Miscibility of otherwise immiscible compounds
View Patent ↗The present invention relates to a novel method for compatibilizing, i.e. improving miscibility of, otherwise immiscible organic materials highly useful in the fibers industry, as well as the compatibilized product of the method. These compatibilized products are stable in the liquid phase at temperatures ranging from about 40° C. to about 200° C. The method involves use of a glycol derived from polymerization of alkylene oxide and tetrahydrofuran, the alkylene oxide having from 2 to 4 carbon atoms, i.e. poly(tetramethylene-co-alkyleneether) glycol, in the mixture.
1. A stable compatibilized mixture consisting of two or more immiscible organic compounds and from about 10 to about 80 wt. % glycol derived from polymerization of alkylene oxide having from 2 to 4 carbon atoms and tetrahydrofuran, said stable compatibilized mixture being stable in the liquid phase at a temperature of from about 40° C. to about 200° C., wherein said immiscible organic compounds consist of a first organic compound selected from the group consisting of short chain glycols, polyethers and mixtures thereof, and a second organic compound selected from the group consisting of long chain polyols, polyesters and mixtures thereof.
2. The stable compatibilized mixture of claim 1 wherein the alkylene oxide is ethylene oxide.
3. The stable compatibilized mixture of claim 1 which is stable in the liquid phase at a temperature of from about 50° C. to about 100° C.
4. The stable compatibilized mixture of claim 1 wherein said first organic compound is selected from the group consisting of ethylene glycol, polyethylene glycol, polypropylene glycol, butanediol and mixtures thereof, and said second organic compound is a polyether polyol.
5. The stable compatibilized mixture of claim 1 wherein said first organic compound is selected from the group consisting of ethylene glycol, butanediol and mixtures thereof, and said second organic compound is selected from the group consisting of polytetramethylene ether glycol, polypropylene glycol, polycaprolactone glycol and a mixture thereof.
6. The stable compatibilized mixture of claim 1 wherein said first organic compound is polyethylene glycol, and said second organic compound is selected from the group consisting of polytetramethylene ether glycol, polypropylene glycol and a mixture thereof.
7. The stable compatibilized mixture of claim 1 wherein from about 10 to about 45 wt. % of one or a mixture of said first organic compounds are present and from about 10 to about 45 wt. % of one or a mixture of said second organic compounds immiscible with said first organic compounds are present.