Substrate treatment method and substrate treatment apparatus
The inventive substrate treatment apparatus includes a spin chuck which horizontally holds and rotates a wafer; a heater which is disposed in opposed relation to a lower surface of the wafer held by the spin chuck and heats the wafer from a lower side; a phosphoric acid nozzle which spouts a phosphoric acid aqueous solution to a front surface (upper surface) of the wafer held by the spin chuck; and a suspension liquid nozzle which spouts a silicon suspension liquid to the front surface of the wafer held by the spin chuck. The wafer is maintained at a higher temperature on the order of 300° C. and, in this state, a liquid mixture of the phosphoric acid aqueous solution and the silicon suspension liquid is supplied to the front surface of the wafer.
1. A substrate treatment method comprising:
a higher temperature maintaining step of maintaining a substrate held by a substrate holding unit at a higher temperature that is not lower than 250° C.; and
a phosphoric acid/suspension liquid supplying step of supplying a phosphoric acid aqueous solution and a silicon suspension liquid to a front surface of the substrate held by the substrate holding unit.
2. The substrate treatment method according to claim 1 , wherein both a nitride film and an oxide film are completely removed from the front surface of the substrate held by the substrate holding unit.
3. The substrate treatment method according to claim 1 , wherein the silicon suspension liquid to be supplied to the front surface of the substrate in the phosphoric acid/suspension liquid supplying step is a silicon suspension liquid saturated with silicon.
4. The substrate treatment method according to claim 1 , wherein the phosphoric acid/suspension liquid supplying step comprises:
a phosphoric acid liquid film forming step of forming a liquid film of the phosphoric acid aqueous solution on the front surface of the substrate held by the substrate holding unit; and
a silicon suspension liquid supplying step of supplying the silicon suspension liquid to the front surface of the substrate formed with the liquid film of the phosphoric acid aqueous solution after the phosphoric acid liquid film forming step.
5. The substrate treatment method according to claim 1 , further comprising a cleaning step of cleaning the front surface of the substrate held by the substrate holding unit after the phosphoric acid/suspension liquid supplying step.