Process for producing cellulose derivatives of high bulk density and good flowability
View Patent ↗A particulate cellulose derivative is obtained in a process of grinding and drying a moist cellulose derivative wherein A) a cellulose derivative having a moisture content of from 60 to 95 percent, based on the total weight of the moist cellulose derivative, is provided, B) the moist cellulose derivative is dried and partially ground in a gas-swept impact mill; and C) the ground and partially dried cellulose derivative is contacted with an additional amount of a drying gas outside the gas-swept impact mill. The obtained particulate cellulose derivative has a high untapped bulk density and a good flowability.
1. A process for producing a particulate cellulose derivative by grinding and drying a moist cellulose derivative using a drying gas stream, comprising the steps of
A) providing a moist cellulose derivative having a moisture content of from 60 to 95 percent, based on the total weight of the moist cellulose derivative,
B) grinding and partially drying the moist cellulose derivative in a gas-swept impact mill into which a first drying gas stream is fed; and
C) contacting the ground and partially dried cellulose derivative with a second drying gas stream outside the gas-swept impact mill,
wherein the cellulose derivative is suspended in the entire amount or in at least a portion of the first drying gas stream exiting the gas swept impact mill when the cellulose derivative is contacted with the second drying gas stream outside the gas-swept impact mill
to produce the particulate cellulose derivative.
2. The process of claim 1 wherein the moisture content of the moist cellulose derivative in step A), prior to grinding and drying, is from 75 to 85 percent, based on the total weight of the moist cellulose derivative.
3. The process of claim 1 wherein the ratio of the gas flow of first drying gas stream in the gas-swept impact mill in step B) and the flow of the second drying gas stream in step C) is from 1:10 to 8:1.
4. The process of claim 1 wherein
in step B) moist cellulose derivative and the first drying gas stream are fed into the gas-swept impact mill at a rate of from 52 to 67 m 3 drying gas/kg cellulose derivative, based on the dry weight of cellulose derivative, and/or
in step C) a second drying gas stream is contacted with the cellulose derivative at an amount of from 25 to 150 m 3 drying gas/kg cellulose derivative, based on the dry weight of cellulose derivative.
5. The process of claim 1 wherein the cellulose derivative is a cellulose ether.
6. The process of claim 1 wherein the produced particulate cellulose derivative has a median Equivalent Projected Circle Diameter (EQPC) of less than 140 micrometers.
7. The process of claim 1 wherein the produced particulate cellulose derivative has an untapped bulk density of at least 0.40 g/cm 3 .
8. The process of claim 1 wherein the produced particulate cellulose derivative has a Carr Index of 30.0 or less.
9. The process of claim 1 wherein the produced particulate cellulose derivative has an onset dissolution temperature of at least 61.5° C.
10. A method of increasing the flowability and/or the onset dissolution temperature of a particulate cellulose derivative comprising the steps of
A) providing a moist cellulose derivative having a moisture content of from 60 to 95 percent, based on the total weight of the moist cellulose derivative,
grinding and partially drying the moist cellulose derivative in a gas-swept impact mill into which a first drying gas stream is fed; and
contacting the ground and partially dried cellulose derivative with a second drying gas stream outside the gas-swept impact mill, wherein the cellulose derivative is suspended in the entire amount or in at least a portion of the first drying gas stream exiting the gas swept impact mill when the suspended cellulose derivative is contacted with the second gas stream outside the gas-swept impact mill.
11. The process of claim 1 wherein the drying gas stream used for drying the cellulose derivative is split into two drying gas streams via a slide valve wherein the first drying gas stream is fed into the gas-swept impact mill and the second drying gas stream is contacted with the ground and partially dried cellulose derivative that leaves the impact mill such that the cellulose derivative is suspended in the entire amount or in at least a portion of the drying gas stream exiting the gas swept impact mill when the cellulose derivative is contacted with the second drying gas stream.