Organic electroluminescence element
View Patent ↗Provided is an organic EL element having a high emission efficiency, a light emission life, and excellent high-temperature preservation stability. This organic electroluminescence element has at least one light-emitting layer between a positive electrode and a negative electrode. The light-emitting layer comprises at least one type of light-emitting dopant and at least three types of non-emitting organic materials represented by general formula (2); of the non-emitting organic materials, the material with the largest molecular weight has a molecular weight of 1,500 or less; and the minimum content of the non-emitting organic materials is 1 mass % or greater.
1. An organic electroluminescence element comprising an anode, a cathode and one or more light-emitting layers provided between the anode and the cathode,
wherein
at least one of the one or more light-emitting layers includes at least one type of a light-emitting dopant and at least three types of non-light-emitting organic materials,
a largest molecular weight among molecular weights of the at least three types of the non-light-emitting organic materials is 1500 or less,
a minimum content of the at least three types of the non-light-emitting organic materials is 1% by mass or more, and
the non-light-emitting organic materials are represented by a following general formula (2):
wherein X represents NR′, O, S, PR′, PR′R″R′″, CR′R″ or SiR′R″; R′, R″ and R′″ each represent a hydrogen atom or a substituent; Ar represents an aromatic hydrocarbon ring or an aromatic hetero ring; and n represents an integer from 0 to 8.
2. The organic electroluminescence element of claim 1 , wherein at least one of the at least three types of the non-light-emitting organic materials is a compound represented by a following general formula (3):
wherein X, Y and Z each represent NR′, O, S, PR′, PR′R″R′″, CR′R″ or SiR′R″; R′, R″ and R′″ each represent a hydrogen atom or a substituent; and a benzene ring optionally includes a substituent.
3. The organic electroluminescence element of claim 1 , wherein
five types of the non-light-emitting organic materials represented by the general formula (2) are contained.
4. The organic electroluminescence element of claim 1 , wherein
a content (% by mass) of each of the at least three types of the non-light-emitting organic materials increases with increase of molecular weight of each of the at least three types of the non-light-emitting organic materials.
5. The organic electroluminescence element of claim 1 , wherein
among molecular weights of the at least three types of the non-light-emitting organic materials represented by the general formula (2), a difference between a largest molecular weight M (max) and a smallest molecular weight M (min) is less than 250.
6. The organic electroluminescence element of claim 1 , wherein
the at least one type of the light-emitting dopant is a phosphorescence-emitting dopant.
7. The organic electroluminescence element of claim 6 , wherein
the phosphorescence-emitting dopant is represented by a following general formula (1):
wherein R 1 represents a substituent; Z represents a non-metal atom group necessary for forming a five to seven-membered ring; n1 represents an integer from 0 to 5; B 1 to B 5 each represent a carbon atom, a nitrogen atom, an oxygen atom or a sulfur atom, and at least one of B 1 to B 5 represents a nitrogen atom; M 1 represents a transition metal of Group 8 to 10 on a periodic table; X 1 and X 2 each represent a carbon atom, a nitrogen atom or an oxygen atom; L 1 represents a atom group forming a bidentate ligand with X 1 and X 2 ; m1 represents an integer 1, 2 or 3; m2 represents an integer 0, 1 or 2; and m1+m2 is 2 or 3.