Granted Patent B2

US 9,309,410 · App. 14/011,762 · Granted Apr 12, 2016

Abstract

Claims (87)

1. A compound of the formula

wherein:

(a) Ra and Rb each, independently of the other, are:

(i) hydrogen;

(ii) alkyl, including substituted and unsubstituted alkyl, wherein hetero atoms may optionally be present in alkyl;

(iii) aryl, including substituted and unsubstituted aryl, wherein hetero atoms may optionally be present in aryl;

(iv) arylalkyl; including substituted and unsubstituted arylalkyl, wherein hetero atoms may optionally be present in either the aryl or the alkyl portion of arylalkyl; or

(v) alkylaryl, including substituted and unsubstituted alkylaryl, wherein hetero atoms may optionally be present in either the aryl or the alkyl portion of alkylaryl; and

(b) R1 and R2 each, independently of the other, are:

(i) hydrogen, provided that at least one of R1 and R2 is other than hydrogen;

(ii) alkyl, including substituted and unsubstituted alkyl, wherein hetero atoms may optionally be present in alkyl, provided that when R1 and R2 are both alkyl at least one of R1 and R2 has at least about 6 carbons;

(iii) aryl, including substituted and unsubstituted aryl, wherein hetero atoms may optionally be present in aryl;

(iv) arylalkyl, including substituted and unsubstituted arylalkyl, wherein hetero atoms may optionally be present in either the aryl or the alkyl portion of arylalkyl; or

(v) alkylaryl, including substituted and unsubstituted alkylaryl, wherein hetero atoms may optionally be present in either the aryl or the alkyl portion of alkylaryl.

2. A compound according to claim 1 of the formula

3. A compound according to claim 1 of the formula

4. A compound according to claim 1 wherein at least one of R 1 and R 2 is of the formula

- n -C n H 2n+1

wherein n is from about 8 to about 100.

5. A compound according to claim 1 wherein at least one of R 1 and R 2 is of the formula

wherein m+p is from about 8 to about 100.

6. A compound according to claim 1 wherein at least one of R 1 and R 2 is of the formula

wherein q+r is from about 8 to about 100.

7. A compound according to claim 1 wherein at least one of R 1 and R 2 is of the formula

wherein s+t is from about 8 to about 100.

8. A compound according to claim 1 wherein at least one of R 1 and R 2 is of the formula

wherein u+v is from about 8 to about 100.

9. A compound according to claim 1 wherein at least one of R 1 and R 2 is of the formula

wherein w+x is from about 8 to about 100.

10. A compound according to claim 1 wherein at least one of R 1 and R 2 is of the formula

wherein y+z is from about 8 to about 100.

11. A compound according to claim 1 wherein at least one of R 1 and R 2 is of the formula

wherein e+f is from about 8 to about 100.

12. A compound according to claim 1 wherein at least one of R 1 and R 2 has at least about 12 carbons.

13. A compound according to claim 1 wherein R 6 and R 7 are joined to form an aromatic ring.

14. A compound of the formula

wherein:

(a) R a and R b each, independently of the other, are:

(i) hydrogen;

(ii) alkyl, including substituted and unsubstituted alkyl, wherein hetero atoms may optionally be present in alkyl, having from about 1 to about 100 carbons;

(iii) aryl, including substituted and unsubstituted aryl, wherein hetero atoms way optionally be present in aryl, having from about 4 to about 24 carbons;

(iv) arylalkyl, including substituted and unsubstituted arylalkyl, wherein hetero atoms may optionally be present in either the aryl or the alkyl portion of arylalkyl, having from about 5 to about 100 carbons; or

(v) alkylaryl, including substituted and unsubstituted alkylaryl, wherein hetero atoms may optionally be present in either the aryl or the alkyl portion of alkylaryl, having from about 5 to about 100 carbons;

(b) at least one of R 1 and R 2 is:

(a)

- n -C n H 2n+1

wherein n is from about 8 to about 100;

(b)

wherein m+p is from about 8 to about 100;

(c)

wherein q+r is from about 8 to about 100;

(d)

wherein s+t is from about 8 to about 100;

(e)

wherein u+v is from about 8 to about 100;

(f)

wherein w+x is from about 8 to about 100;

(g)

wherein y+z is from about 8 to about 100;

(h)

wherein e+f is from about 8 to about 100; or

(i) a combination thereof; and

(c) R 3 , R 4 , R 5 , R 6 , and R 7 each, independently of the others, are:

(1) alkyl, including substituted and unsubstituted alkyl, wherein hetero atoms may optionally be present in alkyl, having from about 1 to about 100 carbons;

(2) aryl, including substituted and unsubstituted aryl, wherein hetero atoms may optionally be present in aryl, having from about 4 to about 24 carbons;

(3) arylalkyl, including substituted and unsubstituted arylalkyl, wherein hetero atoms may optionally be present in either the aryl or the alkyl portion of arylalkyl, having from about 5 to about 100 carbons;

(4) alkylaryl, including substituted and unsubstituted alkylaryl, wherein hetero atoms may optionally be present in either the aryl or the alkyl portion of alkylaryl, having from about 5 to about 100 carbons;

(5) a substituent other than hydrogen, alkyl, aryl, arylalkyl, or alkylaryl which is halogen, hydroxy, amino, imine, ammonium, pyridine, pyridinium, ether, aldehyde, ketone, ester, amide, carbonyl, thiocarbonyl, sulfate, sulfonate, sulfonic acid, sulfide, sulfoxide, phosphine, phosphonium, phosphate, phosphonate, nitrile, mercapto, nitro, nitroso, sulfone, acyl, acid anhydride, azide, azo, cyanato, isocyanato, thiocyanato, isothiocyanato, carboxylate, carboxylic acid, carbamate, carbamide, silyl, siloxyl, silane, or a combination thereof; or

(6) hydrogen;

wherein two or more of R 3 , R 4 , R 5 , R 6 , and R 7 can be joined together to form a ring and wherein two or three of R 3 , R 4 , R 5 , R 6 , and R 7 are hydrogen.

15. A compound of the formula

wherein:

(a) Ra and Rb each, independently of the other, are:

(i) hydrogen;

(ii) alkyl, including substituted and unsubstituted alkyl, wherein hetero atoms may optionally be present in alkyl, having from about 1 to about 100 carbons;

(iii) aryl, including substituted and unsubstituted aryl, wherein hetero atoms may optionally be present in aryl, having from about 6 to about 12 carbons;

(iv) arylalkyl, including substituted and unsubstituted arylalkyl, wherein hetero atoms may optionally be present in either the aryl or the alkyl portion of arylalkyl, having, from about 7 to about 100 carbons; or

(v) alkylaryl, including substituted and unsubstituted alkylaryl, wherein hetero atoms may optionally be present in either the aryl or the alkyl portion of alkylaryl, having from about 7 to about 100 carbons; and

(b) R1 and R2 each, independently of the other, are:

(i) hydrogen, provided that at least one of R1 and R2 is other than hydrogen;

(ii) alkyl: including substituted and unsubstituted alkyl, wherein hetero atoms may optionally be present in alkyl, having from about 1 to about 100 carbons, provided that when R1 and R2 are both alkyl at least one of R1 and R2 has at least about 6 carbons;

(iii) aryl, including substituted and unsubstituted aryl, wherein hetero atoms may optionally be present in aryl, having from about 6 to about 12 carbons;

(iv) arylalkyl, including substituted and unsubstituted arylalkyl, wherein hetero atoms may optionally be present in either the aryl or the alkyl portion of arylalkyl, having from about 7 to about 100 carbons; or

(v) alkylaryl, including substituted and unsubstituted alkylaryl,

wherein hetero atoms may optionally be present in either the aryl or the alkyl portion of alkylaryl, having from about 7 to about 100 carbons.

16. A compound according to claim 15 wherein the compound is of the formula

17. A compound according to claim 15 wherein the compound is of the formula

Assignments (10)