IP Library Granted Patent US 9,127,234
Granted Patent B2
US 9,127,234 · App. 14/017,617 · Granted Sep 8, 2015

Coke compositions for on-line gas turbine cleaning

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Quick Facts
Patent No.
US 9,127,234
App. No.
14/017,617
Granted
Sep 8, 2015
Kind
B2
Abstract

A particulate coke composition including expandable coke is capable of removing deposits from rotating parts of a gas turbine engine while under full fire or idle speed. The coke composition may be introduced directly into the combustion chamber (combustor) of the gas turbine or, alternatively, anywhere in the fuel stream, water washing system, or the combustion air system. By kinetic impact with the deposits on blades and vanes, the deposits will be dislodged and will thereby restore the gas turbine to rated power output. If introduced into the compressor section, the coke particles impinge on those metal surfaces, cleaning them prior to entering the hot gas section where the process is repeated.

Claims (16)

1. A particulate cleaning composition for on-line cleaning of surfaces hydrocarbon fuel burning gas turbine system a comprising:

a high purity expandable coke or a mixture of high purity expandable cokes,

a high purity non-expandable coke or a mixture of high purity non-expandable cokes, or

mixtures of high purity expandable cokes and high purity non-expandable cokes,

where:

the coke particles have sizes ranging between about 0.01 microns (μm) and about 1,000 microns (μm),

the high purity cokes are greater than 99% carbon,

the expandable coke particles are capable of expanding up to about 150 times their initial volume when heated above a predetermined temperature, and

the composition is capable of cleaning selected sections of a hydrocarbon fuel burning gas turbine system without significant loss of in system power production.

2. The composition of claim 1 , wherein the high purity cokes are greater than 99.5% carbon.

3. The composition of claim 1 , wherein the high purity cokes are greater than 99.75% carbon.

4. The composition of claim 1 , wherein the high purity cokes are greater than 99.9% carbon.

5. The composition of claim 1 , wherein the selected sections are associated with a compressor.

6. The composition of claim 1 , wherein the selected sections are associated with a hot gas path.

7. The composition of claim 1 , wherein the selected sections are associated with heat recovery equipment.

8. The composition of claim 1 , wherein the system burns wherein the system burns a fuel selected from the group consisting of heavy fuel oil, Light Arabian crude oil, light distillate fuel oil, natural gas fuel and mixtures or combinations thereof.

Assignments (5)
SECURITY INTEREST Recorded Mar 2, 2023
From: PILOT CHEMICAL CORP.; PILOT POLYMER TECHNOLOGIES, INC.; LIQUID MINERALS GROUP LTD.
To: U.S. BANK NATIONAL ASSOCIATION, AS ADMINISTRATIVE AGENT
Reel/Frame 062859/0909 →
SECURITY INTEREST Recorded Oct 28, 2016
From: LIQUID MINERALS GROUP LTD.
To: U.S. BANK NATIONAL ASSOCIATION, AS ADMINISTRATIVE AGENT
Reel/Frame 040163/0537 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 25, 2016
From: PILOT CHEMICAL CORP.
To: LIQUID MINERALS GROUP LTD.
Reel/Frame 040120/0730 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 12, 2016
From: LIQUID MINERALS GROUP, INC.; ENVIROCHEM SOLUTIONS LLC; HUGHES, MARK D.; SMITH, DANIEL T.
To: PILOT CHEMICAL CORP.
Reel/Frame 039138/0557 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 12, 2016
From: HUGHES, MARK D.; SMITH, DANIEL T.; KOCH, KENNETH W., SR
To: ENVIROCHEM SOLUTIONS LLC
Reel/Frame 037469/0768 →