Process for preparing adhesive using planetary extruder
View Patent ↗A continuous process for preparing a pressure sensitive adhesive using a planetary roller extruder is described. The continuous process includes introducing at least one non-thermoplastic elastomer into a planetary roller extruder and initially compounding the non-thermoplastic elastomer in the planetary roller extruder to form an initially masticated non-thermoplastic elastomer. Then, a solid raw material, a liquid material, or both are introduced into the initially masticated non-thermoplastic elastomer in the planetary roller extruder, and subsequent compounding of the initially masticated non-thermoplastic elastomer with these additional components occurs to form an adhesive composition.
1. A continuous process for preparing an adhesive composition comprising:
introducing at least one non-thermoplastic elastomer into a planetary roller extruder;
initially compounding the non-thermoplastic elastomer in the planetary roller extruder to form an initially masticated non-thermoplastic elastomer;
introducing a solid raw material, a liquid material, or both into the initially masticated non-thermoplastic elastomer in the planetary roller extruder; and
subsequently compounding the initially masticated non-thermoplastic elastomer with the solid raw material, the liquid material, or both thereof to form an adhesive composition;
wherein the liquid material is present and comprises a solvent added to the adhesive composition in an amount of about 10% to about 50% by weight.
2. The continuous process of claim 1 , wherein the solid raw material has a specific heat that enables the solid raw material to act as a heat sink while subsequently compounding with the initially masticated non-thermoplastic elastomer.
3. The continuous process of claim 1 , wherein the solid raw material includes at least one of a thermoplastic elastomer, a tackifier resin, an extender, an activator, an anti-degradent, a crosslinker, an opacifier, and a colorant.
4. The continuous process of claim 3 , wherein the solid raw material includes at least one thermoplastic elastomer, and the non-thermoplastic elastomer includes at least one natural rubber, synthetic rubber, or one of both.
5. The continuous process of claim 3 , wherein the solid raw material includes at least one thermoplastic elastomer selected from the group consisting of styrene-isoprene-styrene, styrene-butadiene-styrene, styrene-isoprene-butadiene-styrene, styrene-ethylene-butadiene-styrene, styrene-ethylene-propylene-styrene, and combinations thereof.
6. The continuous process of claim 1 , wherein the liquid material further comprises at least one of an elastomer, a tackifier resin, an oil, and a plasticizer.
7. The continuous process of claim 1 , wherein the solvent comprises at least one non-polar aromatic, one non-polar aliphatic, or a blend thereof.
8. The continuous process of claim 1 , wherein the solvent is added in an amount of about 10% to about 20% by weight of the adhesive composition, and the process further comprises applying the adhesive composition to a substrate using a slot-die applicator.
9. The continuous process of claim 1 , wherein the solvent is added in an amount of about 10% to about 20% by weight of the adhesive composition, and the process further comprises applying the adhesive composition to a substrate using a reverse roll, roll-over-roll, or knife-over-roll applicator.
10. The continuous process of claim 1 , wherein the non-thermoplastic elastomer in the adhesive composition has a molecular weight less than 1,000,000 as measured by GPC.
11. The continuous process of claim 1 , wherein the non-thermoplastic elastomer has an initial molecular weight when introduced into the planetary roller extruder and the initial molecular weight is reduced by more than about 50% during the process.
12. The continuous process of claim 1 , further comprises:
introducing a heat-activatable crosslinker into the planetary roller extruder while initially masticating, after initially masticating, or while subsequently masticating the non-thermoplastic elastomer in the planetary roller extruder.
13. The continuous process of claim 12 , wherein the heat-activatable crosslinker is selected from the group consisting of an accelerated sulphur or sulphur donor system, an isocyanate system, a reactive melamine resin, a formaldehyde resin, a phenol-formaldehyde resin, a reactive phenolic resin, a diisocyanate system, an epoxidized polyester resin, and combinations thereof.
14. The continuous process of claim 12 , wherein the adhesive composition has a final temperature of about 25° C. to about 100° C.
15. The continuous process of claim 12 , wherein the activation temperature of the heat-activatable crosslinker is about 110° C. to about 140° C.
16. The continuous process of claim 14 , wherein the activation temperature of the heat-activatable crosslinker is about 110° C. to about 140° C.
17. The continuous process of claim 14 , wherein the temperature is maintained at about 80° C.
18. The continuous process of claim 13 , wherein the heat-activatable crosslinker is the isocyanate system or the diisocyanate system.