IP Library Granted Patent US 9,534,170
Granted Patent B2
US 9,534,170 · App. 14/039,888 · Granted Jan 3, 2017

Dense high-speed scintillator material of low afterglow

Inventors: Bernard Ferrand (Voreppe, FR); Bruno Viana (Montgeron, FR); Ludivine Pidol (Cachan, FR); Pieter Dorenbos (Gm Rijswijk, NL)
Assignee: SAINT-GOBAIN CRISTAUX ET DETECTEURS
C09K11/7774C09K11/745G21K4/00A61B6/4258
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Quick Facts
Patent No.
US 9,534,170
App. No.
14/039,888
Granted
Jan 3, 2017
Kind
B2
Abstract

The invention relates to an inorganic scintillator material of formula Lu (2-y) Y (y-z-x) Ce x M z Si (1-v) M′ v O 5 , in which: M represents a divalent alkaline earth metal and M′ represents a trivalent metal, (z+v) being greater than or equal to 0.0001 and less than or equal to 0.2; z being greater than or equal to 0 and less than or equal to 0.2; v being greater than or equal to 0 and less than or equal to 0.2; x being greater than or equal to 0.0001 and less than 0.1; and y ranging from (x+z) to 1. In particular, this material may equip scintillation detectors for applications in industry, for the medical field (scanners) and/or for detection in oil drilling. The presence of Ca in the crystal reduces the afterglow, while stopping power for high-energy radiation remains high.

Claims (46)

1. A positron emission tomography scanner, comprising:

a computed tomography system comprising an inorganic LSO or LYSO scintillation material comprising a divalent alkaline earth metal ion, M, or Al, wherein the M or Al reduces an afterglow.

2. The scanner of claim 1 , wherein the scintillation material comprises Lu, Si, O, and M, wherein M is Ca, Mg, or Sr, and M reduces an afterglow.

3. The scanner of claim 1 , wherein the scintillation material comprises Lu, Si, O, and Al, wherein the Al reduces an afterglow.

4. The scanner of claim 1 , wherein the scintillation material comprises Lu, Si, O, and Ca, wherein the Ca reduces an afterglow.

5. The scanner of claim 1 , wherein the scintillation material comprises Lu, Si, O, and Al, wherein the Al reduces an afterglow.

6. The scanner of claim 1 , wherein the scintillation material is a single-crystal material.

7. A time of flight positron emission tomography scanner, comprising:

a computed tomography system comprising an inorganic LSO or LYSO scintillation material comprising a divalent alkaline earth metal ion, M, or Al, wherein the M or Al reduces an afterglow.

8. The scanner of claim 7 , wherein the scintillation material comprises Lu, Si, O, and M, wherein M is Ca, Mg, or Sr, and M reduces an afterglow.

9. The scanner of claim 7 , wherein the scintillation material comprises Lu, Si, O, and Al, wherein the Al reduces an afterglow.

10. The scanner of claim 7 , wherein the scintillation material comprises Lu, Si, O, Y and Ca, wherein the Ca reduces an afterglow.

11. The scanner of claim 7 , wherein the scintillation material comprises Lu, Si, O, Y and Al, wherein the Al reduces an afterglow.

12. The scanner of claim 7 , wherein the scintillation material is a single-crystal material.

13. A positron emission tomography scanner, comprising:

a computed tomography system comprising a scintillation material of formula (I):

Lu (2-y) Ce x Ca z SiO 5   (I),

wherein:

z is greater than or equal to 0.0001 and less than 0.05;

x is greater than or equal to 0.0001 and less than 0.1; and

y is equal to (x+z).

14. The scanner of claim 13 , wherein it is of the time of flight type.

15. A positron emission tomography scanner, comprising:

a computed tomography system comprising a scintillation material of formula (II):

Lu (2-y) Ce x M z Si (1-v) M′ v O 5   (Formula II),

wherein:

M is a divalent alkaline earth metal ion;

M′ is a trivalent metal;

(z+v) is greater than or equal to 0.0001 and less than or equal to 0.2;

z is greater than or equal to 0 and less than or equal to 0.2;

v is greater than or equal to 0 and less than or equal to 0.2;

x is greater than or equal to 0.0001 and less than 0.1; and

y is equal to (x+z).

16. The scanner of claim 15 , wherein it is of the time of flight type.

17. A method for improving the resolution of the computed tomography of a positron emission tomography scanner comprising a computed tomography system and an inorganic LSO or LYSO scintillation material, wherein a divalent alkaline earth metal ion, M, or Al is added to said material to reduce an afterglow.

18. The method of claim 17 , wherein the scintillation material comprises Lu, Si, O, and M, wherein M is Ca, Mg, or Sr, and M reduces an afterglow.

19. The method of claim 17 , wherein the scintillation material comprises Lu, Si, O, and Al, wherein the Al reduces an afterglow.

20. The method of claim 17 , wherein the scintillation material comprises Lu, Si, O, and Ca, wherein the Ca reduces an afterglow.

21. The method of claim 17 , wherein the scintillation material comprises Lu, Si, O, and Al, wherein the Al reduces an afterglow.

22. The method of claim 17 , wherein the scintillation material is a single-crystal material.

23. A method for improving the resolution of the computed tomography of a time of flight positron emission tomography scanner comprising a computed tomography system and an inorganic LSO or LYSO scintillation material, wherein a divalent alkaline earth metal ion, M, or Al is added to said material to reduce an afterglow.

24. The method of claim 23 , wherein the scintillation material comprises Lu, Si, O, and M, wherein M is Ca, Mg, or Sr, and M reduces an afterglow.

25. The method of claim 23 , wherein the scintillation material comprises Lu, Si, O, and Al, wherein Al reduces an afterglow.

26. The method of claim 23 , wherein the scintillation material comprises Lu, Si, O, and Ca, wherein the Ca reduces an afterglow.

27. The method of claim 23 , wherein the scintillation material comprises Lu, Si, O, and Al, wherein the Al reduces an afterglow.

28. The method of claim 23 , wherein the scintillation material is a single-crystal material.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 22, 2023
From: SAINT-GOBAIN CRISTAUX ET DETECTEURS
To: LUXIUM SOLUTIONS, LLC
Reel/Frame 063066/0758 →
Priority Claims (1)
FR 04 51815 · Aug 9, 2004 · national
Continuity (4)
Continuation 13214648 · Aug 22, 2011
Division 12622881 · Nov 20, 2009
Division 11573323
Related Publication 20140097385A1 · Apr 10, 2014