Nonaqueous electrolyte secondary battery having a positive electrode including an aluminum foil and a positive electrode active material layer formed thereon
View Patent ↗Provided is a nonaqueous electrolyte secondary battery with improved high-rate discharge characteristics. The nonaqueous electrolyte secondary battery includes a positive electrode including a metal foil and a positive electrode active material layer formed thereon; a negative electrode containing a negative electrode active material; and a nonaqueous electrolyte containing a nonaqueous solvent and a solute dissolved therein. The metal foil of the positive electrode is an aluminum foil having an at least partially roughened surface adjacent to the positive electrode active material layer. The positive electrode includes a conductive layer containing a conductor and a binder in recesses in the at least partially roughened surface of the aluminum foil. The positive electrode active material layer is disposed on the conductive layer and contains a positive electrode active material, the conductor, and the binder.
1. A nonaqueous electrolyte secondary battery comprising:
a positive electrode including an aluminum foil and a positive electrode active material layer formed thereon;
a negative electrode containing a negative electrode active material; and
a nonaqueous electrolyte containing a nonaqueous solvent and a solute dissolved therein, wherein
the aluminum foil of the positive electrode having an at least partially roughened surface adjacent to the positive electrode active material layer,
the positive electrode including a conductive layer containing a conductor and a binder in recesses in the at least partially roughened surface of the aluminum foil, and
the positive electrode active material layer being disposed on the conductive layer and containing a positive electrode active material, the conductor, and the binder,
wherein the conductor contained in the positive electrode comprises at least two conductors with different particle sizes, and
wherein the nonaqueous electrolyte secondary battery satisfies the relationship R AM >R G2 >Rsm>R G1 ,
where R G1 is a particle size (D 50 ) of a conductor G 1 having a smaller particle size,
R G2 is a particle size (D 50 ) of a conductor G 2 having a larger particle size than the conductor G 1 ,
R AM is a particle size (D 10 ) of the positive electrode active material, and
Rsm is an average roughening interval of a roughened surface of the aluminum foil determined by a method specified as a mean width of profile elements in JIS B0601-2001.
2. The nonaqueous electrolyte secondary battery according to claim 1 , wherein
an average roughening interval R sm of the roughened surface of the aluminum foil determined by a method specified as a mean width of profile elements in JIS B0601-2001 is 0.05 to 3.0 μm.
3. The nonaqueous electrolyte secondary battery according to claim 1 , wherein the volume ratio of the conductor G 2 having a larger particle size than the average roughening interval Rsm to the conductor G 1 having a smaller particle size than the average roughening interval Rsm is 1:1 to 0.25:1.
4. The nonaqueous electrolyte secondary battery according to claim 3 , wherein the volume ratio of the conductor having a smaller particle size than the average roughening interval Rsm to the binder is 1:0.5 to 1:1.
5. The nonaqueous electrolyte secondary battery according to claim 1 , wherein the conductor is a carbon material or a metal powder.
6. The nonaqueous electrolyte secondary battery according to claim 5 , wherein the conductor is a carbon material.