Fluorinated elastomer composition and fluorinated foamed rubber
View Patent ↗To provide a fluorinated elastomer composition which can improve, in production of a fluorinated foamed rubber by foaming and crosslinking a fluorinated elastomer using an organic peroxide as a crosslinking agent, the foamed state and physical properties of the fluorinated foamed rubber. A fluorinated elastomer composition which comprises 100 parts by mass of a fluorinated elastomer, from 0.1 to 20 parts by mass of a blowing agent and from 0.05 to 10 parts by mass of a crosslinking agent comprising a peroxide compound, and which contains no crosslinking aid or contains a crosslinking aid comprising a compound having at least two carbon-carbon double bond-containing groups in the same molecule, in a content of at most 0.3 part by mass, is foamed and crosslinked to produce a fluorinated foamed rubber.
1. A fluorinated elastomer composition to be used for production of a fluorinated foamed rubber, comprising:
100 parts by mass of a fluorinated elastomer;
from 0.1 to 20 parts by mass of a blowing agent;
from 0.05 to 10 parts by mass of a crosslinking agent comprising a peroxide compound; and
from 0.001 to 0.3 part by mass of a crosslinking aid which is a compound having at least two carbon-carbon double bond-containing groups in the same molecule, provided that the carbon-carbon double bond-containing groups present in the same molecule may be the same or different,
wherein the fluorinated elastomer is at least one member selected from the group consisting of a tetrafluoroethylene/propylene copolymer and a tetrafluoroethylene/propylene/vinylidene fluoride copolymer.
2. The fluorinated elastomer composition according to claim 1 , wherein the crosslinking aid is triallyl cyanurate, triallyl isocyanurate or trimethallyl isocyanurate.
3. The fluorinated elastomer composition according to claim 1 , wherein an amount of the crosslinking aid is less than 0.1 part by mass.
4. The fluorinated elastomer composition according to claim 1 , wherein the blowing agent is an azo compound, a nitroso compound or a hydrazine compound.
5. A fluorinated foamed rubber, obtained by foaming and crosslinking the fluorinated elastomer composition as defined in claim 1 .
6. The fluorinated foamed rubber according to claim 5 , wherein the expansion ratio represented by the following formula is at least 5, and the tensile break strength is at least 8 kg/cm 2 :
expansion ratio=[specific gravity of the fluorinated elastomer composition before foaming]/[specific gravity of the fluorinated foamed rubber].
7. A method for producing a fluorinated foamed rubber, comprising foaming and crosslinking the fluorinated elastomer composition as defined in claim 1 .
8. The method according to claim 7 , wherein the fluorinated elastomer composition is heated to from 100 to 300° C. to be foamed and crosslinked.
9. The method according to claim 7 , wherein the fluorinated elastomer composition is heated to a first temperature of from 100 to 250° C., and then heated to a second temperature of from 150 to 300° C., the second temperature being higher than the first temperature.
10. The fluorinated elastomer composition according to claim 1 , wherein an amount of the blowing agent is from 0.3 to 15 parts by mass.
11. The fluorinated elastomer composition according to claim 1 , wherein an amount of the blowing agent is from 0.5 to 10 parts by mass.
12. The fluorinated elastomer composition according to claim 1 , wherein an amount of the crosslinking agent is from 0.3 to 5 parts by mass.
13. The fluorinated elastomer composition according to claim 1 , wherein an amount of the crosslinking agent is from 0.5 to 3 parts by mass.
14. The fluorinated elastomer composition according to claim 1 , wherein an amount of crosslinking aid is 0.005 part by mass or more.
15. The fluorinated elastomer composition according to claim 1 , wherein an amount crosslinking aid is 0.01 part by mass or more.