Detection apparatus and methods utilizing ion mobility spectrometry
A method of and system for analyzing ion mobility of a sample. The sample is received by an ionization chamber, which ionizes molecules of the sample. The ionized sample is received from the ionization chamber by a drift tube coupled to the ionization chamber and propelled along a length of the drift tube in a first direction away from the ionization chamber by an electric field gradient of the drift tube. A magnitude of the electric field gradient is in view of an atmospheric pressure measurement. A drift gas is propelled through the drift tube in a second direction opposite the first direction such that different types of ionized molecules travel through the drift tube at different rates. An arrival time of each of the different types of molecules at a detector located at a second end of the drift tube opposite the first end is detected.
1. An apparatus for analyzing a sample, the apparatus comprising:
an ionization chamber that receives and ionizes molecules of the sample;
a drift tube coupled to the ionization chamber at a first end of the drift tube that receives the sample from the ionization chamber, the drift tube having an electric field gradient along a length of the drift tube that propels the sample in a first direction away from the ionization chamber, wherein a magnitude of the electric field gradient is in view of an atmospheric pressure measurement;
a drift gas supply coupled to the drift tube that propels a drift gas through the drift tube in a second direction opposite the first direction such that different types of the ionized molecules of the sample travel through the drift tube at different rates; and
a detector at a second end of the drift tube opposite the first end that detects an arrival time of each of the different types of the ionized molecules.
2. The apparatus of claim 1 further comprising a suction device coupled to the ionization chamber that draws the sample into the ionization chamber.
3. The apparatus of claim 1 further comprising a gate between the ionization chamber and the drift tube to maintain the sample in the ionization chamber until the gate is opened when a measurement cycle is initiated.
4. The apparatus of claim 3 , wherein the ionization chamber and the gate have a substantially similar electrical potential until a measurement cycle is initiated and an electrical potential of the ionization chamber is pulsed to propel the ionized sample into the drift tube.
5. The apparatus of claim 1 , wherein the drift tube comprises glass.
6. The apparatus of claim 1 , wherein the detector is a Faraday plate collector.
7. The apparatus of claim 1 further comprising a focusing ring located between the drift tube and the detector that directs the ionized molecules towards the detector.
8. The apparatus of claim 7 , wherein the detector comprises a pin collector, and wherein the focusing ring directs the ionized molecules towards the pin collector.
9. The apparatus of claim 1 further comprising a heated port coupled to the ionization chamber, where the heated port receives sample particulate on a sampling screen and desorbs the sample particulate from the sampling screen into the ionization chamber.
10. A method of analyzing a sample, the method comprising:
receiving the sample by an ionization chamber;
ionizing molecules of the sample by the ionization chamber;
receiving the sample from the ionization chamber by a drift tube coupled at a first end to the ionization chamber;
propelling the sample along a length of the drift tube in a first direction away from the ionization chamber by an electric field gradient of the drift tube, wherein a magnitude of the electric field gradient is in view of an atmospheric pressure measurement;
propelling a drift gas from a drift gas supply coupled to the drift tube through the drift tube in a second direction opposite the first direction such that different types of the ionized molecules of the sample travel through the drift tube at different rates; and
detecting an arrival time of each of the different types of the ionized molecules at a detector located at a second end of the drift tube opposite the first end.
11. The method of claim 10 further comprising drawing the sample into the ionization chamber via a suction device.
12. The method of claim 10 further comprising maintaining the sample in the ionization chamber via a gate until the gate is opened when a measurement cycle is initiated.
13. The method of claim 12 further comprising:
maintaining the ionization chamber and the gate at a substantially similar electrical potential; and
upon initiation of a measurement cycle, pulsing the electrical potential of the ionization chamber to propel the sample into the drift tube.
14. The method of claim 10 , wherein the drift tube comprises glass.
15. The method of claim 10 , wherein the detector is a Faraday plate collector.
16. The method of claim 10 further comprising directing the ionized molecules towards the detector via a focusing ring.
17. The method of claim 16 , wherein the detector comprises a pin collector, and wherein the focusing ring directs ionized molecules towards the pin collector.
18. The method of claim 10 further comprising:
receiving sample particulate on a sampling screen by a heated port; and
desorbing the sample particulate from the sampling screen into the ionization chamber.
19. The method of claim 10 , wherein ionizing the molecules of the sample comprises exposing the molecules of the sample to a radioactive source having radioactivity in a range from about 100 microcurie to about 1000 microcurie.