Polyimide film production method, polyimide film production apparatus, and polyimide film
View Patent ↗A polyimide film which rarely undergoes the formation of bubbles, blisters or the like, even when heated to a high temperature; and a production method and a production apparatus for the polyimide film. The polyimide film production apparatus includes a support body, a cast furnace and a cure furnace, wherein the cure furnace is partitioned into multiple zones so that the temperature of a self-supporting film can be increased in a stepwise manner, and an infrared electric heater, which is disposed at a predetermined distance from the film, is arranged in a zone for heating the atmosphere of the self-supporting film to a temperature of 450° C. or higher on the upper surface side and/or the lower surface side of the self-supporting film. The polyimide production apparatus enables the production of a polyimide film which has a volatile content of 0.1 mass % or less after being heated at 450° C. for 20 minutes.
1. A method for manufacturing a polyimide film, comprising:
a casting step for casting a polyimide precursor solution onto a support, drying the polyimide precursor solution, and forming a self-supporting film having self-supporting properties; and
a curing step for peeling the self-supporting film obtained in the casting step from the support and heat treating the self-supporting film to complete an imidization thereof;
wherein the curing step is carried out in a curing furnace, and the curing step is configured so that a heating means, not being an infrared heater, is operable to increase the ambient temperature in stages, thereby the temperature of the self-supporting film can be increased in stages,
wherein an infrared heater is disposed at a position 0.5 L to 1.0 L, L representing the length of the curing furnace, and an entrance of the curing furnace being at 0 L, and
wherein during a heat treatment of the self-supporting film in which the ambient temperature thereof is increased to a temperature of 450° C. or higher by the heating means, the heating means and heating by the infrared heater are jointly employed so as to increase the surface temperature of the self-supporting film to a temperature of 450° C. to 600° C.
2. The method for manufacturing a polyimide film according to claim 1 , wherein the heating means comprises a heating gas.
3. The method for manufacturing a polyimide film according to claim 1 , wherein the polyimide precursor is a polyamic acid obtained by polymerizing a tetracarboxylic acid component containing 3,3′,4,4′-biphenyltetracarboxylic acid dianhydride and a diamine component containing paraphenylenediamine.
4. The method for manufacturing a polyimide film according to claim 1 , wherein a polyimide film having a width of 200 mm or greater is continuously manufactured.