Curable latex inks comprising an unsaturated polyester for indirect printing
View Patent ↗The present disclosure provides an ink comprising a latex comprising a photoinitiator and at least one unsaturated polyester, which is suitable for use in an indirect printing method.
1. An ink for use in an indirect printing process comprising:
water;
a water-miscible organic solvent, wherein the water to water-miscible organic solvent is from about 97:3 to about 40:60, further wherein the total amount of water and water-miscible organic solvent is from about 75 to about 97 percent by weight based on the total weight of the ink;
a colorant having an average particle size of from about 20 to about 500 nm; and
a latex comprising at least one unsaturated polyester and a photoinitiator, wherein the at least one unsaturated polyester has an acid value in the range of from 9 to 13; wherein the at least one unsaturated polyester comprises at least a first residue of a diacid or diester monomer, and a second residue of a diol monomer, the unsaturated polyester being prepared by reacting the first residue of a diacid or diester monomer and the second residue of a diol monomer;
wherein the diacid monomer is selected from the group consisting of fumaric acid, maleic acid, itaconic acid, and mixtures thereof, wherein the diester monomer is selected from the group consisting of dimethyl fumarate, dimethyl itaconate, cis-1,4-diacetoxy-2-butene, diethyl fumarate, diethyl maleate, and mixtures thereof, and further the diol monomer is selected from the group consisting of propoxylated bisphenol A, butoxylated bisphenol A, ethoxylated bisphenol A, 1,2-propanediol, and mixtures thereof,
wherein the ink has a surface tension of from about 15 to about 50 dynes/cm at the jetting temperature, and a viscosity of from about 2 centipoise to about 20 centipoise at the jetting temperature.
2. The ink of claim 1 , wherein either one or both of the first residue of a diacid or diester monomer and the second residue of a diol monomer comprises an unsaturated moiety.
3. The ink of claim 1 , wherein the at least one unsaturated polyester comprises an amorphous polyester.
4. The ink of claim 1 , wherein the at least one unsaturated polyester has a weight average molecular weight of from about 5,000 g/mol to about 40,000 g/mol.
5. The ink of claim 1 , wherein the at least one unsaturated polyester has a glass transition point of from about 45° C. to about 70° C.
6. The ink of claim 1 , wherein the at least one unsaturated polyester has an average particle size of from about 50 nm to about 600 nm.
7. The ink of claim 1 , wherein the at least one unsaturated polyester is present in an amount of from about 1 weight percent to about 20 weight percent based on the total weight of the ink.
8. The ink of claim 1 , wherein the photoinitiator is selected from the group consisting of hydroxyketones, acyl phosphine oxides, benzophenones, phenylglyoxylates and mixtures thereof.
9. The ink of claim 1 , wherein the colorant is selected from the group consisting of pigment, dye, mixtures of pigment and dye, mixtures of pigments, and mixtures of dyes.
10. The ink of claim 1 , wherein the water-miscible organic solvent is selected from the group consisting of sulfolane, methyl ethyl ketone, isopropanol, 2-pyrrolidinone, polyethylene glycol, and mixtures thereof.
11. The ink of claim 1 further comprises sulfolane.
12. An ink for use in an indirect printing process comprising:
water;
a water-miscible organic solvent, wherein the water to water-miscible organic solvent is from about 97:3 to about 40:60, further wherein the total amount of water and water-miscible organic solvent is from about 75 to about 97 percent by weight based on the total weight of the ink;
a colorant having an average particle size of from about 20 to about 500 nm; and
a latex comprising at least one unsaturated polyester and a photoinitiator selected from the group consisting of hydroxyketones, acyl phosphine oxides, benzophenones, phenylglyoxylates and mixtures thereof; and
wherein the at least one unsaturated polyester has an acid value in the range of from 14 to 17; wherein the at least one unsaturated polyester comprises at least a first residue of a diacid or diester monomer, and a second residue of a diol monomer, the at least one unsaturated polyester being prepared by reacting the first residue of a diacid or diester monomer and second residue of a diol monomer; wherein either one or both of the first residue of a diacid or diester monomer and second residue of a diol monomer comprises an unsaturated moiety;
wherein the diacid monomer is selected from the group consisting of fumaric acid, maleic acid, itaconic acid, and mixtures thereof, wherein the diester monomer is selected from the group consisting of dimethyl fumarate, dimethyl itaconate, cis-1,4-diacetoxy-2-butene, diethyl fumarate, diethyl maleate, and mixtures thereof, and further the diol monomer is selected from the group consisting of propoxylated bisphenol A, butoxylated bisphenol A, ethoxylated bisphenol A, 1,2-propanediol, and mixtures thereof.
13. The ink of claim 12 , wherein the diacid monomer comprises fumaric acid.
14. The ink of claim 12 , wherein the diol monomer comprises propoxylated Bisphenol A.
15. The ink of claim 12 , wherein the at least one unsaturated polyester is present in an amount of from about 1 weight percent to about 20 weight percent based on the total weight of the ink.
16. A process comprising:
incorporating an ink, wherein the ink comprises:
water;
a water-miscible organic solvent, wherein the water to water-miscible organic solvent is from about 97:3 to about 40:60, further wherein the total amount of water and water-miscible organic solvent is from about 75 to about 97 percent by weight based on the total weight of the ink;
a colorant having an average particle size of from about 20 to about 500 nm; and
a latex comprising at least one unsaturated polyester and a photoinitiator, wherein the at least one unsaturated polyester has an acid value in the range of from 9 to 13; wherein the at least one unsaturated polyester comprises at least a first residue of a diacid or diester monomer, and a second residue of a diol monomer, the unsaturated polyester being prepared by reacting the first residue of a diacid or diester monomer and the second residue of a diol monomer;
wherein the diacid monomer is selected from the group consisting of fumaric acid, maleic acid, itaconic acid, and mixtures thereof, wherein the diester monomer is selected from the group consisting of dimethyl fumarate, dimethyl itaconate, cis-1,4-diacetoxy-2-butene, diethyl fumarate, diethyl maleate, and mixtures thereof, and further the diol monomer is selected from the group consisting of propoxylated bisphenol A, butoxylated bisphenol A, ethoxylated bisphenol A, 1,2-propanediol, and mixtures thereof,
wherein the ink has a surface tension of from about 15 to about 50 dynes/cm at the jetting temperature, and a viscosity of from about 2 centipoise to about 20 centipoise at the jetting temperature
ejecting droplets of ink in an imagewise pattern onto an intermediate transfer member; and
heating the image to partially or completely remove solvents; optionally partially curing the ink; transferring the ink in the imagewise pattern from the intermediate transfer member to a final recording substrate and curing to a robust final image.