Selective catalyst reduction filter washcoat thickness ammonia compensation system

1. An exhaust treatment system, comprising:

a selective catalyst reduction filter (SCRF) device, the SCRF device including a filter portion having a washcoat disposed thereon defining a washcoat thickness (WCT);

a reductant delivery system configured to inject a reductant that reacts with the washcoat;

at least one pressure sensor that determines a pressure differential across the SCRF;

a reductant storage module including an electronic processor that executes instructions stored in memory, the reductant storage module in electrical communication with the reductant delivery system and configured to determine a reductant setpoint that controls an amount of reductant injected from the reductant delivery system; and

a WCT compensation module including an electronic processor that executes instructions stored in memory, the WCT compensation module in electrical communication with the reductant storage module, the WCT compensation module configured to determine a WCT compensation value based the WCT and to electrically communicate a WCT compensation value to the reductant storage module to control the amount of reductant injected from the reductant delivery system, wherein the WCT is based on a the pressure differential indicated by a pressure signal output by the at least one pressure sensor.

2. The exhaust treatment system of claim 1 , further comprising a WCT module that determines the WCT based on the pressure differential across the SCRF, wherein the reductant storage module adjusts the reductant setpoint according to the WCT compensation value.

3. The exhaust treatment system of claim 2 , wherein the WCT compensation module determines the WCT compensation value based on a comparison between the WCT and a nominal WCT value stored in a memory device.

4. The exhaust treatment system of claim 3 , wherein the reductant setpoint is based on a reductant storage model stored in the memory device and indicates a target storage level of the SCRF device.

5. The exhaust treatment system of claim 4 , wherein the reductant storage model is based on a temperature of the SCRF device and an exhaust mass flow rate of exhaust gas flowing through the exhaust treatment system.

6. The exhaust treatment system of claim 5 , wherein reductant storage module further adjusts the reductant setpoint based on an age of the SCRF device.

7. The exhaust treatment system of claim 6 , wherein the reductant setpoint is adjusted from a first setpoint to a second setpoint different from the first setpoint, the second setpoint minimizing the amount of reductant that slips from the SCRF device with respect to the first setpoint.

8. A control module including an electronic processor that executes instructions stored in memory, the electronic processor configured to control an injector to inject a reductant that reacts with a washcoat disposed on a SCRF device, the control module comprising:

a reductant control module including an electronic processor that executes instructions stored in memory, the reductant control module configured to inject reductant according to an initial setpoint that indicates a target storage level of the SCRF device;

a reduction storage module including an electronic processor that executes instructions stored in a memory device, the reduction storage module configured to determine the initial setpoint based on a reductant storage model stored in the memory device; and

a washcoat thickness (WCT) compensation module including an electronic processor that executes instructions stored in memory, the WCT compensation module configured to compare a thickness of the washcoat disposed on the SCRF device with a nominal washcoat thickness value stored in the memory device, and to generate a WCT compensation value based on the comparison, the thickness of the washcoat based on a pressure differential indicated by a pressure signal output by at least one pressure sensor,

wherein the reductant storage module is in electrical communication with the WCT compensation module and adjusts the initial setpoint based on the WCT compensation value to generate a new setpoint different from the initial setpoint.

9. The control module of claim 8 , wherein the new setpoint reduces the amount of reductant that slips from the SCRF device with respect to the initial setpoint.

10. The control module of claim 9 , further comprising a WCT module including an electronic processor that executes instructions stored in memory, the WCT module in electrical communication with the WCT compensation module and the at least one pressure sensor, the WCT module configured to determine the thickness of the washcoat based on the pressure differential across the SCRF.

11. The control module of claim 10 , wherein the reductant storage model is based on a temperature of the SCRF device and an exhaust gas mass flow rate realized by the SCRF device.

12. A method of controlling an exhaust treatment system, the method comprising:

determining a setpoint corresponding to a reductant delivery model that controls an amount of reductant injected from a reductant delivery system;

determining a pressure differential across an SCRF device using at least one pressure sensor, and determining the thickness of the washcoat based on the pressure differential;

determining a thickness of a washcoat disposed on the SCRF device included in the exhaust treatment system, the thickness of the washcoat determined using a washcoat thickness WCT module including an electronic processor that executes instructions stored in memory;

comparing the thickness of the washcoat to a nominal WCT value stored in an electronic memory device;

adjusting the setpoint according to the WCT compensation value to generate a new setpoint that minimizes an amount of ammonia that slips from the SCRF device; and

injecting the reductant from the reductant delivery system based on the new setpoint.

13. The method of claim 12 , further comprising determining the reductant storage model based on a temperature of the SCRF device and an exhaust mass flow rate of exhaust gas flowing through the exhaust treatment system.

14. The method of claim 13 , further comprising generating the new setpoint based on an age of the SCRF device.