ENVIRONMENTALLY BENEFICIAL AND EFFECTIVE HYDROCHLOROFLUOROCARBON COMPOSITIONS FOR FIRE EXTINGUISHING APPLICATIONS
Compositions are described which are useful in many applications such as fire extinguishing or refrigeration. The compositions may include a hydrochlorofluorocarbon such as 2,2-dichloro-1,1,1-trifluoroethane, a dispersant such as CF 3 I, and an inert gas such as argon, and may in some embodiments be held under pressure. For example, some fire extinguishing compositions may be composed of 2,2-dichloro-1,1,1-trifluoroethane, CF 3 I, and argon.
1 . A fire extinguishing unit, comprising a container, a valve, and a nozzle, wherein said container contains a fire extinguishing composition;
wherein the fire extinguishing composition has a pressure of about 70 psig to about 800 psig at about 20° C. and consists essentially of:
2,2-dichloro-1,1,1-trifluoroethane;
CF 3 I; and
argon.
2 . The fire extinguishing unit of claim 1 , wherein the 2,2-dichloro-1,1,1-trifluoroethane is about 95% by weight of the of the fire extinguishing composition without the argon.
3 . The fire extinguishing unit of claim 1 , wherein the fire extinguishing composition has a pressure of about 70 psig to about 250 psig at about 20° C.
4 . The fire extinguishing unit of claim 1 , wherein the CF 3 I is about 4% to about 6% by weight of the of the fire extinguishing composition without the argon.
5 . A composition comprising 2,2-dichloro-1,1,1-trifluoroethane, CF 3 I, and argon.
6 . The composition of claim 5 , which is substantially free of SF 6 , CF 4 , CHF 3 , and CO 2 .
7 . The composition of claim 6 , which is substantially free of CF 4 .
8 . The composition of claim 5 , wherein the CF 3 I has a concentration in the range of about 4% to about 6% by weight based upon the total weight of the composition without the argon.
9 . The composition of claim 5 , comprising about 92% to about 97% by weight 2,2-dichloro-1,1,1-trifluoroethane and about 3% to about 8% by weight CF 3 I based upon the weight of the composition without argon, and wherein the addition of argon results in a composition pressure of about 70 psig to about 150 psig at about 20° C.
10 . The composition of claim 5 , comprising about 94% to about 96% by weight 2,2-dichloro-1,1,1-trifluoroethane and about 4% to about 6% by weight CF 3 I based upon the weight of the composition without argon, and wherein the addition of argon results in a composition pressure of about 100 psig at about 20° C.
11 . A fire extinguishing unit comprising a fire extinguishing composition, wherein the fire extinguishing composition is the composition of claim 5
12 . The fire extinguishing unit of claim 11 , further comprising a container, a valve, and a nozzle, wherein said container contains the fire extinguishing composition;
wherein the composition further comprises:
a basis comprising the 2,2-dichloro-1,1,1-trifluoroethane;
a dispersant consisting essentially of CF 3 I; and
an inert gas comprising argon.
13 . The fire extinguishing unit of claim 12 , wherein the fire extinguishing composition is substantially free of CF 4 .
14 . The fire extinguishing unit of claim 12 , wherein the basis consists essentially of 2,2-dichloro-1,1,1 -trifluoroethane.
15 . The fire extinguishing unit of claim 12 , wherein the fire extinguishing composition has a pressure of about 70 psig to about 200 psig at about 20° C.
16 . The fire extinguishing unit of claim 12 , wherein the fire extinguishing composition has a pressure of about 100 psig to about 150 psig at about 20° C.
17 . The fire extinguishing unit of claim 11 , wherein the fire extinguishing composition comprises about 94% to about 96% by weight 2,2-dichloro-1,1,1-trifluoroethane and about 4% to about 6% by weight CF 3 I, based upon the total weight of the basis and the dispersant.
18 . The fire extinguishing unit of claim 11 , further comprising a pressure delivery system, a container, and the composition, wherein the fire extinguishing composition consists essentially of about 94% to about 96% by weight 2,2-dichloro-1,1,1-trifluoroethane and about 4% to about 6% by weight CF 3 I based upon the total weight of the 2,2-dichloro-1,1,1-trifluoroethane and the CF 3 I; and argon resulting in a composition pressure of about 100 to about 195 psig at about 20° C.
19 . The fire extinguishing unit of claim 18 , wherein the fire extinguishing composition has a pressure of about 100 psig to 150 psig at 20° C.
20 . The fire extinguishing unit of claim 18 , wherein the fire extinguishing composition consists essentially of about 95% by weight 2,2-dichloro-1,1,1-trifluoroethane and about 5% by weight CF 3 I based upon the total weight of the 2,2-dichloro-1,1,1-trifluoroethane and the CF 3 I; and argon resulting in a composition pressure of about 100 to about 195 psig at about 20° C.