System and method for purifying process water produced from biomass conversion to fuels
View Patent ↗In accordance with one embodiment, a process is described for a water treatment process in which water produced from a fuel production process is treated with recycled biochar. In accordance with one aspect, process water is passed through activated carbon generated by the biomass pyrolysis and gasification. In accordance with another aspect, the process water is treated to expel gaseous compounds within the process water. In this manner both inorganics, light organics and heavy organics can be removed from the process water. No fermentation is involved.
1. A method for removing contaminants from process water produced during biomass conversion to fuels comprising:
pyrolyzing biomass to produce gaseous compounds and biochar;
gasifying the biochar from the pyrolysis process to create an adsorptive medium;
passing the gaseous compounds to a fuel production process to create fuel and process water, wherein the process water contains one or more of organic contaminants, inorganic contaminants or particulate contaminants; and
treating the resulting process water by passing the process water through the adsorptive medium to remove one or more of organic contaminants, inorganic contaminants or particulate contaminants to produce treated process water.
2. The method of claim 1 further comprising gasifying organic contaminants adsorbed on the adsorptive medium.
3. The method of claim 2 wherein the gaseous compounds and biochar resulting from the pyrolyzing step are substantially uncontaminated.
4. The method of claim 2 wherein the minerals content of the biochar in the adsorptive medium increases after gasifying organic contaminants adsorbed on the adsorptive medium.
5. The method of claim 1 wherein the biomass is pyrolyzed in a pyrolysis reactor selected from the group consisting of fixed bed reactors, fluidized bed reactors, circulating bed reactors, bubbling fluid bed reactors, vacuum moving bed reactors, entrained flow reactors, cyclonic or vortex reactors, rotating cone reactors, auger reactors, ablative reactors, microwave or plasma assisted pyrolysis reactors, and vacuum moving bed reactors.
6. The method of claim 1 wherein the biomass is provided as thin sheets.
7. The method of claim 6 wherein the biomass is pyrolyzed by applying pressure shocks and temperature ramps to the thin sheets of biomass.
8. The method of claim 1 wherein the treated process water contains less than 1% hydrocarbons.
9. The method of claim 8 wherein the treated process water contains less than 1% aromatic hydrocarbons.
10. The method of claim 9 wherein the treated process water contains less than 100 ppm aromatic hydrocarbons.
11. The method of claim 10 wherein the treated process water contains less than 1 ppm aromatic hydrocarbons.
12. The method of claim 1 wherein the process water is contaminated with inorganic compounds.
13. The method of claim 1 wherein the adsorptive medium is activated in situ.
14. The method of claim 1 wherein the adsorptive medium comprises biochar having a surface area varying from 0.1 m 2 /g to 500 m 2 /g.
15. The method of claim 1 wherein waste heat from pyrolyzing the biomass is used in the step of treating the process water.
16. A biochar recycling system for treatment of water produced from biomass conversion to fuels comprising:
a pyrolyzer capable of pyrolyzing biomass to produce gaseous compounds and biochar;
a converter for converting the gaseous compounds to fuels via catalytic conversion and producing process water;
a water treatment system for removing impurities from the process water; and
a gasification system for gasifying the removed impurities.
17. The system according to claim 16 wherein the water treatment system comprises an adsorptive medium comprising biochar derived from gasification.
18. The system according to claim 16 wherein the water treatment system comprises a heating device capable of increasing the temperature of the process water to remove light organic impurities.
19. The system according to claim 16 wherein the gaseous compounds and biochar exit the pyrolyzer in substantially uncontaminated form.
20. The system according to claim 16 wherein the biochar produced by the system has a surface area varying from 0.1 m 2 /g to 500 m 2 /g.
21. The system according to claim 16 wherein the process water after treatment contains less than 1% hydrocarbons.
22. The system according to claim 21 wherein the process water after treatment contains less than 1% aromatic hydrocarbons.
23. The system according to claim 22 wherein the process water after treatment contains less than 100 ppm aromatic hydrocarbons.
24. The system according to claim 23 wherein the process water after treatment contains less than 1 ppm aromatic hydrocarbons.
25. The system according to claim 16 wherein the process water before treatment is contaminated with inorganic compounds.
26. The system according to claim 17 wherein the adsorptive medium is activated in situ.
27. The system according to claim 16 wherein the gasification system decomposes adsorbed contaminants in the process water.
28. The system according to claim 18 wherein the light organic impurities are directed to the gasifier.