IP Library Granted Patent US 9,115,855
Granted Patent B2
US 9,115,855 · App. 14/026,693 · Granted Aug 25, 2015

White light source

Inventors: Tatsunori Itoga (Kamakura, JP); Masahiko Yamakawa (Yokohama, JP); Yasumasa Ooya (Chigasaki, JP)
Assignees: KABUSHIKI KAISHA TOSHIBA; TOSHIBA MATERIALS CO., LTD.
F21K9/56C09K11/02C09K11/7734H05B33/0857H01L33/502H01L33/507Y02B20/181
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Quick Facts
Patent No.
US 9,115,855
App. No.
14/026,693
Granted
Aug 25, 2015
Kind
B2
Abstract

A white light source 1 of an embodiment has color temperature of 2600 [K] or more and less than 3200 [K]. The white light source of the embodiment has a ratio of a minimum emission intensity to a maximum emission intensity in a wavelength region of from 450 to 610 [nm] on an emission spectrum of 0.16 or more and less than 0.35.

Claims (95)

1. A white light source, comprising:

a light-emitting diode; and

a phosphor layer absorbing a light radiated from the light-emitting diode to emit a white light;

the phosphor layer including a blue phosphor of from 30 to 60 mass %, a blue-green phosphor of from 5 to 20 mass %, at least one phosphor selected from a green phosphor and a yellow phosphor of from 3 to 20 mass %, and a red phosphor of from 20 to 50 mass %;

the white light having a color temperature of 2600 [K] or more and less than 3200 [K] and an emission spectrum which has a wavelength region of from 450 to 610 [nm]; and

a ratio of a minimum emission intensity to a maximum emission intensity in the wavelength region being 0.16 or more and less than 0.35.

2. The white light source according claim 1 ,

wherein a difference between the ratio of the minimum emission intensity to the maximum emission intensity in the wavelength region of the emission spectrum and a ratio of a minimum emission intensity to a maximum emission intensity in a wavelength region of from 450 to 610 [nm] on an emission spectrum of black body radiation at the same color temperature as the white light source is −0.02 or more and +0.02 or less.

3. The white light source according to claim 1 ,

wherein the phosphor layer has a single-layer structure or a stacked structure.

4. The white light source according to claim 1 ,

wherein the blue phosphor is a europium-activated alkaline earth chlorophosphate phosphor,

wherein the blue-green phosphor is a europium-activated strontium aluminate phosphor,

wherein the green or yellow phosphor is at least one selected from a europium and manganese-activated alkaline earth aluminate phosphor, a europium and manganese-activated alkaline earth silicate phosphor, and a europium-activated SiAlON phosphor, and

wherein the red phosphor is at least one selected from a europium-activated lanthanum oxysulfide phosphor, a europium-activated CASN phosphor, and a europium-activated SiAlON phosphor.

5. The white light source according to claim 1 ,

wherein the phosphor layer has an average particle diameter of from 3 to 50 μm.

6. The white light source according to claim 1 ,

wherein an amount of the blue-green phosphor is 13.8 mass % or more, and a total amount of the green phosphor and the yellow phosphor is 4.7 mass % or less.

7. A white light source, comprising:

a light-emitting diode; and

a phosphor layer absorbing a light radiated from the light-emitting diode to emit a white light;

the phosphor layer including a blue phosphor of from 35 to 65 mass %, a blue-green phosphor of from 5 to 25 mass %, at least one phosphor selected from a green phosphor and a yellow phosphor of from 3 to 20 mass %, and a red phosphor of from 15 to 45 mass %;

the white light having a color temperature of 3200 [K] or more and less than 3900 [K] and an emission spectrum which has a wavelength region of from 450 to 610 [nm]; and

a ratio of a minimum emission intensity to a maximum emission intensity in the wavelength region being 0.31 or more and less than 0.55.

8. The white light source according claim 7 ,

wherein a difference between the ratio of the minimum emission intensity to the maximum emission intensity in the wavelength region of the emission spectrum and a ratio of a minimum emission intensity to a maximum emission intensity in a wavelength region of from 450 to 610 [nm] on an emission spectrum of black body radiation at the same color temperature as the white light source is −0.02 or more and +0.02 or less.

9. The white light source according to claim 7 ,

wherein the phosphor layer has a single-layer structure or a stacked structure.

10. The white light source according to claim 7 ,

wherein the blue phosphor is a europium-activated alkaline earth chlorophosphate phosphor,

wherein the blue-green phosphor is a europium-activated strontium aluminate phosphor,

wherein the green or yellow phosphor is at least one selected from a europium and manganese-activated alkaline earth aluminate phosphor, a europium and manganese-activated alkaline earth silicate phosphor, and a europium-activated SiAlON phosphor, and

wherein the red phosphor is at least one selected from a europium-activated lanthanum oxysulfide phosphor, a europium-activated CASN phosphor, and a europium-activated SiAlON phosphor.

11. The white light source according to claim 7 ,

wherein the phosphor layer has an average particle diameter of from 3 to 50 μm.

12. The white light source according to claim 7 ,

wherein an amount of the blue-green phosphor is 15.3 mass % or more, and a total amount of the green phosphor and the yellow phosphor is 8.4 mass % or less.

13. A white light source, comprising:

a light-emitting diode; and

a phosphor layer absorbing a light radiated from the light-emitting diode to emit a white light;

the phosphor layer including a blue phosphor of from 40 to 70 mass %, a blue-green phosphor of from 10 to 30 mass %, at least one phosphor selected from a green phosphor and a yellow phosphor of from 3 to 20 mass %, and a red phosphor of from 10 to 40 mass %;

the white light having a color temperature of 3900 [K] or more and less than 4600 [K] and an emission spectrum which has a wavelength region of from 450 to 610 [nm]; and

a ratio of a minimum emission intensity to a maximum emission intensity in the wavelength region being 0.51 or more and less than 0.76.

14. The white light source according claim 13 ,

wherein a difference between the ratio of the minimum emission intensity to the maximum emission intensity in the wavelength region of the emission spectrum and a ratio of a minimum emission intensity to a maximum emission intensity in a wavelength region of from 450 to 610 [nm] on an emission spectrum of black body radiation at the same color temperature as the white light source is −0.02 or more and +0.02 or less.

15. The white light source according to claim 13 ,

wherein the phosphor layer has a single-layer structure or a stacked structure.

16. The white light source according to claim 13 ,

wherein the blue phosphor is a europium-activated alkaline earth chlorophosphate phosphor,

wherein the blue-green phosphor is a europium-activated strontium aluminate phosphor,

wherein the green or yellow phosphor is at least one selected from a europium and manganese-activated alkaline earth aluminate phosphor, a europium and manganese-activated alkaline earth silicate phosphor, and a europium-activated SiAlON phosphor, and

wherein the red phosphor is at least one selected from a europium-activated lanthanum oxysulfide phosphor, a europium-activated CASN phosphor, and a europium-activated SiAlON phosphor.

17. The white light source according to claim 13 ,

wherein the phosphor layer has an average particle diameter of from 3 to 50 μm.

18. The white light source according to claim 13 ,

wherein an amount of the blue-green phosphor is 16.4 mass % or more, and a total amount of the green phosphor and the yellow phosphor is 9.1 mass % or less.

19. A white light source, comprising:

a light-emitting diode; and

a phosphor layer absorbing a light radiated from the light-emitting diode to emit a white light;

the phosphor layer including a blue phosphor of from 45 to 75 mass %, a blue-green phosphor of from 10 to 30 mass %, at least one phosphor selected from a green phosphor and a yellow phosphor of from 3 to 20 mass %, and a red phosphor of from 5 to 30 mass %;

the white light having a color temperature of 4600 [K] or more and less than 5700[K] and an emission spectrum which has a wavelength region of from 450 to 610 [nm]; and

a ratio of a minimum emission intensity to a maximum emission intensity in the wavelength region being 0.72 or more and less than 0.97.

20. The white light source according claim 19 ,

wherein a difference between the ratio of the minimum emission intensity to the maximum emission intensity in the wavelength region of the emission spectrum and a ratio of a minimum emission intensity to a maximum emission intensity in a wavelength region of from 450 to 610 [nm] on an emission spectrum of black body radiation at the same color temperature as the white light source is −0.02 or more and +0.02 or less.

21. The white light source according to claim 19 ,

wherein the phosphor layer has a single-layer structure or a stacked structure.

22. The white light source according to claim 19 ,

wherein the blue phosphor is a europium-activated alkaline earth chlorophosphate phosphor,

wherein the blue-green phosphor is a europium-activated strontium aluminate phosphor,

wherein the green or yellow phosphor is at least one selected from a europium and manganese-activated alkaline earth aluminate phosphor, a europium and manganese-activated alkaline earth silicate phosphor, and a europium-activated SiAlON phosphor, and

wherein the red phosphor is at least one selected from a europium-activated lanthanum oxysulfide phosphor, a europium-activated CASN phosphor, and a europium-activated SiAlON phosphor.

23. The white light source according to claim 19 ,

wherein the phosphor layer has an average particle diameter of from 3 to 50 μm.

24. The white light source according to claim 19 ,

wherein an amount of the blue-green phosphor is 16.7 mass % or more, and a total amount of the green phosphor and the yellow phosphor is 15.2 mass % or less.

25. A white light source, comprising:

a light-emitting diode; and

a phosphor layer absorbing a light radiated from the light-emitting diode to emit a white light;

the phosphor layer including a blue phosphor of from 50 to 80 mass %, a blue-green phosphor of from 10 to 30 mass %, at least one phosphor selected from a green phosphor and a yellow phosphor of from 3 to 20 mass %, and a red phosphor of from 5 to 20 mass %;

the white light having a color temperature of 5700 [K] or more and 6500 [K] or less and an emission spectrum which has a wavelength region of from 450 to 610 [nm]; and

a ratio of a minimum emission intensity to a maximum emission intensity in the wavelength region being 0.79 or more and 0.91 or less.

26. The white light source according claim 25 ,

wherein a difference between the ratio of the minimum emission intensity to the maximum emission intensity in the wavelength region of the emission spectrum and a ratio of a minimum emission intensity to a maximum emission intensity in a wavelength region of from 450 to 610 [nm] on an emission spectrum of black body radiation at the same color temperature as the white light source is −0.02 or more and +0.02 or less.

27. The white light source according to claim 25 ,

wherein the phosphor layer has a single-layer structure or a stacked structure.

28. The white light source according to claim 25 ,

wherein the blue phosphor is a europium-activated alkaline earth chlorophosphate phosphor,

wherein the blue-green phosphor is a europium-activated strontium aluminate phosphor,

wherein the green or yellow phosphor is at least one selected from a europium and manganese-activated alkaline earth aluminate phosphor, a europium and manganese-activated alkaline earth silicate phosphor, and a europium-activated SiAlON phosphor, and

wherein the red phosphor is at least one selected from a europium-activated lanthanum oxysulfide phosphor, a europium-activated CASN phosphor, and a europium-activated SiAlON phosphor.

29. The white light source according to claim 25 ,

wherein the phosphor layer has an average particle diameter of from 3 to 50 μm.

30. The white light source according to claim 25 ,

wherein an amount of the blue-green phosphor is 18.3 mass % or more, and a total amount of the green phosphor and the yellow phosphor is 8.6 mass % or less.

Assignments (3)
NUNC PRO TUNC ASSIGNMENT Recorded Nov 26, 2021
From: TOSHIBA MATERIALS CO.,LTD.
To: SEOUL SEMICONDUCTOR CO.,LTD.
Reel/Frame 058251/0316 →
NUNC PRO TUNC ASSIGNMENT Recorded Jun 21, 2021
From: KABUSHIKI KAISHA TOSHIBA
To: TOSHIBA MATERIALS CO., LTD.
Reel/Frame 057436/0701 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 16, 2013
From: ITOGA, TATSUNORI; YAMAKAWA, MASAHIKO; OOYA, YASUMASA
To: KABUSHIKI KAISHA TOSHIBA; TOSHIBA MATERIALS CO., LTD.
Reel/Frame 031209/0940 →
Priority Claims (1)
JP 2011-057246 · Mar 15, 2011 · national
Continuity (2)
Continuation PCTJP2012001377 · Feb 29, 2012
Related Publication 20140009061A1 · Jan 9, 2014