IP Library Granted Patent US 9,556,373
Granted Patent B2
US 9,556,373 · App. 14/036,497 · Granted Jan 31, 2017

Gel comprising a phase-change material, method of preparing the gel, and thermal exchange implement comprising the gel

Inventors: Richard M. Formato (Grafton, MA); Dimitrios P. Bakllas (Worcester, MA)
Assignee: COLD CHAIN TECHNOLOGIES, INC.
C09K5/06C09K5/063C08K5/01C08L9/00C08L9/06C08L15/00Y02E60/147Y10T428/1334
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Quick Facts
Patent No.
US 9,556,373
App. No.
14/036,497
Granted
Jan 31, 2017
Kind
B2
Abstract

Gel including a phase-change material and a gelling agent. In one embodiment, the phase-change material may be n-tetradecane, and the gelling agent may be a styrene-ethylene-butylene-styrene (SEBS) triblock copolymer. In particular, the SEBS copolymer may be a high molecular weight SEBS copolymer with a styrene:rubber ratio of about 30:70 to 33:67% by weight. The SEBS copolymer may constitute up to about 10%, by weight, of the gel, preferably less than 6%, by weight, of the gel, with n-tetradecane constituting the remainder. To form the gel, the phase-change material and the gelling agent are mixed together at an elevated temperature relative to room temperature to partially, but not completely, dissolve the gelling agent, i.e., a homogeneous solution is not formed. The mixture is then allowed to cool to room temperature. The invention is also directed at a method of preparing the gel and a thermal exchange implement including the gel.

Claims (43)

1. A method of preparing a gel, the method comprising the steps of:

(a) providing a phase-change material, wherein the phase-change material comprises at least one organic phase-change material selected from the group consisting of n-alkanes;

(b) providing a gelling agent, wherein the gelling agent comprises at least one saturated olefin rubber and wherein the gelling agent constitutes up to about 10%, by weight, of the gel;

(c) mixing together the phase-change material and the gelling agent at a temperature above room temperature, below the flashpoint of the phase-change material and not exceeding 90° C. to partially, but not completely, dissolve the gelling agent, whereby a non-homogeneous mixture is produced; and

(d) allowing the non-homogeneous mixture to cool to room temperature.

2. The method as claimed in claim 1 wherein the at least one organic phase-change material is selected from the group consisting of n-tetradecane, n-hexadecane, n-octadecane, and mixtures thereof.

3. The method as claimed in claim 1 wherein the gelling agent is at least one hydrogenated styrenic block copolymer.

4. The method as claimed in claim 3 wherein the gelling agent is at least one styrene-ethylene-butylene-styrene tri-block copolymer.

5. The method as claimed in claim 4 wherein the gelling agent is at least one high molecular weight styrene-ethylene-butylene-styrene tri-block copolymer with a styrene:rubber ratio in the range of about 30:70 to 33:67 by weight.

6. The method as claimed in claim 1 wherein the gelling agent is selected from the group consisting of a styrene-ethylene-butylene-styrene tri-block copolymer and a styrene-ethylene-propylene-styrene tri-block copolymer.

7. A method of preparing a gel, the method comprising the steps of:

(a) providing a phase-change material, wherein the phase-change material comprises at least one organic phase-change material, wherein the at least one organic phase-change material is n-tetradecane;

(b) providing a gelling agent, wherein the gelling agent comprises at least one saturated olefin rubber and wherein the gelling agent constitutes up to about 10%, by weight, of the gel;

(c) mixing together the phase-change material and the gelling agent at a temperature above room temperature, below the flashpoint of the phase-change material and not exceeding 90° C. to partially, but not completely, dissolve the gelling agent, whereby a non-homogeneous mixture is produced; and

(d) allowing the non-homogeneous mixture to cool to room temperature.

8. A method of preparing a gel, the method comprising the steps of:

(a) providing a phase-change material, wherein the phase-change material comprises at least one organic phase-change material, wherein the at least one organic phase-change material is n-tetradecane;

(b) providing a gelling agent, wherein the gelling agent comprises at least one saturated olefin rubber, wherein the gelling agent constitutes up to about 10%, by weight, of the gel, and wherein the gelling agent is a high molecular weight styrene-ethylene-butylene-styrene tri-block copolymer with a styrene:rubber ratio in the range of about 30:70 to 33:67 by weight;

(c) mixing together the phase-change material and the gelling agent at a temperature above room temperature but below the flashpoint of the phase-change material to partially, but not completely, dissolve the gelling agent, whereby a non-homogeneous mixture is produced; and

(d) allowing the non-homogeneous mixture to cool to room temperature.

9. A method of preparing a gel, the method comprising the steps of:

(a) providing a phase-change material, wherein the phase-change material is n-tetradecane;

(b) providing a gelling agent, wherein the gelling agent is a high molecular weight styrene-ethylene-butylene-styrene tri-block copolymer with a styrene:rubber ratio in the range of about 30:70 to 33:67 by weight and wherein the gelling agent constitutes up to about 10%, by weight, of the gel, with the phase-change material constituting the remainder of the gel;

(c) mixing together the phase-change material and the gelling agent at a temperature above room temperature but below the flashpoint of the phase-change material to partially, but not completely, dissolve the gelling agent, whereby a non-homogeneous mixture is produced; and

(d) allowing the non-homogeneous mixture to cool to room temperature.

10. The method as claimed in claim 9 wherein the gelling agent constitutes less than 6%, by weight, of the gel, with the phase-change material constituting the remainder of the gel.

11. The method as claimed in claim 10 wherein the temperature at which the phase-change material and the gelling agent are mixed together is in the range of about 40° C. to about 55° C.

12. A method of preparing a gel, the method comprising the steps of:

(a) providing a phase-change material;

(b) providing a gelling agent, wherein the gelling agent is at least one styrene-ethylene-propylene-styrene tri-block copolymer;

(c) mixing together the phase-change material and the gelling agent at a temperature above room temperature but below the flashpoint of the phase-change material to partially, but not completely, dissolve the gelling agent, whereby a non-homogeneous mixture is produced; and

(d) allowing the non-homogeneous mixture to cool to room temperature.

13. The method as claimed in claim 12 wherein the gelling agent is at least one high molecular weight styrene-ethylene-propylene-styrene tri-block copolymer with a styrene:rubber ratio of about 20:80 by weight.

14. A method of preparing a gel, the method comprising the steps of:

(a) providing a phase-change material, wherein the phase-change material comprises at least one organic phase-change material selected from the group consisting of n-alkanes;

(b) providing a gelling agent, wherein the gelling agent comprises at least one saturated olefin rubber and wherein the gelling agent constitutes less than 6% by weight of the gel;

(c) mixing together the phase-change material and the gelling agent at a temperature above room temperature but below the flashpoint of the phase-change material to partially, but not completely, dissolve the gelling agent, whereby a non-homogeneous mixture is produced; and

(d) allowing the non-homogeneous mixture to cool to room temperature.

15. A method of preparing a gel, the method comprising the steps of:

(a) providing a phase-change material, wherein the phase-change material is at least one n-alkane;

(b) providing a gelling agent, wherein the gelling agent is selected from the group consisting of a styrene-ethylene-butylene-styrene tri-block copolymer and a styrene-ethylene-propylene-styrene tri-block copolymer and wherein the gelling agent constitutes up to about 10%, by weight, of the gel;

(c) mixing together the phase-change material and the gelling agent at a temperature above room temperature but below the flashpoint of the phase-change material to partially, but not completely, dissolve the gelling agent, whereby a non-homogeneous mixture is produced, wherein the temperature at which the phase-change material and the gelling agent are mixed together is in the range of about 40° C. to about 55° C.; and

(d) allowing the non-homogenous mixture to cool to room temperature.

Assignments (4)
CHANGE OF NAME Recorded Jan 19, 2020
From: COLD CHAIN TECHNOLOGIES, INC.
To: COLD CHAIN TECHNOLOGIES, LLC
Reel/Frame 051642/0744 →
PATENT SECURITY AGREEMENT Recorded Aug 2, 2019
From: COLD CHAIN TECHNOLOGIES, LLC
To: ANTARES CAPITAL LP, AS AGENT
Reel/Frame 049945/0515 →
CHANGE OF ADDRESS OF ASSIGNEE Recorded Aug 13, 2018
From: COLD CHAIN TECHNOLOGIES, INC.
To: COLD CHAIN TECHNOLOGIES, INC.
Reel/Frame 046779/0558 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 25, 2013
From: FORMATO, RICHARD M.; BAKLLAS, DIMITRIOS P.
To: COLD CHAIN TECHNOLOGIES, INC.
Reel/Frame 031277/0763 →
Continuity (2)
Provisional Application 61705293 · Sep 25, 2012
Related Publication 20140087105A1 · Mar 27, 2014