Blend of poly(phenylene ether) particles and polyoxymethylene, article thereof, and method of preparation
View Patent ↗A composition contains (a) 1 to 40 weight percent of poly(phenylene ether) particles having a mean particle size of 1 to 40 micrometers; and (b) 60 to 99 weight percent of a polyoxymethylene; wherein polystyrene is absent from the poly(phenylene ether) particles; wherein the composition comprises less than 0.1 volume percent, based on the total volume of the composition, of particulate metals, metalloids, oxides thereof, and combinations thereof, wherein the metals and metalloids are selected from iron, copper, aluminum, magnesium, lead, zinc, tin, chromium, nickel, tungsten, silicon, gold, silver, platinum, and alloys thereof. The poly(phenylene ether) particles reduce the density and increase the char yield of the polyoxymethylene. When the composition is prepared at a temperature below the glass transition temperature of the poly(phenylene ether), increased flexural strength can also be obtained. The composition is useful as a molding composition for a variety of articles.
1. A composition comprising:
(a) 1 to 40 weight percent of poly(phenylene ether) particles having a mean particle size of 1 to 40 micrometers; and
(b) 60 to 99 weight percent of a polyoxymethylene selected from a homopolymer of formaldehyde end-capped with acetic anhydride, a copolymer of formaldehyde and ethylene oxide or dioxolane, and a combination thereof;
wherein the weight percents are based on the combined weight of the poly(phenylene ether) particles and the polyoxymethylene;
wherein polystyrene is absent from the poly(phenylene ether) particles; and
wherein the composition comprises less than 0.1 volume percent, based on the total volume of the composition, of particulate metals, metalloids, oxides thereof, and combinations thereof, wherein the metals and metalloids are selected from iron, copper, aluminum, magnesium, lead, zinc, tin, chromium, nickel, tungsten, silicon, gold, silver, platinum, and alloys thereof; and
wherein the poly(phenylene ether) particles and polyoxymethylene are mixed at a temperature of 100 to 200° C., provided that the temperature is below the glass transition temperature of the poly(phenylene ether).
2. The composition of claim 1 , comprising:
a continuous phase comprising the polyoxymethylene; and
a disperse phase comprising the poly(phenylene ether) particles.
3. The composition of claim 1 , wherein the poly(phenylene ether) particles have a glass transition temperature that is 0 to 20° C. lower than the glass transition temperature of the poly(phenylene ether).
4. The composition of claim 1 , wherein the poly(phenylene ether) particles consist of poly(phenylene ether).
5. The composition of claim 4 , wherein the composition is prepared at a temperature below the glass transition temperature of the poly(phenylene ether).
6. The composition of claim 5 , wherein the composition comprises poly(phenylene ether) particles that are smaller than the poly(phenylene ether) particles when the composition is prepared at a temperature above the glass transition temperature of the poly(phenylene ether).
7. The composition of claim 4 , wherein a test part molded from the composition has a flexural modulus that is 5 to 20% greater, and/or a flexural stress that is 10 to 50% greater, than a test part molded from the same composition prepared at a temperature above the glass transition temperature of the poly(phenylene ether), wherein the flexural modulus and/or flexural stress are measured at 23° C. and a sample thickness of 3.2 millimeters in accordance with ASTM D790-07e1.
8. The composition of claim 4 , wherein the poly(phenylene ether) particles have an aspect ratio of 0.5 to 0.9.
9. The composition of claim 4 , wherein the mean particle size of the poly(phenylene ether) particles is 1 to 10 micrometers.
10. The composition of claim 4 , wherein 90 percent of the particle volume distribution of the poly(phenylene ether) particles is less than 8 micrometers.
11. The composition of claim 4 , wherein the poly(phenylene ether) is poly(2,6-dimethyl-1,4-phenylene ether).
12. The composition of claim 1 , wherein polyolefins, rubber-modified polystyrenes, styrene-containing copolymers, hydrogenated and unhydrogenated block copolymers of an alkenyl aromatic compound and a conjugated diene, and combinations thereof are absent from the poly(phenylene ether) particles.
13. The composition of claim 4 , having one or more of:
a density of 1.10 to 1.38 grams per cubic centimeter, measured in accordance with ASTM D 792-08 at 23° C.;
a heat deflection temperature of 105 to 150° C., measured at 1.92 megapascals in accordance with ASTM D648-07; and
2 to 30 weight percent char, based on the total weight of the poly(phenylene ether) particles and the polyoxymethylene, and measured at 600° C. in air by thermogravimetric analysis.
14. A composition comprising:
(a) 1 to 40 weight percent of poly(phenylene ether) particles having a mean particle size of 1 to 40 micrometers; and
(b) 60 to 99 weight percent of a polyoxymethylene selected from a homopolymer of formaldehyde end-capped with acetic anhydride, a copolymer of formaldehyde and ethylene oxide or dioxolane, and a combination thereof;
wherein the weight percents are based on the combined weight of the poly(phenylene ether) particles and the polyoxymethylene;
wherein polystyrene is absent from the composition; and
wherein the composition comprises less than 0.1 volume percent, based on the total volume of the composition, of particulate metals, metalloids, oxides thereof, and combinations thereof, wherein the metals and metalloids are selected from iron, copper, aluminum, magnesium, lead, zinc, tin, chromium, nickel, tungsten, silicon, gold, silver, platinum, and alloys thereof; and
wherein the poly(phenylene ether) particles and polyoxymethylene are mixed at a temperature of 100 to 210° C., provided that the temperature is below the glass transition temperature of the poly(phenylene ether).
15. The composition of claim 4 , comprising:
(a) 5 to 40 weight percent of poly(2,6-dimethyl-1,4-phenylene ether) particles having a mean particle size of 1 to 10 micrometers; and
(b) 60 to 95 weight percent of a polyoxymethylene selected from a homopolymer of formaldehyde end-capped with acetic anhydride, a copolymer of formaldehyde and ethylene oxide or dioxolane, and a combination thereof; and
wherein the weight percents are based on the combined weight of the poly(2,6-dimethyl-1,4 phenylene ether) particles and the polyoxymethylene.
16. An article comprising the composition of claim 1 .
17. A method of preparing the composition of claim 1 , comprising mixing the poly(phenylene ether) particles and the polyoxymethylene at a temperature of 100 to 210° C., temperature is below the glass transition temperature of the poly(phenylene ether) particles.
18. The method of embodiment 18, wherein the poly(phenylene ether) particles consist of poly(2,6-dimethyl-1,4-phenylene ether), and the poly(2,6-dimethyl-1,4-phenylene ether) particles and polyoxymethylene are mixed at a temperature of 140 to 200° C.
19. A method of forming the article of claim 16 , comprising forming the article at a temperature of 100 to 210° C., provided that the temperature is below the glass transition temperature of the poly(phenylene ether) particles.