Procatalyst composition with substituted amide ester internal electron donor
View Patent ↗Disclosed are procatalyst compositions having an internal electron donor which includes a substituted amide ester and optionally an electron donor component. Ziegler-Natta catalyst compositions containing the present procatalyst compositions exhibit improved catalyst activity and/or improved catalyst selectivity and produce propylene-based olefins with broad molecular weight distribution.
1. A procatalyst composition comprising:
a combination of a magnesium moiety, a titanium moiety and an internal electron donor comprising a substituted amide ester having the structure (II):
R 1 -R 6 are the same or different, each of R 1 -R 6 is selected from the group consisting of hydrogen and a hydrocarbyl group having 1-20 carbon atoms,
wherein at least one of R 1 -R 6 is a hydrocarbyl group having at least 2 carbon atoms, or
each of R 3 and R 5 is a hydrocarbyl group having 1-20 carbon atoms; and
R 11 -R 13 and R 21 -R 23 are the same or different, each of R 11 -R 13 and R 21 -R 23 is selected from the group consisting of hydrogen and a hydrocarbyl group having 1-20 carbon atoms.
2. The procatalyst composition of claim 1 wherein at least two of R 1 -R 6 are a hydrocarbyl group having at least 2 carbon atoms.
3. The procatalyst composition of claim 1 wherein each of R 1 and R 2 is a hydrocarbyl group with at least two carbon atoms.
4. The procatalyst composition of claim 1 wherein at least one of R 11 -R 13 and at least one of R 21 -R 23 is a hydrocarbyl group having 1-20 carbon atoms.
5. The procatalyst composition of any of claim 1 wherein each of R 1 and R 2 is are selected from the group consisting of an isopropyl group, an isobutyl group, a sec-butyl group, a cyclopentyl group, and a cyclohexyl group.
6. The procatalyst composition of claim 1 wherein each of R 1 , R 2 , R 4 , and R 6 is hydrogen and each of R 3 and R 5 is a methyl group.
7. A procatalyst composition comprising:
a combination of a magnesium moiety, a titanium moiety and an internal electron donor comprising a substituted amide ester having the structure (II):
wherein R 1 -R 6 , R 11 -R 13 , and R 21 -R 23 are the same or different, each of R 1 -R 6 , R 11 -R 13 , and R 21 -R 23 are is selected from the group consisting of hydrogen and a hydrocarbyl group having 1-20 carbon atoms,
wherein at least one of R 1 -R 6 is a hydrocarbyl group having 1-20 carbon atoms, and at least one of R 11 -R 13 and R 21 -R 23 is a hydrocarbyl group having 1-20 carbon atoms.
8. The procatalyst composition of claim 7 wherein each of R 1 and R 2 is a methyl group and each of R 12 and R 22 is selected from the group consisting of ethyl, butyl, and phenyl.
9. The procatalyst composition of claim 1 comprising a mixed external electron donor comprising the substituted amide ester of structure (II) and an electron donor component.
10. A catalyst composition comprising:
a procatalyst composition of claim 1 ; and
a cocatalyst.
11. The catalyst composition of claim 10 comprising an external electron donor selected from the group consisting of a silicon compound, a bidentate compound, a diether, a diol ester, a carboxylate, an amine, a phosphite, and combinations thereof.
12. The catalyst composition of claim 10 comprising two or more alkoxysilane external electron donors.
13. The catalyst composition of claim 10 comprising an activity limiting agent selected from the group consisting of a carboxylic acid ester, a diether, a diol ester, and combinations thereof.
14. A process for producing an olefin-based polymer comprising:
contacting, under polymerization conditions, an olefin with a catalyst composition comprising a procatalyst of claim 1 ; and
forming an olefin-based polymer comprising a substituted amide ester.
15. The process of claim 14 wherein the olefin is propylene, the process comprising forming a propylene-based polymer having a polydispersity index from about 5.0 to about 20.0.