Ammonia recovery device and recovery method
View Patent ↗A method includes a first step of, with a CO 2 .H 2 S stripper maintained to have a pressure higher than atmospheric pressure, from the ammonia-containing wastewater, discharging CO 2 and H 2 S in a form of gas having a low moisture concentration from a tower top of the CO 2 .H 2 S stripper while discharging an ammonia-containing solution from a tower bottom of the CO 2 .H 2 S stripper; a second step of introducing the ammonia-containing solution obtained after the first step into an ammonia stripper which is maintained to have a lower pressure than that of the CO 2 .H 2 S stripper, and thereby discharging a gas rich in ammonia containing a small amount of H 2 S and CO 2 from a tower top of the ammonia stripper while discharging water usable as industrial water from a tower bottom of the ammonia stripper; and a third step of introducing the ammonia rich gas obtained after the second step into a washing tower which is maintained to have a lower pressure than that of the ammonia stripper, and thereby discharging a wastewater containing a Na compound from a tower bottom of the washing tower while discharging a H 2 S-free gas rich in ammonia from a tower top of the washing tower.
1. An ammonia recovery device for recovering ammonia from an ammonia-containing wastewater from a gasification furnace, the ammonia recovery device comprising:
a CO 2 .H 2 S stripper configured for maintaining an inner pressure higher than atmospheric pressure;
an ammonia stripper configured for maintaining an inner pressure lower than that of the CO 2 .H 2 S stripper; and
a washing tower configured for maintaining an inner pressure maintained lower than that of the ammonia stripper; wherein
the CO 2 .H 2 S stripper has:
a tower top portion configured for the discharge of CO 2 and H 2 S gas; and
a tower bottom portion configured for the discharge of a solution containing ammonia;
the ammonia stripper has:
a tower top portion configured for the discharge of a gas rich in ammonia;
a connection to the tower bottom portion of the CO 2 .H 2 S stripper configured for introducing the solution containing ammonia discharged from the CO 2 .H 2 S stripper; and
a tower bottom portion configured for discharging a water reusable as industrial water; and
the washing tower includes:
a water washing tower located above; and
a NaOH washing tower located below which are coupled to each other, the NaOH washing tower has:
a connection to the tower top portion of the ammonia stripper configured for introducing a gas rich in ammonia discharged from the ammonia stripper;
a connecting part to the water washing tower located above the NaOH washing tower configured for sending the gas rich in ammonia after treatment with NaOH in a circulating water to absorb H 2 S and CO 2 ;
a tower bottom portion configured for the discharge of a wastewater containing a Na compound;
a circulation pipe configured for the circulation of a solution from the tower bottom back into the NaOH washing tower by the action of a pump; and
an injection pipe connected to the circulation pipe configured for the injection of NaOH into the NaOH washing tower through the injection pipe, and
the water washing tower has a tower top portion configured for the discharge of a purified gas rich in ammonia after a make-up water is supplied to the gas rich in ammonia sent through the connecting part of the NaOH washing tower so as to wash with the make-up water.