IP Library Granted Patent US 9,132,318
Granted Patent B2
US 9,132,318 · App. 14/035,074 · Granted Sep 15, 2015

Multi-layer core golf ball

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Quick Facts
Patent No.
US 9,132,318
App. No.
14/035,074
Granted
Sep 15, 2015
Kind
B2
Abstract

Golf balls having a very high positive gradient multilayer core are provided. The multilayer core includes an outer core layer and a very soft, low compression inner core layer. The inner core layer is formed from an unfoamed composition and has a center hardness that is at least 40 Shore C points less than the outer surface hardness of the outer core layer.

Claims (54)

1. A golf ball comprising a core and a cover, wherein the core consists of:

a solid inner core layer formed from an unfoamed first polybutadiene composition and having a diameter of 1.10 inch or less and a center Shore C hardness (H center ) of 40 or less,

one or more optional intermediate core layers, and

an outer core layer formed from a second polybutadiene composition and having a thickness of 0.150 inches or greater and an outer surface Shore C hardness (H outer surface ) of 80 or greater,

wherein H outer surface >H center , and H outer surface −H center ≧40, and

wherein the core has a gradient quotient, Q, of from 7 to 12, as defined by the equation:

G

+

T

10

×

COR

=

Q

where G is the hardness gradient of the core in Shore C as defined by H outer surface minus H center , T is the percent of trans-polybutadiene isomer at the surface of the outer core layer, and COR is the coefficient of restitution of the core measured at an incoming velocity of 125 ft/s.

2. The golf ball of claim 1 , wherein the hardness gradient, G, is from 60 to 90.

3. The golf ball of claim 1 , wherein the percent of trans-polybutadiene isomer at the surface of the outer core layer, T, is from 1 to 5.

4. The golf ball of claim 1 , wherein the COR of the core is from 0.790 to 0.840.

5. The golf ball of claim 1 , wherein H outer surface −H center ≧45.

6. The golf ball of claim 1 , wherein H outer surface −H center ≧55.

7. The golf ball of claim 1 , wherein H outer surface −H center ≧60.

8. The golf ball of claim 1 , wherein the inner core layer has a compression of <0.

9. The golf ball of claim 8 , wherein the core has an overall compression of ≧70.

10. A golf ball comprising a core and a cover, wherein the core consists of:

a solid inner core layer formed from an unfoamed first polybutadiene composition and having a diameter of 1.10 inch or less and a center Shore C hardness (H center ) of 30 or less,

one or more optional intermediate core layers, and

an outer core layer formed from a second polybutadiene composition and having a thickness of 0.150 inches or greater and an outer surface Shore C hardness (H outer surface ) of 80 or greater,

wherein H outer surface ≧H center , and H outer surfac −H center ≧50, and

wherein the core has a gradient quotient, Q, of from 7 to 12, as defined by the equation:

G

+

T

10

×

COR

=

Q

where G is the hardness gradient of the core in Shore C as defined by H outer surface minus H center , T is the percent of trans-polybutadiene isomer at the surface of the outer core layer, and COR is the coefficient of restitution of the core measured at an incoming velocity of 125 ft/s.

11. The golf ball of claim 10 , wherein the hardness gradient, G, is from 60 to 90.

12. The golf ball of claim 10 , wherein the percent of trans-polybutadiene isomer at the surface of the outer core layer, T, is from 1 to 5.

13. The golf ball of claim 10 , wherein the COR of the core is from 0.790 to 0.840.

14. The golf ball of claim 10 , wherein H outer surfac −H center ≧55.

15. The golf ball of claim 10 , wherein H outer surfac −H center ≧60.

16. The golf ball of claim 10 , wherein H outer surfac −H center ≧65.

17. The golf ball of claim 10 , wherein H outer surfac −H center ≧70.

18. The golf ball of claim 10 , wherein the inner core layer has a compression of <0.

19. The golf ball of claim 18 , wherein the core has an overall compression of ≧70.

20. The golf ball of claim 10 , wherein the inner core layer composition is a thermoset composition consisting essentially of:

polybutadiene;

from 0.1 phr to 2.0 phr of a peroxide;

optionally 5 phr or less of a metal oxide;

optionally 5 phr or less of a metal coagent;

optionally 5 phr or less of a metal carbonate; and

optionally one or more additional components selected from the group consisting of fillers, colorants, and antioxidants.

Assignments (6)
ASSIGNMENT OF SECURITY INTEREST IN PATENTS (ASSIGNS 039506-0030) Recorded Aug 3, 2022
From: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS RESIGNING ADMINISTRATIVE AGENT
To: JPMORGAN CHASE BANK, N.A., AS SUCCESSOR ADMINISTRATIVE AGENT
Reel/Frame 061521/0414 →
SECURITY INTEREST Recorded Aug 3, 2022
From: ACUSHNET COMPANY
To: JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 061099/0236 →
RELEASE OF SECURITY INTEREST IN PATENTS PREVIOUSLY RECORDED AT REEL/FRAME (032019/0075) Recorded Sep 7, 2016
From: KOREA DEVELOPMENT BANK, NEW YORK BRANCH
To: ACUSHNET COMPANY
Reel/Frame 039939/0405 →
SECURITY INTEREST Recorded Jul 28, 2016
From: ACUSHNET COMPANY
To: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS ADMINISTRATIVE AGENT
Reel/Frame 039506/0030 →
SECURITY AGREEMENT Recorded Jan 14, 2014
From: ACUSHNET COMPANY
To: KOREA DEVELOPMENT BANK, NEW YORK BRANCH
Reel/Frame 032019/0075 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 17, 2013
From: SULLIVAN, MICHAEL J.; GOGUEN, DOUGLAS S.; COMEAU, BRIAN
To: ACUSHNET COMPANY
Reel/Frame 031422/0871 →