Method of manufacturing porous sintered reaction-bonded silicon nitride ceramics from granular Si mixture powder and porous sintered reaction-bonded silicon nitride ceramics manufactured thereby
View Patent ↗Disclosed is a porous sintered reaction-bonded silicon nitride ceramic, which includes an array of sintered granules having fine pore channels in the sintered granules and coarse pore channels formed between the sintered granules, and in which the pore channel size is controlled so that both coarse pores and fine pores are formed together in the ceramic, thus simultaneously enhancing air permeability and capturing efficiency. A method of manufacturing the porous sintered reaction-bonded silicon nitride ceramic is also provided.
1. A method of manufacturing a porous sintered reaction-bonded silicon nitride ceramic, the method comprising:
granulating a material comprising silicon and a sintering additive for preparing a sintered silicon nitride from the silicon to obtain material granules;
pre-sintering the material granules in an inert atmosphere to obtain pre-sintered granules;
subjecting the pre-sintered granules to pressing, to produce a material compact; and
subjecting the material compact to reaction-bonding in a nitriding gas atmosphere and post-sintering in a nitrogen atmosphere,
wherein the sintering additive comprises at least one of alkaline earth metal oxides.
2. The method according to claim 1 , wherein the post-sintering is performed at 1700˜1900° C.
3. The method according to claim 1 , wherein the sintering additive is used in an amount of 2˜10 wt % based on complete nitridation of the silicon.
4. The method according to claim 1 , wherein the pressing is performed at a pressure of 1˜20 MPa.