Method for vacuum-degassing molten glass, apparatus for vacuum-degassing molten glass, process for producing molten glass, apparatus for producing molten glass, process for producing glass product, and apparatus for producing glass product
To provide a vacuum-degassing method and a vacuum degassing apparatus excellent in the effect of vacuum-degassing molten glass, more specifically, a method for vacuum-degassing molten glass and a vacuum degassing apparatus, capable of effectively suppressing formation of reboil bubbles. A method for vacuum-degassing molten glass, which comprises melting glass materials to be silicate glass and passing the resulting molten glass in a flow passage in a vacuum degassing vessel, the interior of which is maintained in a reduced pressure state, to vacuum-degas the molten glass, wherein vacuum-degassing is carried out under conditions satisfying the following formula (1) at a bottom portion of the vacuum degassing vessel: SS= p SO 2 /P abs <2.0 (1) wherein SS is the supersaturation degree of SO 2 in the molten glass, pSO 2 is the partial pressure (Pa) of SO 2 , and P abs is the pressure (Pa) at the bottom portion of the glass flow passage of the vacuum degassing vessel.
1. A method, comprising:
passing a molten silicate glass through a glass flow passage in a vacuum degassing vessel, the interior of which is maintained in a reduced pressure state, to vacuum-degas the molten glass, the molten silicate glass comprising a refining agent containing S (sulfur) element, an amount of the refining agent in the molten silicate glass being 0.043 weight % or more as calculated as SO 3 ;
wherein vacuum-degassing of the molten glass is carried out under conditions satisfying formula (1) at least at a bottom portion on a downstream side of the glass flow passage of the vacuum degassing vessel, such that formation of bubbles at an interface between furnace material of the vacuum degassing vessel and the molten silicate glass is suppressed:
SS= p SO 2 /P abs <2.0 (1)
wherein:
SS is a supersaturation degree of SO 2 in the molten glass;
pSO 2 is a partial pressure (Pa) of SO 2 in the molten glass; and
P abs is a pressure (Pa) at the bottom portion of the glass flow passage of the vacuum degassing vessel.
2. The method according to claim 1 , wherein the silicate glass has a composition of SiO 2 ≧50 mol% and (alkali component oxide plus alkaline earth component oxide)≧10 mol%.
3. The method according to claim 1 , wherein the conditions satisfying formula (1) exist between a downstream end of the glass flow passage and a location L/2 from the downstream end of the glass flow passage, wherein L is a length of the glass flow passage in a horizontal direction.
4. A process, comprising:
melting glass materials to obtain a molten silicate glass which comprises a refining agent containing S (sulfur) element, an amount of the refining agent in the molten silicate glass being 0.043 weight % or more as calculated as SO 3 ; and
passing the molten silicate glass through a glass flow passage in a vacuum degassing vessel, the interior of which is maintained in a reduced pressure state, to vacuum-degas the molten glass;
wherein vacuum-degassing of the molten glass is carried out under conditions satisfying formula (1) at least at a bottom portion on a downstream side of the glass flow passage of the vacuum degassing vessel, such that formation of bubbles at an interface between furnace material of the vacuum degassing vessel and the molten silicate glass is suppressed:
SS= p SO 2 /P abs <2.0 (1)
wherein:
SS is a supersaturation degree of SO 2 in the molten glass;
pSO 2 is a partial pressure (Pa) of SO 2 in the molten glass; and
P abs is a pressure (Pa) at the bottom portion of the glass flow passage of the vacuum degassing vessel.
5. The process according to claim 4 , wherein the silicate glass has a composition of SiO 2 ≧50 mol% and (alkali component oxide plus alkaline earth component oxide)≧10 mol%.
6. The process according to claim 4 , wherein the conditions satisfying formula (1) exist between a downstream end of the glass flow passage and a location L/2 from the downstream end of the glass flow passage, wherein L is a length of the glass flow passage in a horizontal direction.
7. A process, comprising;
melting glass materials to obtain a molten silicate glass which comprises a refining agent containing S (sulfur) element, an amount of the refining agent in the molten silicate glass being 0.043 weight % or more as calculated as SO 3 ;
passing the molten silicate glass through a glass flow passage in a vacuum degassing vessel, the interior of which is maintained in a reduced pressure state, to vacuum-degas the molten glass;
forming the vacuum-degassed molten glass in to a formed glass; and
annealing the formed glass;
wherein vacuum-degassing of the molten glass is carried out under conditions satisfying formula (1) at least at a bottom portion on a downstream side of the glass flow passage of the vacuum degassing vessel, such that formation of bubbles at an interface between furnace material of the vacuum degassing vessel and the molten silicate glass is suppressed:
SS= p SO 2 /P abs <2.0 (1)
wherein:
SS is a supersaturation degree of SO 2 in the molten glass;
pSO 2 is a partial pressure (Pa) of SO 2 in the molten glass; and
P abs is a pressure (Pa) at the bottom portion of the glass flow passage of the vacuum degassing vessel.
8. The process according to claim 7 , wherein the silicate glass has a composition of SiO 2 ≧50 mol% and (alkali component oxide plus alkaline earth component oxide)≧10 mol%.
9. The process according to claim 7 , wherein the conditions satisfying formula (1) exist between a downstream end of the glass flow passage and a location L/2 from the downstream end of the glass flow passage, wherein L is a length of the glass flow passage in a horizontal direction.