Bitumen compositions and methods of making
View Patent ↗A non-blown roofing grade bitumen composition comprising bitumen feedstock, polyolefin having a molecular weight of from about 800 to about 50,000 g/mol, and optionally one or more additives, wherein the softening point of the composition is above 70° C. as determined according to method ASTM D36 and the penetration of the composition is at least about 12 dmm at 25° C. as determined according to method ASTM D5. A method of making the same.
1. A non-blown roofing grade bitumen composition comprising:
a) bitumen feedstock; and
b) non-oxidized polyolefin selected from the group consisting of, ethylene-acrylic acid (EAA) co-polymer, ethylene-vinyl acetate (EVA) co-polymer, ethylene maleic anhydride (MAPE) co-polymer, propylene maleic anhydride (MAPP) co-polymer, Fischer-Tropsch wax (FT wax), and mixtures thereof having a crystallinity of greater than 75% and having a molecular weight of from about 2000 to about 15,000 g/mol; wherein the softening point of the composition is above 70° C. as determined according to method ASTM D36, and wherein the penetration of the composition is at least about 12 dmm at 25° C. as determined according to method ASTM D5.
2. The bitumen composition of claim 1 , wherein the bitumen feedstock is a paving grade bitumen.
3. The bitumen composition of claim 2 , wherein the polyolefin is Fischer-Tropsch wax (FT wax).
4. The bitumen composition of claim 3 , further comprising additives, wherein the additives are selected from the group consisting of plastomers, elastomers, waxes, polyphosphoric acid, flux oil, plasticizers and anti-oxidants.
5. The bitumen composition of claim 4 , wherein the polyolefin is present at a concentration of from about 0.5 weight % to about 25 weight % of the total weight of the bitumen composition; wherein the bitumen feedstock is present at a concentration of from about 65 weight % to about 99 weight % of the total weight of the bitumen composition; and wherein the one or more additives together are present at a concentration of from about 0.5 weight % to about 10 weight % of the total weight of the bitumen composition.
6. The bitumen composition of claim 1 , having a softening point at a temperature of from about 80° C. to about 115° C. as determined according to method ASTM D36.
7. The bitumen composition of claim 6 , not comprising styrene/butadiene/styrene triblock copolymer (SBS).
8. The bitumen composition of claim 1 , wherein the polyolefin has a crystallinity of from about 80% to about 90%.
9. A method of making the bitumen composition of claim 1 comprising mixing the polyolefin or mixtures of different low molecular weight polyolefins with the bitumen feedstock at a temperature of from about 75° C. to about 200° C. for a time of about 30 minutes to about 6 hours.
10. The method of claim 9 , wherein the mixing is done by using a low shear mixer at a speed of from about 5 RPM to about 100 RPM.
11. The bitumen composition of claim 1 wherein the polyolefin has a crystallinity of from about 90% to about 100%.
12. A non-blown roofing grade bitumen composition comprising:
a) bitumen feedstock; and
b) a polyolefin having a crystallinity of greater than 75% and having a molecular weight of from about 800 to about 50,000 g/mol; wherein the softening point of the composition is between 57° C. and 113° C. as determined according to method ASTM D36, and wherein the penetration of the composition is at least about 12 dmm at 25° C. as determined according to method ASTM D5, and wherein the polyolefin is non-oxidized and is selected from the group consisting of ethylene-acrylic acid (EAA) co-polymer, ethylene-vinyl acetate (EVA) co-polymer, ethylene maleic anhydride (MAPE) co-polymer, and propylene maleic anhydride (MAPP) co-polymer.
13. The bitumen composition of claim 12 , wherein the softening point of the composition is between 57° C. and 66° C. as determined according to method ASTM D36 and the penetration of the composition is from about 18 to about 60 dmm at 25° C. as determined according to method ASTM D5.
14. The bitumen composition of claim 12 , wherein the softening point of the composition is between 70° C. and 80° C. as determined according to method ASTM D36 and the penetration of the composition is from about 18 to about 40 dmm at 25° C. as determined according to method ASTM D5.
15. The bitumen composition of claim 12 , wherein the softening point of the composition is between 85° C. and 96° C. as determined according to method ASTM D36 and the penetration of the composition is from about 15 to about 35 dmm at 25° C. as determined according to method ASTM D5.
16. The bitumen composition of claim 12 , wherein the softening point of the composition is between 99° C. and 107° C. as determined according to method ASTM D36 and the penetration of the composition is from about 12 to about 25 dmm at 25° C. as determined according to method ASTM D5.
17. The bitumen composition of claim 12 further comprising c) one or more additives, wherein the additives are selected from the group consisting of plastomers, elastomers, waxes, polyphosphoric acid, flux oil, plasticizers and anti-oxidants.
18. The bitumen composition of claim 12 wherein the bitumen composition consists of the bitumen feedstock and the polyolefin.
19. The bitumen composition of claim 12 wherein the polyolefin has a crystallinity of from about 90% to about 100%.