Methods for making a porous nuclear fuel element
View Patent ↗Porous nuclear fuel elements for use in advanced high temperature gas-cooled nuclear reactors (HTGR's), and to processes for fabricating them. Advanced uranium bi-carbide, uranium tri-carbide and uranium carbonitride nuclear fuels can be used. These fuels have high melting temperatures, high thermal conductivity, and high resistance to erosion by hot hydrogen gas. Tri-carbide fuels, such as (U,Zr,Nb)C, can be fabricated using chemical vapor infiltration (CVI) to simultaneously deposit each of the three separate carbides, e.g., UC, ZrC, and NbC in a single CVI step. By using CVI, the nuclear fuel may be deposited inside of a highly porous skeletal structure made of, for example, reticulated vitreous carbon foam.
1. A process for fabricating a porous nuclear fuel element, comprising:
a) providing a skeletal structure comprising interconnected pores; and
b) performing chemical vapor infiltration (CVI) of the skeletal structure with a nuclear fuel material; wherein the process of chemical vapor infiltration comprises:
i) heating the skeletal structure;
ii) forcing a precursor gas through the heated skeletal structure;
iii) decomposing the precursor gas inside of the heated skeletal structure; and
iv) condensing the decomposed gases from the vapor state as a solid deposited on internal and external surfaces of the skeletal structure to form a skeletal structure comprising solid fuel ligaments;
wherein the skeletal structure comprises a reticulated vitreous or glassy carbon foam.
2. The process of claim 1 , further comprising:
machining the skeletal structure to near-final dimensions prior to performing chemical vapor infiltration.
3. The process of claim 1 , further comprising:
coating the solid fuel ligaments with a barrier coating comprising one or more materials selected from the group consisting of: SiC, NbC, ZrC, BeO, BeC2, ZrC2, SiC, pyrolytic carbon, diamond, and diamond-like carbon.
4. The process of claim 1 , wherein the step of providing a skeletal structure comprising a reticulated vitreous or glassy carbon foam comprises:
a) providing polyurethane foam;
b) impregnating the polyurethane foam with a carbon-bearing resin; and then
c) pyrolizing the resin-impregnated polyurethane foam to produce a reticulated vitreous carbon foam skeletal structure comprising vitreous or glassy carbon.
5. The process of claim 1 , wherein precursor gas comprises a mixture of niobium pentachloride, zirconium pentachloride, uranium pentachloride, methane and hydrogen;
wherein the precursor gas decomposes during chemical vapor infiltration to deposit solid uranium tricarbide (U,Zr,Nb)C on the internal and external surfaces of the skeletal structure.
6. The process of claim 1 , wherein the stoichiometry of the solid uranium tricarbide deposit comprises (U0.1Zr0.77Nb0.13) C0.95.
7. The process of claim 1 , wherein the solid fuel ligaments comprises a uranium tricarbide solid-solution alloy having a density of the alloy greater than or equal to 99% of theoretical density.
8. The process of claim 1 , wherein the skeletal structure is formed of ligaments comprising one or more materials selected from the group consisting of: carbon, graphite, Zr, Nb, Mo, Hf, Ta, W, Re, TiC, TaC, ZrC, SiC, HfC, BeC2, B4C, NbC, GdC, HfB2, ZrB2, Si3N4, TiO2, BeO, SiO2, ZrO2, HfO2, Y2O3, Al2O3, Sc2O3, and Ta2O5.
9. The process of claim 1 , wherein the solid fuel ligaments comprise (U,Zr)C or (U,Nb)C.
10. The process of claim 1 , wherein the solid fuel ligaments comprise a uranium tricarbide alloy selected from the group consisting of (U,Zr,Nb)C; (U,Zr,Ta)C; (U,Zr,Hf)C; and (U,Zr,W)C.
11. The process of claim 1 , wherein the solid fuel ligaments comprise (U,Zr)CN or (U,Ta)CN.
12. The process of claim 1 , wherein the solid fuel ligaments comprise (UWZrXNbY)CZ; where 0.04<W<0.12, 0.45<X<0.9, 0<Y<0.45, and 0.92<Z<1.0.).