Aluminum-copper alloys with improved strength
View Patent ↗Aluminum alloys are provided that can comprise boron and vanadium and high amounts of titanium and zirconium. The aluminum alloys described herein can exhibit superior tensile properties at both room temperature and elevated temperatures and still maintain desirable ductility. The aluminum alloys can be used in applications where resistance to fatigue and breakdown at elevated temperatures is desirable, which includes applications in the aerospace and aeronautical fields.
1. An aluminum alloy, the aluminum alloy comprising:
aluminum;
at least 3.5 and up to 6.5 weight percent of copper;
at least 0.25 and up to about 3 weight percent of titanium;
at least 0.08 and up to about 1 weight percent of vanadium;
at least 0.5 and up to about 3 weight percent of zinc;
at least 0.4 weight percent of magnesium;
at least 0.06 weight percent of boron, wherein the Ti/B ratio is in the range of 1 to 10;
zirconium, wherein the Zr/Ti ratio is in the range of 0.1 to 10;
less than about 0.001 weight percent of lithium; and
wherein the aluminum alloy comprises at least one of the following:
(a) at least about 0.01 and up to about 0.5 weight percent of scandium; or
(b) at least about 0.05 and up to about 1.2 weight percent of cobalt.
2. The aluminum alloy of claim 1 , wherein the combined weight percent of the titanium, zirconium, and vanadium in the aluminum alloy is in the range of 0.18 to 1.5 weight percent.
3. The aluminum alloy of claim 1 , wherein the aluminum alloy comprises silver.
4. The aluminum alloy of claim 1 , wherein the aluminum alloy comprises manganese.
5. The aluminum alloy of claim 1 , wherein the aluminum alloy comprises cobalt.
6. The aluminum alloy of claim 1 , wherein the aluminum alloy comprises scandium.
7. The aluminum alloy of claim 1 , wherein the aluminum comprises the majority of the weight percent of the alloy.
8. The aluminum alloy of claim 1 , wherein the aluminum alloy is a wrought alloy.
9. An aerospace component comprising the aluminum alloy of claim 1 .
10. The aluminum alloy of claim 1 , wherein the Zr/Ti ratio is in the range of 0.1 to 4.
11. The aluminum alloy of claim 1 , where the aluminum alloy is practically free of iron and/or silicon.
12. A wrought aluminum alloy, the aluminum alloy comprising:
at least about 40 and up to about 99 weight percent of aluminum;
at least about 3.5 and up to about 20 weight percent of copper;
at least 0.4 and up to about 10 weight percent of magnesium;
at least 0.06 and up to about 2 weight percent of boron;
at least 0.08 and up to about 1 weight percent of vanadium;
at least 0.5 and up to about 3 weight percent of zinc;
at least 0.25 and up to about 3 weight percent of titanium;
less than about 0.001 weight percent of lithium; and
wherein the aluminum alloy comprises at least one of the following:
(a) at least about 0.01 and up to about 0.5 weight percent of scandium; or
(b) at least about 0.05 and up to about 1.2 weight percent of cobalt.
13. The aluminum alloy of claim 12 , wherein the aluminum alloy comprises:
at least about 0.2 and up to about 1 weight percent of manganese.
14. The aluminum alloy of claim 12 , wherein the aluminum alloy comprises:
at least about 0.2 and up to about 1 weight percent of manganese;
at least about 0.1 and up to about 3 weight percent of zirconium; and
at least about 0.1 and up to about 1 weight percent of silver.
15. The aluminum alloy of claim 14 , wherein the aluminum alloy comprises scandium.
16. The aluminum alloy of claim 14 , wherein the aluminum alloy comprises cobalt.
17. The aluminum alloy of claim 12 , wherein the aluminum alloy comprises:
an ultimate tensile strength at room temperature of at least about 65 and up to about 200 ksi as measured according to ASTM E8; and
an ultimate tensile strength at 500° F. of at least about 35 and up to about 150 ksi as measured according to ASTM E8.
18. The aluminum alloy of claim 12 , wherein the aluminum alloy comprises:
an offset yield strength at room temperature of at least about 60 and up to about 200 ksi as measured according to ASTM E8; and
a percent elongation of at least about 2 and up to about 20 percent as measured according to ASTM E8.
19. An aerospace component comprising the aluminum alloy of claim 12 .
20. The aluminum alloy of claim 12 , wherein the aluminum alloy further comprises zirconium and titanium, wherein the Zr/Ti ratio is in the range of 0.1 to 4.
21. The aluminum alloy of claim 12 , where the aluminum alloy is practically free of iron and/or silicon.
22. A method for producing an aluminum alloy, the method comprising:
(a) heat treating an initial aluminum alloy to thereby provide a heat-treated aluminum alloy;
(b) quenching the heat-treated aluminum alloy to thereby provide a quenched aluminum alloy;
(c) working the quenched aluminum alloy to thereby provide a worked aluminum alloy; and
(d) aging the worked aluminum alloy to thereby provide the aluminum alloy, wherein the aluminum alloy comprises at least about 40 and up to about 99 weight percent of aluminum, at least about 3.5 and up to about 20 weight percent of copper, at least 0.4 and up to about 10 weight percent of magnesium, at least 0.06 and up to about 2 weight percent of boron, at least 0.08 and up to about 1 weight percent of vanadium, at least 0.5 and up to about 3 weight percent of zinc, at least 0.25 and up to about 3 weight percent of titanium, and less than about 0.001 weight percent of lithium;
wherein the aluminum alloy comprises at least one of the following:
(a) at least about 0.01 and up to about 0.5 weight percent of scandium; or
(b) at least about 0.05 and up to about 1.2 weight percent of cobalt.
23. The method of claim 22 , wherein the aluminum alloy comprises:
at least about 0.2 and up to about 1 weight percent of manganese;
at least about 0.1 and up to about 3 weight percent of zirconium; and
at least about 0.1 and up to about 1 weight percent of silver.
24. The method of claim 23 , wherein the aluminum alloy comprises at least about 0.01 and up to about 0.5 weight percent of scandium.
25. The method of claim 23 , wherein the aluminum alloy comprises at least about 0.05 and up to about 1.2 weight percent of cobalt.
26. The method of claim 22 , wherein the aluminum alloy comprises:
an ultimate tensile strength at room temperature of at least about 65 and up to about 200 ksi as measured according to ASTM E8; and
an ultimate tensile strength at 500° F. of at least about 35 and up to about 150 ksi as measured according to ASTM E8.