Process for producing polycarbonate compositions
View Patent ↗A method for manufacturing a polycarbonate composition having improved transparency can comprise reacting an aromatic dihydroxy compound and a diaryl carbonate under melt polymerization conditions to provide a polycarbonate; and contacting the polycarbonate with a polydiorgano siloxane having a kinematic viscosity of less than 20 mm 2 /sec at 25° C. as determined in accordance with ASTM D445, and an optional additive thereby making the polycarbonate composition. The polycarbonate composition has haze less than 1% as determined in accordance with ASTM D1003-07, and can be used for optical applications such as automotive headlamps.
1. A method for manufacturing a polycarbonate composition comprising:
reacting an aromatic dihydroxy compound and a diaryl carbonate in the presence of a catalyst to form a polycarbonate; and
adding to the polycarbonate a polydiorgano siloxane having a kinematic viscosity of less than or equal to 20 mm 2 /sec at 25° C. as determined in accordance with ASTM D445, and optionally an additional additive, to form the polycarbonate composition;
wherein the polydiorgano siloxane has a phenyl content;
wherein a 3 mm plaque of the polycarbonate composition has a haze of less than or equal to 1% as determined in accordance with ASTM D1003-07, Procedure A, illuminant CIE-D65; and
wherein the polydiorgano siloxane comprises the formula
CH 3 ((CH 3 ) 2 SiO) n —((C 6 H 5 ) 2 SiO) m —Si(CH 3 ) 3 , wherein a ratio of m/n is 1.0 to 1.6.
2. The method of claim 1 , wherein the polycarbonate composition comprises 0.001 wt % to 5.0 wt % the polydiorgano siloxane, 0.001 wt % to 5.0 wt % UV absorber, 0.001 wt % to 2 wt % heat stabilizer.
3. The method of claim 1 , wherein the polycarbonate composition comprises 0.001 wt % to 2.0 wt % the polydiorgano siloxane, 0.01 wt % to 2.0 wt % UV absorber, 0.001 wt % to 2 wt % heat stabilizer.
4. The method of claim 1 , wherein the polycarbonate composition comprises 0.24 wt % to 0.3 wt % the polydiorgano siloxane.
5. The method of claim 1 , wherein the kinematic viscosity is 15 mm 2 /sec to 20 mm 2 /sec at 25° C.
6. The method of claim 1 , wherein the kinematic viscosity is 16 mm 2 /sec to 19 mm 2 /sec at 25° C.
7. The method of claim 1 , comprising the additional additive, wherein the additional additive is a heat stabilizer, catalyst quencher, UV absorber, coloring agent, plasticizer, lubricant, mold release agent other than polydiorgano siloxanes, or a combination comprising at least one of the foregoing additives.
8. The method of claim 1 , wherein the dihydroxy compound is 1,1-bis(4-hydroxyphenyl)methane, 1,1-bis(4-hydroxyphenyl)ethane, 2,2-bis(4-hydroxyphenyl)propane (BPA), 2,2-bis(4-hydroxyphenyl)butane, 2,2-bis(4-hydroxyphenyl)octane, 1,1-bis(4-hydroxyphenyl)propane, 1,1-bis(4-hydroxyphenyl)n-butane, 2,2-bis(4-hydroxy-2-methylphenyl)propane, 1,1-bis(4-hydroxy-t-butylphenyl)propane, 3,3-bis(4-hydroxyphenyl)phthalimidine, 2-phenyl-3,3-bis(4-hydroxyphenyl)phthalimidine (PPPBP), 1,1-bis(4-hydroxy-3-methylphenyl)cyclohexane (DMBPC), or a combination comprising at least one of the foregoing.
9. The method of claim 1 , wherein the dicarbonate is diphenyl carbonate, bis(4-methylphenyl)carbonate, bis(4-chlorophenyl)carbonate, bis(4-fluorophenyl)carbonate, bis(2-chlorophenyl)carbonate, bis(2,4-difluorophenyl)carbonate, bis(4-nitrophenyl)carbonate, bis(2-nitrophenyl)carbonate, bis(methyl salicyl)carbonate, or a combination comprising at least one of the foregoing.
10. The method of claim 1 , wherein the polycarbonate composition is free of potassium perfluorobutane sulfonate.
11. The method of claim 1 , wherein the polycarbonate composition has a melt volume rate of 3 to 90 cc/10 min, when measured at 300° C. under a load of 1.2 kg according to according to ASTM D1238-04; wherein the polycarbonate composition has an endcap percentage of 65% to 90%; and wherein the polycarbonate composition has a Fries content of 200 ppm to 3000 ppm.
12. The method of claim 1 , wherein the polycarbonate composition has a melt volume rate of 3 to 56 cc/10 min, when measured at 300° C. under a load of 1.2 kg according to according to ASTM D1238-04; wherein the polycarbonate composition has an endcap percentage of 65% to 90%; and wherein the polycarbonate composition has a Fries content of 200 ppm to 2750 ppm.
13. The method of claim 1 , wherein the polycarbonate composition has a melt volume rate of 10 to 35 cc/10 min, when measured at 300° C. under a load of 1.2 kg according to according to ASTM D1238-04; wherein the polycarbonate composition has an endcap percentage of 70% to 85%; and wherein the polycarbonate composition has a Fries content of 300 ppm to 1000 ppm.
14. A polycarbonate composition manufactured by the method of claim 1 .
15. An article of manufacture comprising the polycarbonate composition of claim 14 .
16. The article of claim 15 , wherein the article is a vehicle headlamp.