Electrode material for a spark plug and method of making the same
View Patent ↗An electrode material that may be used in spark plugs and other ignition devices for igniting an air/fuel mixture in an engine. The electrode material has a metal ceramic composite structure and includes a particulate component embedded or dispersed within a matrix component such that the electrode material has a multi-phase microstructure. In an exemplary embodiment, the matrix component includes platinum (Pt) and one or more additive metals like nickel (Ni) or palladium (Pd), and the particulate component includes an electrically conductive ceramic, such as titanium diboride (TiB 2 ). A liquid phase or a solid phase sintering process may be used, depending on the particular constituency of the electrode material.
1. A spark plug, comprising:
a metallic shell having an axial bore;
an insulator having an axial bore and being at least partially disposed within the axial bore of the metallic shell;
a center electrode being at least partially disposed within the axial bore of the insulator; and
a ground electrode being attached to a free end of the metallic shell;
wherein the center electrode, the ground electrode, or both the center and ground electrodes include an electrode material with a metal ceramic composite structure that has a particulate component embedded in a matrix component, and the matrix component includes a platinum-based material and constitutes about 80.0-99.5 wt % of the electrode material, and the particulate component includes an electrically conductive ceramic and constitutes about 0.5-20.0 wt % of the electrode material.
2. The spark plug of claim 1 , wherein the matrix component includes a platinum-based material that includes platinum (Pt) and at least one additive metal, and the platinum (Pt) is the single largest constituent of the platinum-based material on a wt % basis.
3. The spark plug of claim 2 , wherein the platinum-based material includes at least one additive metal that constitutes about 0.5-30.0 wt % of the matrix component.
4. The spark plug of claim 2 , wherein the platinum-based material includes at least one additive metal that is selected from the group consisting of nickel (Ni) or palladium (Pd).
5. The spark plug of claim 4 , wherein the platinum-based material includes at least one alloy that is selected from the group consisting of: Pt—Ni, Pt—Pd, or Pt—Ni—Pd.
6. The spark plug of claim 1 , wherein the particulate component includes at least one electrically conductive ceramic that is selected from the group consisting of: titanium diboride (TiB 2 ), zirconium diboride (ZrB 2 ), or hafnium diboride (HfB 2 ).
7. The spark plug of claim 1 , wherein the particulate component includes particles that have a mean particle diameter of about 1 μm to about 20 μm.
8. The spark plug of claim 1 , wherein the electrode material has a liquid phase sintered metal ceramic composite structure that includes inter-diffused boundaries between melted particles of at least one additive metal and particles of the matrix component or particles of the particulate component.
9. The spark plug of claim 1 , wherein the electrode material has a solid phase sintered metal ceramic composite structure that includes boundaries between non-melted particles of at least one additive metal and particles of the matrix component or particles of the particulate component.
10. A spark plug, comprising:
a metallic shell having an axial bore;
an insulator having an axial bore and being at least partially disposed within the axial bore of the metallic shell;
a center electrode being at least partially disposed within the axial bore of the insulator; and
a ground electrode being attached to a free end of the metallic shell;
wherein the center electrode, the ground electrode, or both the center and ground electrodes include an electrode material with a metal ceramic composite structure that has a particulate component and a matrix component, and the matrix component is a platinum-based alloy in which the particulate component is dispersed, wherein the platinum-based alloy includes at least one additive metal that is selected from the group consisting of nickel (Ni) or palladium (Pd), and the particulate component includes an electrically conductive ceramic that is selected from the group consisting of titanium diboride (TiB 2 ), zirconium diboride (ZrB 2 ), or hafnium diboride (HfB 2 ).