Granted Patent B2

US 9,359,450 · App. 14/009,430 · Granted Jun 7, 2016

Abstract

Claims (14)

1. A process for reducing the amount of water-insoluble fibers in a water-soluble cellulose derivative comprising the steps of

ai) treating cellulose with an alkali metal hydroxide to produce alkali cellulose,

aii) reacting the alkali cellulose with a derivatizing agent to produce a water-soluble cellulose derivative, and

aiii) washing the water-soluble cellulose derivative with a washing liquor having a temperature of 65 to 95° C. to remove by-products with or without a subsequent drying step but in the absence of a grinding step,

to provide a water-soluble cellulose derivative having a residual amount of at least 20 ppm by weight of water-insoluble fibers in a 2 weight percent aqueous solution of the water-soluble cellulose derivative;

b) mixing the water-soluble cellulose derivative of step a) with a liquid in a compounder to provide a moist water-soluble cellulose derivative having a temperature of at least 55° C. and up to 75° C. and a moisture content of from 50 to 75 percent, based on the total weight of the moist cellulose derivative; and

c) drying-grinding the mixture of step b) having a temperature of at least 55° C. and up to 75° C. in a gas-swept impact mill to obtain a dried and ground cellulose derivative, wherein the water-soluble cellulose derivative is a methylcellulose or a hydroxypropyl methylcellulose.

2. The process of claim 1 wherein in step iii) the water-soluble cellulose derivative is washed with a washing liquor to provide a water-soluble cellulose derivative having a moisture content of from 30 to 60 percent, based on the total weight of the moist cellulose derivative, and is mixed with an additional amount of liquid in step b).

3. The process of claim 1 wherein in step iii) the water-soluble cellulose derivative is washed with a washing liquor and subjected to drying to provide a water-soluble cellulose derivative having a moisture content of less than 30 percent, based on the total weight of the moist cellulose derivative, and is mixed with a liquid in step b).

4. The process of claim 1 wherein in step iii) the water-soluble cellulose derivative is washed with water.

5. The process of claim 1 wherein the water-soluble cellulose derivative has a residual amount of at least 150 ppm of water-insoluble fibers.

6. The process of claim 1 wherein the water-soluble cellulose derivative of step a) is mixed in step b) with a liquid in a compounder to provide a moist water-soluble cellulose derivative having a temperature of at least 58° C.

7. The process of claim 1 wherein in step b) aqueous liquid is used.

8. The process of claim 1 wherein the dried and ground cellulose derivative is subjected to gas classification.

Assignments (8)