Method and system to thermally regenerate a sorbent
View Patent ↗The present disclosure is directed to a high temperature method to adsorb carbon dioxide onto an ion-exchange resin and/or regenerate the carbon dioxide-loaded ion-exchange resins.
1. A method, comprising:
contacting an ion-exchange resin with a target component-containing gas stream, wherein the target component-containing gas stream further comprises at least one acid gas, the at least one acid gas being different from the target gas component;
absorbing at least a portion of the target component from the target component-containing gas stream onto the ion-exchange resin at an absorption temperature of at least 20° C. to form a target component-loaded resin, wherein the target component-loaded resin comprises at least one acid gas and/or a salt thereof removed from the target component-containing gas stream;
regenerating the target component loaded resin to form a regenerated ion-exchange resin, wherein the regenerating step comprises;
removing, at a sorbent regeneration temperature of at least about 120° C., at least most of the removed target gas component from the target component-loaded resin to form a lean ion exchange resin, the lean ion exchange resin comprising the at least one acid gas and/or a salt thereof;
contacting the lean ion exchange resin with a regeneration solution to remove, from the lean ion exchange resin, at least most of the at least one acid gas and/or a salt thereof and form the regenerated ion-exchange resin; and
recycling the regenerated ion-exchange resin to the contacting.
2. The method of claim 1 , wherein the target component is carbon dioxide, wherein the acid gas comprises one or more of a sulfur oxide, a nitrogen oxide and hydrogen sulfide, and wherein the ion exchange resin is an amine functionalized ion-exchange resin.
3. The method of claim 2 , wherein the ion-exchange resin is in the form of bead polymers formed of a polystyrene polymer resin comprising primary amines and cross-linked via divinylaromatics or monodisperse or heterodisperse and macroporous or gel-type (microporous) resin.
4. The method of claim 1 , wherein the target component is carbon dioxide, wherein the ion-exchange resin is an amine-based ion-exchange resin, and wherein the absorption temperature is at least about 30° C.
5. The method of claim 4 , wherein the ion-exchange resin is a weakly basic, polystyrene-based ion-exchange resin functionalized with primary amine groups comprising benzylamine, wherein the absorption temperature is at least about 35° C., and wherein the target component is carbon dioxide.
6. The method of claim 5 , wherein the absorption temperature is at least about 40° C.
7. The method of claim 6 , wherein the absorption temperature is at least about 50° C. and wherein the sorbent regeneration temperature is about 140° C. or more.
8. The method of claim 1 , wherein the ion-exchange resin is a weakly basic, polystyrene-based ion-exchange resin functionalized with primary amine groups comprising benzylamine and wherein, in the contacting, the target component-containing gas stream is contacted with a sorbent comprising one or more of activated carbon, zeolite, clay, fly ash, or a metal-containing sorbent, wherein the metal in the metal-containing sorbent is one or more metals from IUPAC Groups 3 through 12 of the Periodic Table of Elements.
9. The method of claim 1 , wherein the target gas component is a carbon oxide, wherein the at least one acid gas is one or more of a sulfur oxide, a nitrogen oxide and hydrogen sulfide, and wherein the regeneration solution has a pH of at least about pH 10.
10. The method of claim 9 , wherein the acid gas comprises SO 2 , wherein the target gas component is CO 2 , wherein the regeneration solution comprises a base, wherein at least most of the CO 2 in the received gas stream is removed by the ion-exchange resin, wherein CO 2 is removed from the target component-loaded ion-exchange resin by a combination of temperature and pressure swing, and wherein the ion-exchange resin is in the form of a solid.
11. The method of claim 1 , wherein bonds between the between adjacent ion-exchange resin components and between the ion-exchange resin component and an adjacent ion-exchange resin substrate are stronger than bonds between the ion-exchange resin component and the target gas component and between the ion-exchange resin component and the at least one acid gas and/or salt thereof and wherein bonds between the between adjacent ion-exchange resin components and between the ion-exchange resin component and an adjacent ion-exchange resin substrate are thermally stable under the temperatures of the contacting and regenerating steps.
12. The method of claim 11 , wherein the regeneration solution does not significantly impact the strengths of the bonds between the between adjacent ion-exchange resin components and between the ion-exchange resin component and an adjacent ion-exchange resin substrate.
13. The method of claim 12 , wherein the regeneration solution comprises a base that is at least one of an alkali or alkaline earth metal carbonate, at least one of an alkali or alkaline earth metal hydroxide, an alkoxide, a metal oxide, ammonia, a metal amine, a carboxylate, a phosphine, an ether, a ketone, an alkene, and CH 3 − .
14. The method of claim 1 , further comprising:
after contact of the lean ion-exchange resin with the regeneration solution, contacting the ion-exchange resin with a wash solution to remove any deposit on the ion-exchange resin after contact with the regeneration solution.
15. A method, comprising:
contacting an ion-exchange resin with a target component-containing gas stream, wherein the ion-exchange resin is an amine-based ion-exchange resin and wherein the target component-containing gas stream further comprises at least one acid gas, the at least one acid gas being different from the target gas component;
absorbing at least a portion of the target component from the target component-containing gas stream onto the ion-exchange resin at an absorption temperature of at least 20° C. to form a target component-loaded resin, wherein the target component-loaded resin comprises at least one acid gas and/or a salt thereof removed from the target component-containing gas stream;
regenerating the target component loaded resin to form a regenerated ion-exchange resin, wherein the regenerating step comprises the sub-steps:
removing, at a sorbent regeneration temperature of at least about 120° C., at least most of the removed target gas component from the target component-loaded ion exchange-resin to form a lean ion-exchange resin, the lean ion-exchange resin comprising the at least one acid gas and/or a salt thereof; and
contacting the lean ion-exchange resin with a regeneration solution to remove, from the lean ion-exchange resin, at least most of the at least one acid gas and/or a salt thereof and form the regenerated ion-exchange resin; and
recycling the regenerated ion-exchange resin to the ion-exchange resin contacting step.
16. The method of claim 15 , wherein the target component is carbon dioxide, wherein the acid gas comprises one or more of a sulfur oxide, a nitrogen oxide and hydrogen sulfide, and wherein the ion exchange resin is an amine functionalized ion-exchange resin.
17. The method of claim 16 , wherein the ion-exchange resin is in the form of bead polymers formed of a polystyrene polymer resin comprising primary amines and cross-linked via divinylaromatics or monodisperse or heterodisperse and macroporous or gel-type (microporous) resin, and wherein the sorbent regeneration temperature is at least about 140° C.
18. The method of claim 15 , wherein the target component is carbon dioxide, and wherein the absorption temperature is at least about 30° C. and wherein the sorbent regeneration temperature is more than about 160° C.
19. The method of claim 18 , wherein the ion-exchange resin is a weakly basic, polystyrene-based ion-exchange resin functionalized with primary amine groups comprising benzylamine, wherein the absorption temperature is at least about 35° C., and wherein the target component is carbon dioxide.
20. The method of claim 19 , wherein the absorption temperature is at least about 40° C.
21. The method of claim 20 , wherein the absorption temperature is at least about 50° C. and wherein the sorbent regeneration temperature is about 140° C. or more.
22. The method of claim 15 , wherein the ion-exchange resin is a weakly basic, polystyrene-based ion-exchange resin functionalized with primary amine groups comprising benzylamine and wherein, in the contacting step, the target component-containing gas stream is contacted with a sorbent comprising one or more of activated carbon, zeolite, clay, fly ash, or a metal-containing sorbent, wherein the metal in the metal-containing sorbent is one or more metals from IUPAC Groups 3 through 12 of the Periodic Table of Elements.
23. The method of claim 15 , wherein the target gas component is a carbon oxide, wherein the at least one acid gas is one or more of a sulfur oxide, a nitrogen oxide and hydrogen sulfide, and wherein the regeneration solution has a pH of at least about pH 10.
24. The method of claim 23 , wherein the acid gas comprises SO 2 , wherein the target gas component is CO 2 , wherein the regeneration solution comprises a base, wherein at least most of the CO 2 in the received gas stream is removed by the ion exchange resin, wherein CO 2 is removed from the target component-loaded ion-exchange resin by a combination of temperature and pressure swing, and wherein the ion-exchange resin is in the form of a solid.
25. The method of claim 15 , wherein bonds between the between adjacent ion-exchange resin components and between the ion-exchange resin component and an adjacent ion-exchange resin substrate are stronger than bonds between the ion-exchange resin component and the target gas component and between the ion-exchange resin component and the at least one acid gas and/or salt thereof and wherein bonds between the between adjacent ion-exchange resin components and between the ion-exchange resin component and an adjacent ion-exchange resin substrate are thermally stable under the temperatures of the contacting and regenerating steps.
26. The method of claim 25 , wherein the regeneration solution does not significantly impact the strengths of the bonds between the between adjacent ion-exchange resin components and between the ion-exchange resin component and an adjacent ion-exchange resin substrate.
27. The method of claim 26 , wherein the regeneration solution comprises a base that is at least one of an alkali or alkaline earth metal carbonate, at least one of an alkali or alkaline earth metal hydroxide, an alkoxide, a metal oxide, ammonia, a metal amine, a carboxylate, a phosphine, an ether, a ketone, an alkene, and CH 3 − .
28. The method of claim 15 , further comprising:
after contact of the lean ion-exchange resin with the regeneration solution, contacting the ion-exchange resin with a wash solution to remove any deposit on the ion-exchange resin after contact with the regeneration solution.
29. A method, comprising:
contacting an ion-exchange resin with a target component-containing gas stream, wherein the ion-exchange resin is an amine-based ion-exchange resin, wherein the ion exchange resin is in the form of bead polymers formed of a polystyrene polymer resin comprising primary amines and cross-linked via divinylaromatics or monodisperse or heterodisperse and macroporous or gel-type (microporous) resin, and wherein the target component-containing gas stream further comprises at least one acid gas, the at least one acid gas being different from the target gas component;
absorbing at least a portion of the target component from the target component-containing gas stream onto the ion-exchange resin at an absorption temperature of at least 20° C. to form a target component-loaded resin, wherein the target component-loaded resin comprises at least one acid gas and/or a salt thereof removed from the target component-containing gas stream;
regenerating the target component-loaded resin by removing, from the target component-loaded resin, the target component while leaving the at least one acid gas and/or salt thereof on the resin, at a sorbent regeneration temperature of at least about 120° C. to form a lean ion-exchange resin, the lean ion-exchange resin comprising the at least one acid gas and/or a salt thereof;
contacting the lean ion-exchange resin with a regeneration solution to remove, from the lean ion-exchange resin, at least most of the at least one acid gas and/or a salt thereof and form a regenerated ion-exchange resin;
after contact of the lean ion-exchange resin with the regeneration solution, contacting the regenerated ion-exchange resin with a wash solution to remove any deposit on the regenerated ion-exchange resin after contact with the regeneration solution; and
recycling the regenerated ion-exchange resin to the step of contacting the ion-exchange resin with the target component-containing gas stream.