Capacitors having conditioned carbon for electrodes
View Patent ↗There is provided an improvement for capacitors having activated carbon electrodes by the use of an electrolyte solution containing a carbonate of the formula RO(C═O)OR 1 and a conductive salt such as a lithium salt or a quaternary ammonium salt at a concentration of from 0.6 to 3 mol/l.
1. An electrochemical device comprising the combination of a conditioned and heat treated carbon electrode comprised of a metal collector and a layer comprised of activated carbon formed on the metal collector, wherein the activated carbon has been heated after acid washing at a temperature of 1100° C. to 1500° C. under an inert atmosphere and consists essentially of carbon, and an electrolyte solution, the electrolyte solution comprising a non-aqueous solvent system comprising 20 to 100% by weight of one or more symmetrical and/or asymmetrical carbonates of the general formula:
RO(C═O)OR 1
wherein R is selected from the group consisting of methyl, ethyl, isopropyl, propyl, CH 3 OCH 2 CH 2 —, CH 3 OCH 2 CH 2 OCH 2 CH 2 —, CH 3 OCH 2 CH 2 OCH 2 CH 2 OCH 2 CH 2 —, R″OCH 2 CH 2 — and R″—O—(CH 2 ) n —, n is 2, 3 or 4, R 1 is selected from the group consisting of CH 3 OCH 2 CH 2 —, CH 3 OCH 2 CH 2 OCH 2 CH 2 —, CH 3 OCH 2 CH 2 OCH 2 CH 2 OCH 2 CH 2 —, CH 3 CH 2 OCH 2 CH 2 — and R″—O—CH 2 CH 2 —, and R″ is methyl, ethyl, propyl or isopropyl, and a conductive salt which is selected from the group consisting of quaternary ammonium tetrafluoroborates and quaternary ammonium triflates at a concentration of from 0.6 to 3 mol/l.
2. The electrochemical device of claim 1 wherein the non-aqueous solvent system is comprised of at least 20% by weight methyl-(2-methoxyethyl)-carbonate.
3. The electrochemical device of claim 1 wherein the non-aqueous solvent system is comprised of at least 20% by weight bis(2-methoxyethyl) carbonate.
4. The electrochemical device of claim 1 wherein the activated carbon of the carbon electrode has a surface area greater than 1200 m 2 /g.
5. The electrochemical device of claim 1 wherein the conductive salt is selected from the group consisting of tetraethyl ammonium tetrafluoroborate, triethylmethylammonium tetrafluoroborate, diethyldimethylammonium tetrafluoroborate, ethyltrimethylammonium tetrafluoroborate, dimethylpyrrolidinium tetrafluoroborate, diethylpyrrolidinium tetrafluoroborate, ethylmethylpyrrolidinium tetrafluoroborate, and spiro-(1,1 1 )-bipiperidinium tetrafluoroborate, piperidine-1-spiro-1 1 -pyrrolidinium tetrafluoroborate and the triflates thereof.
6. The electrochemical device of claim 1 wherein the carbon after heat treatment has a surface area greater than 1200 m 2 /g.
7. The electrochemical device of claim 1 wherein the non-aqueous solvent system includes a solvent selected from the group consisting of dimethyl carbonate, ethyl methyl carbonate, ethylene carbonate, propylene carbonate and diethyl carbonate.
8. The electrochemical device of claim 1 wherein the electrochemical device is an ultra capacitor.
9. The electrochemical device of claim 1 wherein the electrochemical device is an electrochemical double layer capacitor.
10. The electrochemical device of claim 1 wherein the electrolyte solution has a liquidus range from −70° C. to greater than 150° C.
11. The electrochemical device of claim 1 wherein the non-aqueous solvent system consists of asymmetric methyl-(2-methoxy ethyl)-carbonate.
12. The electrochemical device of claim 1 , wherein the non-aqueous solvent system is comprised of 25 to 75% by weight of one or more symmetrical and/or asymmetrical carbonates of the general formula:
RO(C═O)OR 1
13. The electrochemical device of claim 12 , wherein the non-aqueous solvent system is additionally comprised of ethylene carbonate.