Method of forming a catalyst with inhibited mobility of nano-active material
A method of forming a catalyst, comprising: providing a plurality of support particles and a plurality of mobility-inhibiting particles, wherein each support particle in the plurality of support particles is bonded with its own catalytic particle; and bonding the plurality of mobility-inhibiting particles to the plurality of support particles, wherein each support particle is separated from every other support particle in the plurality of support particles by at least one of the mobility-inhibiting particles, and wherein the mobility-inhibiting particles are configured to prevent the catalytic particles from moving from one support particle to another support particle.
1. A method of forming a catalyst, comprising:
nano-sizing a precursor support powder;
nano-sizing a precursor catalytic powder; and
bonding the nano-sized catalytic powder to the nano-sized support powder to form combined support/catalytic particles; and
bonding a plurality of mobility-inhibiting particles to the combined support/catalytic particles,
wherein the mobility-inhibiting particles are configured to inhibit movement of the catalytic particles on the support particles.
2. The method of claim 1 , wherein
the precursor support powder has an average grain size equal to or greater than 1 micron; and
the catalytic powder has an average grain size equal to or greater than 1 micron.
3. The method of claim 1 , wherein:
nano-sizing the precursor support powder and the precursor catalytic powder comprises applying a plasma stream to the precursor support powder and to the precursor catalytic powder, thereby vaporizing the precursor support powder and the precursor catalytic powder; and
bonding the nano-sized catalytic powder to the nano-sized support to form the combined support/catalytic particles comprises condensing the vaporized support powder and the vaporized catalytic powder to form the combined support/catalytic particles.
4. The method of claim 1 , wherein the plurality of mobility-inhibiting particles are formed by nano-sizing a precursor mobility-inhibiting powder that has an average grain size equal to or greater than 1 micron.
5. The method of claim 4 , wherein nano-sizing the precursor mobility-inhibiting powder comprises:
applying a plasma stream to the precursor mobility-inhibiting powder, thereby vaporizing the precursor mobility-inhibiting powder; and
condensing the vaporized mobility-inhibiting powder.
6. The method of claim 1 , comprising:
dispersing the support/catalytic particles in a dispersion liquid;
dispersing the plurality of mobility-inhibiting particles in a dispersion liquid; and
mixing the dispersed support/catalytic particles particles with the dispersed mobility-inhibiting particles, thereby forming a mixture of the dispersed support/catalytic particles and the dispersed mobility-inhibiting particles.
7. The method of claim 6 , wherein the dispersion liquid for at least one of the support/catalytic particles and the mobility-inhibiting particles comprises water.
8. The method of claim 6 , wherein the dispersion liquid for at least one of the support/catalytic particles and the mobility-inhibiting particles comprises an organic liquid.
9. The method of claim 8 , wherein the organic liquid is a glycol ether.
10. The method of claim 6 , wherein at least one of dispersing the plurality of support/catalytic particles and dispersing the plurality of mobility-inhibiting particles comprises adding a surfactant to the dispersion liquid.
11. The method of claim 10 , wherein the surfactant is selected from the group consisting of a carboxylic acid, a polyamine, and a polyether.
12. The method of claim 6 , wherein the dispersed support/catalytic particles and the dispersed mobility-inhibiting particles are mixed using a sonication process.
13. The method of claim 6 , wherein the step of bonding the plurality of mobility-inhibiting particles to the support/catalytic particles, comprises freeze-drying the mixture of dispersed support/catalytic support particles and dispersed mobility-inhibiting particles, thereby forming a dried mixture of dispersed support/catalytic particles and dispersed mobility-inhibiting particles.
14. The method of claim 13 , wherein the step of bonding plurality of mobility-inhibiting particles to the support/catalytic particles comprises calcining the dried mixture of dispersed support/catalytic particles and dispersed mobility-inhibiting particles.
15. The method of claim 1 , wherein the nano-sized support powder comprises alumina.
16. The method of claim 1 , wherein the nano-sized catalytic powder comprises platinum.
17. The method of claim 1 , wherein the plurality of mobility-inhibiting particles comprises a different chemical composition than the support/catalytic particles.
18. The method of claim 17 , wherein the plurality of mobility-inhibiting particles comprises a plurality of ceramic particles.
19. The method of claim 17 , wherein the plurality of mobility-inhibiting particles comprises a plurality of metal-oxide particles.
20. The method of claim 1 , wherein:
the nano-sized support powder has a diameter of between 1 nanometer and 500 nanometers;
the nano-sized catalytic powder has a diameter between 0.5 nanometers and 5 nanometers; and
the mobility-inhibiting particles have a diameter between 1 nanometer and 500 nanometers.
21. A method of forming a catalyst, comprising:
nano-sizing a precursor support powder;
nano-sizing a precursor catalytic powder; and
bonding the nano-sized catalytic powder to the nano-sized support powder to form combined support/catalytic particles;
dispersing the support/catalytic particles in a dispersion liquid, thereby forming a dispersion of support/catalytic particles;
dispersing a plurality of mobility-inhibiting particles in a dispersion liquid, thereby forming a dispersion of mobility-inhibiting particles;
mixing the dispersion of support/catalytic particles with the dispersion of mobility-inhibiting particles, thereby forming a wet mixture;
freeze-drying the wet mixture, thereby forming a dried mixture; and
calcining the dried mixture, thereby forming a cluster of the support/catalytic particles and the plurality of mobility-inhibiting particles, wherein the mobility-inhibiting particles are configured to inhibit movement of the catalytic particles on the support particles.
22. The method of claim 21 , comprising:
nano-sizing a precursor support powder that has an average grain size equal to or greater than 1 micron;
nano-sizing a precursor catalytic powder that has an average grain size equal to or greater than 1 micron; and
nano-sizing a precursor mobility-inhibiting powder that has an average grain size equal to or greater than 1 micron.
23. The method of claim 21 , wherein nano-sizing the precursor powders comprise:
applying a plasma stream to the precursor powders, thereby vaporizing the precursor powders; and
condensing the vaporized powders.
24. The method of claim 21 , wherein the dispersion liquid for at least one of the support/catalytic particles and the mobility-inhibiting particles comprises water.
25. The method of claim 21 , wherein the dispersion liquid for at least one of the support/catalytic particles and the mobility-inhibiting particles comprises an organic liquid.
26. The method of claim 25 , wherein the organic liquid is a glycol ether.
27. The method of claim 21 , wherein at least one of dispersing the support/catalytic particles and dispersing the plurality of mobility-inhibiting particles comprises adding a surfactant to the dispersion liquid.
28. The method of claim 27 , wherein the surfactant is selected from the group consisting of a carboxylic acid, a polyamine, and a polyether.
29. The method of claim 21 , wherein the step of mixing the dispersion of support/catalytic particles with the dispersion of mobility-inhibiting particles comprises using a sonication process.
30. The method of claim 21 , wherein the nano-sized support powder comprises alumina.
31. The method of claim 21 , wherein the nano-sized catalytic powder comprises platinum.
32. The method of claim 21 , wherein the plurality of mobility-inhibiting particles comprises a different chemical composition than the support/catalytic particles.
33. The method of claim 32 , wherein the plurality of mobility-inhibiting particles comprises a plurality of ceramic particles.
34. The method of claim 32 , wherein the plurality of mobility-inhibiting particles comprises a plurality of metal-oxide particles.
35. The method of claim 21 , wherein:
nano-sized support powder has a diameter of between 1 nanometer and 500 nanometers;
the nano-sized catalytic powder has a diameter between 0.5 nanometers and 5 nanometers; and
the mobility-inhibiting particles have a diameter between 1 nanometer and 500 nanometers.
36. A catalyst comprising:
a plurality of support particles comprising alumina and having a diameter between 1 nanometer and 500 nanometers, the plurality of support particles are bonded to a plurality catalytic particles to form support/catalytic particles; and
a plurality of mobility-inhibiting particles having a diameter between 1 nanometer and 500 nanometers bonded to the plurality of support/catalytic particles,
wherein the mobility-inhibiting particles are configured to inhibit the catalytic particles from moving on the support particles.
37. The catalyst of claim 36 , wherein the catalytic particles comprise platinum.
38. The catalyst of claim 36 , wherein the plurality of mobility-inhibiting particles comprises a different chemical composition than the plurality of support particles.
39. The catalyst of claim 38 , wherein the plurality of mobility-inhibiting particles comprises a plurality of ceramic particles.
40. The catalyst of claim 38 , wherein the plurality of mobility-inhibiting particles comprises a plurality of metal-oxide particles.