Biorenewable naphtha composition
View Patent ↗The present invention generally relates to a method for producing a naphtha product from a renewable feedstock. The method includes hydrotreating the renewable feedstock to produce a hydrotreating unit heavy fraction that includes n-paraffins, and hydrocracking the hydrotreating unit heavy fraction to produce a hydrocracking unit product that includes the naphtha product. The method also includes separating the naphtha fraction and optionally recycling the hydrocracking unit heavy fraction through the hydrocracking unit. The present invention also relates to a biorenewable naphtha product suitable for use as feed stock for steam crackers and catalytic reforming units, and for use as fuel, or fuel blend stock.
1. A naphtha boiling range hydrocarbon composition comprising:
n-paraffins, iso-paraffins, aromatics, and naphthenes;
wherein the composition
is produced by hydrocracking a hydrotreated biorenewable feedstock;
comprises
C 4 , C 5 , C 6 , C 7 , C 8 , and C 9 hydrocarbons;
greater than 80.0% by weight n- and iso-paraffins; and
is free of benzene.
2. The composition of claim 1 , wherein the composition has a specific gravity at 20° C. of 0.680 to 0.740.
3. The composition of claim 1 , wherein the n-paraffins and iso-paraffins both comprise C 4 , C 5 , C 6 , C 7 , C 8 , C 9 , and C 10 paraffins.
4. The composition of claim 1 , wherein the biorenewable feedstock comprises monoglycerides, diglycerides, triglycerides, free fatty acids, or combinations thereof.
5. The composition of claim 4 , wherein the biorenewable feedstock is selected from the group comprising animal fats, animal oils, poultry fat, poultry oil, vegetable fats, vegetable oils, rendered fats, rendered oils, restaurant grease, brown grease, waste industrial frying oils, fish oils, fish fats, and combinations thereof.
6. The composition of claim 1 , comprising greater than 90% by weight n- and iso-paraffins.
7. The composition of claim 1 , comprising less than 0.5% by weight olefins.
8. The composition of claim 1 , comprising less than 0.3% by weight olefins.
9. The composition-of claim 1 , comprising less than 7.0% by weight naphthenes.
10. The composition of claim 1 , comprising less than 6.5% by weight naphthenes.
11. The composition of claim 1 , comprising less than 2% by weight total aromatics.
12. The composition of claim 1 , comprising less than 1.0% by weight total aromatics.
13. The composition of claim 1 , wherein the composition is free of oxygenates.
14. The composition of claim 1 , comprising:
greater than 90.0% by weight n- and iso-paraffins;
less than 0.5% by weight olefins;
less than 7.0% by weight naphthenes; and
less than 2% by weight total aromatics.
15. The composition of claim 1 , comprising:
greater than 90.0% by weight n- and iso-paraffins;
less than 0.5% by weight olefins;
less than 7.0% by weight naphthenes;
less than 2% by weight total aromatics; and
wherein the composition is free of oxygentates.
16. The composition of claim 1 , comprising:
greater than 90.0% by weight n- and iso-paraffins;
less than 0.3% by weight olefins;
less than 6.5% by weight naphthenes; and
less than 2% by weight total aromatics.
17. The composition of claim 1 , comprising:
greater than 90.0% by weight n- and iso-paraffins;
less than 0.3% by weight olefins;
less than 6.5% by weight naphthenes; and
less than 1.0% by weight total aromatics.
18. A naphtha boiling range hydrocarbon composition, comprising:
n-paraffins, iso-paraffins, aromatics, and naphthenes;
wherein the composition comprises
C 4 , C 5 , C 6 , C 7 , C 8 , and C 9 hydrocarbons;
greater than 90.0% by weight n- and iso-paraffins;
less than 0.3% by weight olefins;
less than 7.0% by weight naphthenes;
less than 2% by weight total aromatics; and
is free of benzene and oxygenates.
19. The composition of claim 18 , wherein the n-paraffins and iso-paraffins both comprise C 4 , C 5 , C 6 , C 7 , C 8 , C 9 , and C 10 paraffins.