IP Library Granted Patent US 9,236,545
Granted Patent B2
US 9,236,545 · App. 14/082,266 · Granted Jan 12, 2016

Hybrid metallization on plastic for a light emitting diode (LED) lighting system

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Quick Facts
Patent No.
US 9,236,545
App. No.
14/082,266
Granted
Jan 12, 2016
Kind
B2
Abstract

Provided is a multi-layer reflective coating for application to a lighting housing assembly, including a polymer substrate adjacent a polymer base coat layer applied to the lighting housing. Atop the polymer base coat layer is an aluminum adhesion layer, followed by a diffusive barrier layer, and a silver reflective layer. The aluminum adhesion layer promotes adhesion between the polymer base coat layer and the silver reflective layer. The diffusive barrier layer prevents aluminum and silver interaction, which could form a silver and aluminum alloy. A spectrum tunable layer is applied atop the silver reflective layer for spectrum tuning the silver reflective layer for maximum compatibility with a light emitting diode (LED) lighting source.

Claims (32)

1. A multi-layer reflective coating for application to a lighting housing assembly, comprising:

an aluminum adhesion promotion layer applied atop a polymer base coat layer, wherein the aluminum adhesion promotion layer comprises a 1-10 nanometer (nm) thick Aluminum (Al) film;

a diffusive barrier layer applied atop the aluminum adhesion promotion layer, wherein the diffusive barrier layer comprises a 50-100 nm thick film of NiCr or Ni and Cr;

a reflective layer applied atop the diffusive barrier layer, wherein the reflective layer comprises 100-400 nm thick silver (Ag) film;

wherein the aluminum adhesion promotion layer promotes adhesion between the polymer base coat layer and the reflective layer; and

a spectrum tunable layer applied atop the reflective layer for spectrum tuning the reflective layer to be used with a light emitting diode lighting source.

2. The multi-layer reflective coating of claim 1 , further comprising a polymer substrate layer below the polymer base coat layer, wherein the polymer substrate layer comprises a ultra-violet cured polyimide that can be applied to plastic, glass or metal.

3. The multi-layer reflective coating of claim 1 , wherein the diffusive barrier layer is applied atop the aluminum adhesion promotion layer for preventing the formation of an Al2Ag alloy due to the migration of atoms from the aluminum adhesion layer with atoms from the silver film of the reflective layer.

4. The multi-layer reflective coating of claim 1 , wherein the spectrum tunable layer comprises a 100-300 nm metal oxide based film.

5. The multi-layer reflective coating of claim 4 , wherein the metal oxide based film is selected from a group comprising Titanium Oxide (TiO2), Silicon Dioxide (SiO2) or Tantalum Pentoxide (Ta2O5) or combination of these metal oxide films.

6. The multi-layer reflective coating of claim 1 , wherein a protective top layer comprising a transparent organic or inorganic-organic hybrid coating is applied atop the spectrum turntable layer as well as the combined previous layers as a protective coating.

7. A method of creating a multi-layer reflective coating, the method comprising:

applying an aluminum adhesion promotion layer atop a polymer base coat layer, wherein the aluminum adhesion promotion layer comprises a 1-10 nanometer (nm) thick Aluminum (Al) film,

applying a diffusive barrier layer atop the aluminum adhesion promotion layer,

wherein the diffusive barrier layer comprises a 50-100 nm thick film of NiCr or Ni and Cr;

applying a reflective layer applied atop the diffusive barrier layer, wherein the reflective layer comprises 200-400 nm thick Silver (Ag) film;

wherein the aluminum adhesion promotion layer promotes adhesion between the polymer base coat layer and the reflective layer; and

applying a spectrum tunable layer atop the reflective layer for spectrum tuning the reflective layer to be used with a Light Emitting Diode lighting source.

8. The method of creating a multi-layer reflective coating of claim 7 , further comprising a polymer substrate layer below the polymer base coat layer, wherein the polymer substrate layer comprises a ultra-violet cured polyimide that can be applied to plastic, glass or metal.

9. The method of creating a multi-layer reflective coating of claim 7 , wherein the diffusive barrier layer is applied atop the aluminum adhesion promotion layer for preventing the formation of an Al2Ag alloy due to the migration of atoms from the aluminum adhesion layer with silver atoms forming the reflective layer.

10. The method of creating a multi-layer reflective coating of claim 7 , wherein the spectrum tunable layer comprises a 100-300 nm thick metal oxide based film, the metal oxide based film is selected from a group comprising Titanium Oxide (TiO2), Silicon Dioxide (SiO2) or Tantalum Pentoxide (Ta2O5) or combination of these metal oxide films.

11. The method of creating a multi-layer reflective coating of claim 7 , wherein the spectrum tunable layer comprises a 100-300 nm thick silicon nitride, or any other kind of nitride, fluoride, or sulfide, or combination of these metal oxide films.

12. The method of creating a multi-layer reflective coating of claim 10 or 11 , wherein the spectrum tunable layer serves also as protective layer for the silver reflective layer.

13. The method of creating a multi-layer reflective coating of claim 7 , wherein a protective top layer comprising a transparent organic or inorganic-organic hybrid coating is applied atop the spectrum turntable layer as well as the combined previous layers as a protective coating.

14. A method of creating a multi-layer reflective coating for a light emitting diode housing assembly, the method comprising:

vacuum coating an aluminum adhesion promotion layer atop a polymer base coat layer, wherein the aluminum adhesion promotion layer comprises a 1-10 nanometer (nm) thick Aluminum (Al) film;

vacuum coating a diffusive barrier layer atop the aluminum adhesion promotion layer,

wherein the diffusive barrier layer comprises a 50-100 nm thick film of NiCr or Ni and Cr;

using vacuum deposition to deposit a silver reflective layer atop the diffusive barrier layer, wherein the silver reflective layer comprises 200-400 nm thick Silver (Ag) film;

wherein the aluminum adhesion promotion layer promotes adhesion between the polymer base coat layer and a silver reflective layer; and

wherein the diffusive barrier layer is applied atop the aluminum adhesion promotion layer for preventing the formation of an Al2Ag alloy due to the migration of atoms between the aluminum adhesion layer and the silver reflective layer; and

vacuum coating a spectrum tunable layer applied atop the silver reflective layer for spectrum tuning the silver reflective layer to be used with a Light Emitting Diode lighting source.

Assignments (6)
CORRECTIVE ASSIGNMENT TO CORRECT THE PATENT NUMBER PREVIOUSLY RECORDED AT REEL: 059034 FRAME: 0469. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY INTEREST. Recorded Jan 25, 2024
From: HUBBELL LIGHTING, INC.; LITECONTROL CORPORATION; CURRENT LIGHTING SOLUTIONS, LLC; DAINTREE NETWORKS INC.; FORUM, INC.
To: ATLANTIC PARK STRATEGIC CAPITAL FUND, L.P., AS COLLATERAL AGENT
Reel/Frame 066372/0590 →
CORRECTIVE ASSIGNMENT TO CORRECT THE PATENT NUMBER 10841994 TO PATENT NUMBER 11570872 PREVIOUSLY RECORDED ON REEL 058982 FRAME 0844. ASSIGNOR(S) HEREBY CONFIRMS THE SECURITY AGREEMENT. Recorded Jan 19, 2024
From: HUBBELL LIGHTING, INC.; LITECONTROL CORPORATION; CURRENT LIGHTING SOLUTIONS, LLC; DAINTREE NETWORKS INC.; FORUM, INC.
To: ALLY BANK, AS COLLATERAL AGENT
Reel/Frame 066355/0455 →
SECURITY INTEREST Recorded Feb 11, 2022
From: HUBBELL LIGHTING, INC.; LITECONTROL CORPORATION; CURRENT LIGHTING SOLUTIONS, LLC; DAINTREE NETWORKS INC.; FORUM, INC.
To: ATLANTIC PARK STRATEGIC CAPITAL FUND, L.P., AS COLLATERAL AGENT
Reel/Frame 059034/0469 →
SECURITY AGREEMENT Recorded Feb 2, 2022
From: HUBBELL LIGHTING, INC.; LITECONTROL CORPORATION; CURRENT LIGHTING SOLUTIONS, LLC; DAINTREE NEETWORKS INC.; FORUM, INC.
To: ALLY BANK, AS COLLATERAL AGENT
Reel/Frame 058982/0844 →
CHANGE OF NAME Recorded Apr 9, 2019
From: GE LIGHTING SOLUTIONS, LLC
To: CURRENT LIGHTING SOLUTIONS, LLC
Reel/Frame 048830/0564 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 18, 2013
From: CAI, DENGKE; SMITH, GABRIEL MICHAEL; LOU, XIAOMEI; SAHA, BABI; MAYER, MARK J; BROWN, PETER W; ZHAO, TIANJI
To: GE LIGHTING SOLUTIONS LLC
Reel/Frame 031618/0868 →