Tamper evident documents and inks
View Patent ↗A tamper evident document, a process of preparing the tamper evident document, and a tamper evident ink. The tamper evident document includes a paper substrate having a face for providing information, and a tamper evident ink applied on the face of the paper substrate. The tamper evident ink includes (i) microcapsules having a cross-linked polymer shell and a core surrounded by the shell; and (ii) developer particles. The cores of the microcapsules include at least one color former dissolved in a carrier oil. If information on the tamper evident document is altered by force or pressure (e.g., by scraping with a knife), the microcapsules rupture and the color former reacts with the developer particles to provide a visual indication of tampering (e.g., appearance of color or color change) on the face of the document.
1. A tamper evident document comprising:
a paper substrate having a surface for providing information; and
a tamper evident ink on at least a portion of said surface, the ink being in water-in-oil emulsion form having a water phase dispersed in an oil phase;
wherein the water phase contains microcapsules having a cross-linked polymer shell and a core surrounded by the shell, the core comprising at least one color former dissolved in a carrier oil; and
wherein the oil phase contains developer particles.
2. The tamper evident document of claim 1 , wherein the cross-linked polymer shell comprises polyurea.
3. The tamper evident document of claim 1 , wherein the microcapsules have a diameter of about 2-8 microns.
4. The tamper evident document of claim 3 , wherein the developer particles have a diameter of 0.01 to 2 microns.
5. The tamper evident document of claim 1 , wherein the microcapsules have a wall thickness of 110-120 nanometers.
6. The tamper evident document of claim 1 , wherein the at least one color former comprises at least one leuco dye.
7. The tamper evident document of claim 1 , wherein the carrier oil comprises vegetable oil, soybean oil, or mixtures thereof.
8. The tamper evident document of claim 1 , wherein the developer particles comprise zinc.
9. The tamper evident document of claim 1 , wherein the tamper evident ink comprises:
15-25% by weight of the microcapsules; and
15-20% by weight of the developer particles.
10. The tamper evident document of claim 1 , wherein the tamper evident ink further comprises:
20-40% by weight ester resin; and
20-30% by weight oil.
11. The tamper evident document of claim 1 , wherein the tamper evident ink is colorless so long as the at least one color former is not in contact with the developer particles.
12. The tamper evident document of claim 1 , wherein if the information is altered by force or pressure, the microcapsules rupture and the at least one color former reacts with the developer particles to provide a visual indication of tampering.
13. The tamper evident document of claim 12 , wherein the visual indication is a color change or appearance of color where the force or pressure was applied.
14. The tamper evident document of claim 1 , wherein the tamper evident document is a security document selected from the group consisting of a check, lottery ticket, passport, gaming document, and casino document.
15. A process of preparing a tamper evident document comprising:
applying a tamper evident ink on a surface of the document, the tamper evident ink being in emulsion form and having a water phase dispersed in an oil phase;
wherein the water phase contains microcapsules having a cross-linked polymer shell and a core surrounded by the shell, the core comprising at least one color former dissolved in a carrier oil; and
wherein the oil phase contains developer particles.
16. The process of claim 15 , wherein the tamper evident ink is applied to portions of the surface which will contain variable or sensitive information.
17. The process of claim 16 further comprising printing the variable or sensitive information on the surface.
18. The process of claim 15 , wherein the tamper evident ink is applied by coating or printing the tamper evident ink on the surface.
19. The process of claim 18 , wherein the tamper evident ink is applied by dry offset printing.
20. The process of claim 15 , wherein the tamper evident ink comprises an aqueous microcapsule slurry dispersed in an oil phase containing the developer particles.
21. The process of claim 20 , wherein the microcapsules are prepared by polymerizing at least one of hexamethylene diisocyanate and methylene diphenyl diisocyanate with a guanidine carbonate cross linker.
22. A tamper evident ink comprising:
a water in oil emulsion having a water phase dispersed in an oil phase;
the water phase further comprising 15-25% by weight microcapsules having a cross-linked polyurea shell and a core surrounded by the shell, wherein the core comprises at least one color former dissolved in a carrier oil;
the oil phase comprising 15-20% by weight developer particles, 20-40% by weight ester resin, and 20-30% by weight oil.
23. The tamper evident ink of claim 22 , wherein the microcapsules have a wall thickness of 110-120 nanometers.
24. The tamper evident ink of claim 22 , wherein the microcapsule shells comprise a diisocyanate selected from the group consisting of hexamethylene diisocyanate, methylene diphenyl diisocyanate , and mixtures thereof, and a guanidine carbonate cross linker.