
the tungsten oxide contained in the hole injection layer satisfying a condition, determined from an XPS measurement, that a ratio in a number density of atoms other than tungsten atoms and oxygen atoms to the tungsten atoms does not exceed 0.83.
2. The organic EL display panel of claim 1 , wherein
the second electrode is a transparent electrode.
3. The organic EL display panel of claim 2 , wherein
the transparent electrode is made up from one of ITO and IZO.
4. The organic EL display panel of claim 1 , wherein
the second electrode has one of Al and Ag as a primary component.
5. The organic EL display panel of claim 1 , further comprising:
a metal layer formed to be continuous above the first electrode and above the auxiliary wiring, wherein
above the first electrode, the metal layer is between the second electrode and the light-emitting layer, and above the auxiliary wiring, the metal layer is between the second electrode and the hole injection layer.
6. The organic EL display panel of claim 5 , wherein
the metal layer is an electron injection layer that, above the first electrode, injects electrons from the second electrode to the light-emitting layer.
7. The organic EL display panel of claim 6 , wherein
the metal layer includes Ba.
8. The organic EL display panel of claim 1 , wherein
the auxiliary wiring is made up from one of ITO and IZO.
9. The organic EL display panel of claim 1 , wherein
the hole injection layer above the auxiliary wiring has properties identical to the hole injection layer above the first electrode.
10. The organic EL display panel of claim 1 , wherein
at least above the auxiliary wiring, the hole injection layer is at least 4 nm thick.
11. The organic EL display panel of claim 1 , further comprising:
a bank on the hole injection layer defining an aperture above the first electrode, wherein
the functional layer is formed in the aperture defined by the bank.
12. The organic EL display panel of claim 11 , wherein
the first electrode comprises a plurality of first electrodes, one per pixel, and
the aperture in the bank comprises a plurality of apertures formed in one-to-one correspondence with the first electrodes.
13. The organic EL display panel of claim 11 , wherein
the first electrode comprises a plurality of first electrodes, one per pixel, arranged in lines, and
the aperture in the bank comprises a plurality of apertures, one for each of the lines of the first electrodes.
14. The organic EL display panel of claim 1 , wherein
in the UPS spectrum, the protrusion appears within the bonding energy range that is from 1.8 eV to 3.6 eV lower than the top of the valance band.
15. The organic EL display panel of claim 1 , wherein
the ratio in the number density of the other atoms to the tungsten atoms does not exceed 0.62.
16. The organic EL display panel of claim 1 , wherein
the atoms other than tungsten atoms and oxygen atoms comprise carbon atoms.
17. The organic EL display panel of claim 1 , wherein
the hole injection layer is irradiated with ultraviolet light so that
the UPS spectrum obtained from the UPS measurement has the protrusion appearing near the Fermi surface and within the region corresponding to the binding energy range lower than the top of a valence band, and
the tungsten oxide contained in the hole injection layer satisfies the condition, as determined by the XPS measurement, that the ratio in the number density of atoms other than tungsten atoms and oxygen atoms to the tungsten atoms does not exceed 0.83.
18. An organic EL display apparatus having the organic EL display panel of claim 1 .
19. An organic EL display panel comprising:
a substrate;
a first electrode on or in the substrate;
wiring on or in the substrate at a distance from the first electrode;
an organic layer, including organic material, above the first electrode;
a tungsten oxide layer, including a tungsten oxide, between the organic layer and the first electrode; and
a second electrode above the organic layer, wherein
the tungsten oxide layer and the second electrode are both formed to be continuous above the first electrode and above the wiring,
the second electrode and the wiring are electrically connected by the tungsten oxide layer,
an UPS spectrum of the tungsten oxide layer, obtained from a UPS measurement, has a protrusion appearing near a Fermi surface and within a region corresponding to a binding energy range lower than a top of a valence band, and
the tungsten oxide satisfies a condition, determined from an XPS measurement, that a ratio in a number density of atoms other than tungsten atoms and oxygen atoms to the tungsten atoms does not exceed 0.83.
20. An organic EL display apparatus having the organic EL display panel of claim 19 .
21. An organic EL display panel comprising:
a substrate;
a first electrode on or in the substrate;
auxiliary wiring on or in the substrate at a distance from the first electrode;
a functional layer, including at least a light-emitting layer, above the first electrode;
a hole injection layer for injecting holes to the functional layer, the hole injection layer being between the first electrode and the functional layer; and
a second electrode, above the functional layer, wherein
the hole injection layer and the second electrode are both formed to be continuous above the first electrode and above the auxiliary wiring,
the second electrode and the auxiliary wiring are electrically connected by the hole injection layer, and
the hole injection layer contains a tungsten oxide,
an UPS spectrum, obtained from a UPS measurement, having:
a protrusion appearing near a Fermi surface and within a region corresponding to a binding energy range lower than a top of a valence band; and
a peak appearing within a region corresponding to a binding energy range from 4.5 eV to 5.4 eV.
22. The organic EL display panel of claim 21 , wherein
in the UPS spectrum, the protrusion appears within the region corresponding to the binding energy range from 1.8 eV to 3.6 eV lower than the top of the valance band.
23. The organic EL display panel of claim 21 , wherein
the hole injection layer is irradiated with ultraviolet light so that
the UPS spectrum obtained from the UPS measurement has:
the protrusion appearing near the Fermi surface and within the region corresponding to the binding energy range lower than the top of a valence band; and
the peak appearing within the region corresponding to the binding energy range from 4.5 eV to 5.4 eV.
24. An organic EL display apparatus having the organic EL display panel of claim 21 .
25. An organic EL display panel comprising:
a substrate;
a first electrode on or in the substrate;
wiring on or in the substrate at a distance from the first electrode;
an organic layer, including organic material, above the first electrode;
a tungsten oxide layer, including a tungsten oxide, between the organic layer and the first electrode; and
a second electrode above the organic layer, wherein
the tungsten oxide layer and the second electrode are both formed to be continuous above the first electrode and above the wiring,
the second electrode and the wiring are electrically connected by the tungsten oxide layer, and
an UPS spectrum of the tungsten oxide layer, obtained from a UPS measurement, has:
a protrusion appearing near a Fermi surface and within a region corresponding to a binding energy range lower than a top of a valence band; and
a peak appearing within a region corresponding to a binding energy range from 4.5 eV to 5.4 eV.
26. An organic EL display apparatus having the organic EL display panel of claim 25 .