Alkaline detergent composition containing a carboxylic acid/polyalkylene oxide copolymer for hard water scale control
An alkaline detergent is described which includes the use of a copolymer in combination with an alkali metal hydroxide. The detergent maintains cleaning functions and also prevents hard water scaling, for example at application temperatures of between 145-180 degrees Fahrenheit and with a pH of 9.5 to about 13.
1. A detergent composition for hard water scale control comprising:
at least 55 wt-% of alkali metal hydroxide; and
at least one copolymer (A) comprising the following monomers in copolymerized form:
from 45 to 95% by weight of at least one monoethylenically unsaturated C 3 -C 8 -carboxylic acid, or an anhydride or salt thereof, and from about 5 to 55% by weight of at least one nonionic monomer of the formula I
H 2 C═C(R 1 )(CH 2 ) x O[R 2 —O] y —R 3 (I)
in which R 1 is hydrogen or methyl, R 2 are identical or different, linear or branched C 2 -C 6 -alkylene wherein R 2 —O may be arranged in blocks or randomly, and R 3 is hydrogen or a straight-chain or branched C 1 -C 4 -alkyl, x is 0, 1 or 2 and y is a number from 3 to 50;
wherein the detergent composition is free of phosphate.
2. The detergent composition of claim 1 further comprising an additional polymer selected from the group consisting of: polyacrylic acid, polymethacrylic acid, polymaleic acid homopolymers, copolymers of acrylic methacrylic or maleic acids, terpolymers of acrylic acid, methacrylic acid, and maleic acid and combinations thereof.
3. The detergent composition of claim 1 , further comprising a phosphonate.
4. The detergent composition of claim 1 , comprising from 55 wt-% to about 90 wt-% of the alkali metal hydroxide, and from about 1 wt-% to about 25 wt-% of the copolymer (A); wherein the composition, during use, has a pH between about 9.5 and 14.
5. The detergent composition of claim 1 , further comprising from about 1 wt-% to about 20 wt-% of an additional polymer.
6. The detergent composition of claim 1 , wherein y in formula (I) is >5, x in formula (I) is 1, and R 1 in formula (I) is H, or wherein y in formula (I) is >5, x in formula (I) is 2, and R 1 in formula (I) is methyl.
7. The detergent composition of claim 1 , further comprising at least one functional ingredient selected from the group consisting of: chelating agents, sequestering agents, alkaline sources, builders, water conditioners, surfactants, hardening agents, bleaching agents, sanitizers, activators, fillers, defoaming agents, anti-redeposition agents, optical brighteners, dyes, odorants, stabilizing agents, dispersants, enzymes, corrosion inhibitors, thickeners and solubility modifiers.
8. The detergent composition of claim 1 , wherein R 2 is selected from CH 2 CH 2 and CH 2 CH(CH 3 ), and y is in the range of from 8 to 40, and/or wherein the carboxylic acid monomer or anhydride or salt thereof is selected from the group consisting of acrylic acid, methacrylic acid and salts thereof.
9. The detergent composition of claim 8 , wherein the detergent composition is a solid.
10. The detergent composition of claim 9 , wherein the solid is a cast, pressed, or extruded solid.