COMPOSITIONS AND METHODS FOR IMPROVING THE COMPATIBILITY OF WATER SOLUBLE HERBICIDE SALTS
Methods and compositions for improving the compatibility of aqueous herbicide solutions containing at least one of a water soluble salt of an aryloxyalkanoic acid, a water soluble salt of a pyridyloxyalkanoic acid, and a water soluble salt of glyphosate by adding a surface active compatibilizer are provided.
1 . A method of improving the compatibility of an aqueous herbicide solution including at least one of a water soluble salt of an aryloxyalkanoic acid, a water soluble salt of a pyridyloxyalkanoic acid, and a water soluble salt of glyphosate, comprising adding to the aqueous herbicide solution one or more surface active compatibilizers.
2 . The method of claim 1 , wherein the aryloxyalkanoic acid is 2,4-D, 2,4-DB, dichlorprop, mecoprop, MCPA, or MCPB.
3 . The method of claim 1 , wherein the pyridyloxyalkanoic acid is triclopyr or fluoroxypyr.
4 . The method of claim 1 , further comprising one or more inorganic cations selected from the group consisting of NH 4 + , Na + , K + , Ca 2+ , Me + , Fe 2+ , Fe 3+ , Cu 2+ , Mn 2+ , and Zn 2+ , or one or more organo ammonium cations selected from the group consisting of monomethyl ammonium, isopropyl ammonium, butyl ammonium, dimethyl ammonium, diethyl ammonium, triethyl ammonium, monoethanol ammonium, diethanol ammonium, dimethylethyl ammonium, diethylethanol ammonium, triethanol ammonium, triisopropanol ammonium, tetramethyl ammonium, tetraethyl ammonium, and N,N,N-trimethylethanol ammonium (choline), or mixtures thereof.
5 . The method of claim 1 , wherein the aqueous herbicide solution is a concentrate or a pre-mix concentrate.
6 . The method of claim 5 , wherein the aqueous herbicide solution is a concentrate containing water soluble salts of 2,4-D and/or glyphosate.
7 . The method of claim 1 , wherein the aqueous herbicide solution is a spray solution.
8 . The method of claim 1 , wherein the surface active compatibilizer is a copolymer or grafted polymer of a polyvinylpyrrolidone or a polyvinyl alcohol, a polyacrylate or a polymethacrylate grafted with polyethylene oxide side chains, a polymeric amphoteric dispersant, an ethylene oxide-propylene oxide block copolymer, a sulfonated lignin, a synthetic latex, or mixtures thereof.
9 . The method of claim 8 , wherein the surface active compatibilizer is in the form of a salt.
10 . The method of claim 8 , wherein the surface active compatibilizer is in the form of an acid.
11 . The method of claim 9 , wherein the salt is an organic amine salt or a salt containing inorganic cations.
12 . The method of claim 11 , wherein the organic amine salt comprises a cation selected from monomethyl ammonium, isopropyl ammonium, butyl ammonium, dimethyl ammonium, diethyl ammonium, triethyl ammonium, monoethanol ammonium, diethanol ammonium, dimethylethyl ammonium, diethylethanol ammonium, triethanol ammonium, triisopropanol ammonium, tetramethyl ammonium, tetraethyl ammonium, and N,N,N-trimethylethanol ammonium (choline), or mixtures thereof.
13 . An aqueous herbicide solution of improved compatibility including at least one of a water soluble salt of an aryloxyalkanoic acid, a water soluble salt of a pyridyloxyalkanoic acid, and a water soluble salt of glyphosate, and one or more surface active compatibilizers.
14 . The aqueous herbicide solution of claim 13 , wherein the aryloxyalkanoic acid is at least one of 2,4-D, 2,4-DB, dichlorprop, mecoprop, MCPA, and MCPB.
15 . The aqueous herbicide solution of claim 13 , wherein the pyridyloxyalkanoic acid is triclopyr or fluoroxypyr.
16 . The aqueous herbicide solution of claim 13 , further comprising one or more inorganic cations selected from the group consisting of NH 4 + , Na + , K + , Ca 2+ , Mg 2+ , Fe 2+ , Fe 3+ , Cu 2+ , Mn 2+ , and Zn 2+ , or one or more organo ammonium cations selected from the group consisting of monomethyl ammonium, isopropyl ammonium, butyl ammonium, dimethyl ammonium, diethyl ammonium, triethyl ammonium, monoethanol ammonium, diethanol ammonium, dimethylethyl ammonium, diethylethanol ammonium, triethanol ammonium, triisopropanol ammonium, tetramethyl ammonium, tetraethyl ammonium, N,N,N-trimethylethanol ammonium (choline), or mixtures thereof.
17 . The aqueous herbicide solution of claim 13 , wherein the aqueous herbicide solution is a concentrate or a pre-mix concentrate.
18 . The aqueous herbicide solution of claim 13 , wherein the aqueous herbicide solution is a concentrate containing water soluble salts of 2,4-D and/or glyphosate.
19 . The aqueous herbicide solution of claim 13 , wherein the aqueous herbicide solution is a spray solution.
20 . The aqueous herbicide solution of claim 13 , wherein the surface active compatibilizer is a copolymer or grafted polymer of a polyvinylpyrrolidone or a polyvinyl alcohol, a polyacrylate or a polymethacrylate grafted with polyethylene oxide side chains, a polymeric amphoteric dispersant, an ethylene oxide-propylene oxide block copolymer, a sulfonated lignin, a synthetic latex, or mixtures thereof.
21 . The aqueous herbicide solution of claim 20 , wherein the surface active compatibilizer is in the form of a salt.
22 . The aqueous herbicide solution of claim 21 , wherein the salt is an organic amine salt or a salt containing inorganic cations.
23 . The aqueous herbicide solution of claim 22 , wherein the organic amine salt comprises a cation selected from monomethyl ammonium, isopropyl ammonium, butyl ammonium, dimethyl ammonium, diethyl ammonium, triethyl ammonium, monoethanol ammonium, diethanol ammonium, dimethylethyl ammonium, diethylethanol ammonium, triethanol ammonium, triisopropanol ammonium, tetramethyl ammonium, tetraethyl ammonium, and N,N,N-trimethylethanol ammonium (choline), or mixtures thereof.
24 . A dry herbicide composition comprising a water soluble salt of 2,4-D and/or a water soluble salt of glyphosate, and one or more surface active compatibilizers.
25 . The dry herbicide composition of claim 24 , further comprising one or more inorganic cations selected from the group consisting of NH 4 + , Na + , K + , Ca 2+ , Mg 2+ , Fe 2+ , Fe 3+ , Cu 2+ , Mn 2+ , and Zn 2+ , or one or more organo ammonium cations selected from the group consisting of monomethyl ammonium, isopropyl ammonium, butyl ammonium, dimethyl ammonium, diethyl ammonium, triethyl ammonium, monoethanol ammonium, diethanol ammonium, dimethylethyl ammonium, diethylethanol ammonium, triethanol ammonium, triisopropanol ammonium, tetramethyl ammonium, tetraethyl ammonium, N,N,N-trimethylethanol ammonium (choline), or mixtures thereof.
26 . The dry herbicide composition of claim 24 , wherein the surface active compatibilizer is a copolymer or grafted polymer of a polyvinylpyrrolidone or a polyvinyl alcohol, a polyacrylate or a polymethacrylate grafted with polyethylene oxide side chains, a polymeric amphoteric dispersant, an ethylene oxide-propylene oxide block copolymer, a sulfonated lignin, a synthetic latex, or mixtures thereof.
27 . The dry herbicide composition of claim 26 , wherein the surface active compatibilizer is in the form of a salt.
28 . The dry herbicide composition of claim 27 , wherein the salt is an organic amine salt or a salt containing inorganic cations.
29 . The dry herbicide composition of claim 28 , wherein the organic amine salt comprises a cation selected from monomethyl ammonium, isopropyl ammonium, butyl ammonium, dimethyl ammonium, diethyl ammonium, triethyl ammonium, monoethanol ammonium, diethanol ammonium, dimethylethyl ammonium, diethylethanol ammonium, triethanol ammonium, triisopropanol ammonium, tetramethyl ammonium, tetraethyl ammonium, and N,N,N-trimethylethanol ammonium (choline), or mixtures thereof.