Phenolic modified polyesters and aqueous dispersions
View Patent ↗Substrates, such as the interior surfaces of food containers, can be coated using a composition including a phenolic modified polyester resin prepared using a formulation not including Bisphenol A as a component or subcomponent. These polymers arid subsequent coatings are free of both mobile and bound Bisphenol A moieties. These polymers and resulting coatings have properties similar to and, in some embodiments, superior over comparable conventional polyester coatings.
1. A phenolic modified polyester resin composition prepared by grafting a phenolic resin to a polyester resin, wherein the phenolic modified polyester resin is substantially free of bisphenol A, wherein the polyester resin is prepared by condensing one or more carboxylic acids with one or more polyalcohols, and wherein the phenolic resin is grafted to the carboxylic acid residues or the polyalcohol residues of the polyester resin.
2. The phenolic modified polyester resin according to claim 1 , wherein the phenolic resin is a condensation product of at least one aromatic hydrocarbon and at least one of an aldehyde or a ketone.
3. The phenolic modified polyester resin according to claim 2 , wherein the polyester resin has a molecular weight of between 6,000 and 100,000 g/mol.
4. The phenolic modified polyester resin according to claim 3 , wherein the polyester resin has a molecular weight of between 7,000 and 35,000 g/mol.
5. The phenolic modified polyester resin according to claim 4 , wherein the polyester resin has an Acid Number of between 25 and 55, a hydroxyl number between 30 and 60 and a Tg of between 30° C. and 55° C.
6. The phenolic modified polyester resin according to claim 2 , wherein the phenolic resin is the condensation product of an aromatic hydrocarbon and one of an aldehyde and ketone.
7. The phenolic modified polyester resin according to claim 6 , wherein the phenolic resin is present in amount from 6% to 30% per total weight of the combined resins, and the polyester resin is present in an amount from 70% to 94% per total weight.
8. The phenolic modified polyester resin according to claim 6 , wherein the phenolic resin is selected from the group consisting of a novolak resin and a resol resin.
9. The phenolic modified polyester resin according to claim 1 , wherein the one or more carboxylic acids comprise adipic acid, isophthalic acid and terephthalic acid, and the one or more polyalcohols comprise 2-methyl-1,3-propanediol and trimethylol propane.
10. The phenolic modified polyester resin according to claim 1 , wherein the one or more carboxylic acids is selected from the group consisting of succinic acid, glutaric acid, dimethyl glutaric acid, adipic acid, dimethyl adipic acid, azelaic acid, phthalic acid, isophthalic acid, 5-tert-butyl isophthalic acid, terephthalic acid, dimethyl terephthalic acid, 2,6-naphthalene dicarboxylic acid, and mixtures thereof.
11. The phenolic modified polyester resin according to claim 1 , wherein the one or more carboxylic acids is selected from the group consisting of adipic acid, isophthalic acid, terephthalic acid, and mixtures thereof.
12. A composition comprising:
A phenolic modified polyester resin composition prepared by grafting a phenolic resin to a polyester resin, wherein the phenolic modified polyester resin is dispersed in an aqueous medium and is substantially free of bisphenol A, wherein the polyester resin is prepared by condensing one or more carboxylic acids with one or more polyalcohols, and wherein the phenolic resin is grafted to the carboxylic acid residues or the polyalcohol residues of the polyester resin.
13. The composition according to claim 12 , wherein the polyester resin comprises a condensation product of one or more carboxylic acids with one or more polyalcohols, and the phenolic resin is a condensation product of at least one aromatic hydrocarbon and at least one of an aldehyde or a ketone.
14. The composition according to claim 13 , wherein the polyester resin has a molecular weight of between 7,000 and 35,000 g/mol.
15. The composition according to claim 14 , wherein the polyester resin has an Acid Number of between 25 and 55, an hydroxyl number between 30 and 60 and a Tg of between 30° C. and 55° C.
16. The composition according to claim 12 , wherein the phenolic resin is present in phenolic modified polyester resin in amount from 6% to 30% per total weight of the combined resins, and the polyester resin is present in an amount from 70% to 94% per total weight.
17. The composition according to claim 12 , wherein the composition is between 30% and 50% NVM.
18. A phenolic modified polyester resin composition comprising a phenolic resin grafted to a polyester resin, wherein the phenolic modified polyester resin is substantially free of bisphenol A, wherein the polyester resin is prepared by condensing one or more carboxylic acids with one or more polyalcohols, and wherein the phenolic resin is grafted to the carboxylic acid residues or the polyalcohol residues of the polyester resin.