On-board catalyst health monitoring and control system adaptation in internal combustion engines

1. A catalyst deterioration detection system comprising:

a pre-catalytic converter gas sensor;

a post-catalytic converter gas sensor;

at least one computing device in communication with the pre-catalytic converter and post-catalytic converter gas sensors, the at least one computing device programmed to monitor catalyst deterioration by performing actions including:

estimating a catalyst gas storage level by comparing a difference between a pre-catalytic converter gas level from the pre-catalytic converter gas sensor and a post-catalytic converter gas level from the post-catalytic converter gas sensor;

comparing the estimated catalyst gas storage level to a baseline catalyst gas storage level; and

determining that the catalyst is deteriorated in response to the baseline catalyst gas storage level exceeding the estimated gas storage level by a threshold difference.

2. The catalyst deterioration detection system of claim 1 , further comprising:

a fault indicator designed to signal that the catalyst is deteriorated in response to the determining that the catalyst is deteriorated.

3. The catalyst deterioration detection system of claim 1 , wherein the catalyst deterioration detection system is a three-way catalytic converter system for use with a three-way catalytic converter,

wherein the pre-catalytic converter gas sensor includes an oxygen sensor and the post-catalytic converter gas sensor includes an oxygen sensor,

wherein the pre-catalytic converter gas level includes a pre-catalytic converter oxygen level,

wherein the post-catalytic converter gas level includes a post-catalytic converter oxygen level,

wherein the estimated catalyst gas storage level includes an estimated catalyst oxygen storage level, and

wherein the baseline catalyst gas storage level includes a baseline catalyst oxygen storage level.

4. The catalyst deterioration detection system of claim 3 , wherein the at lease one computing device is further programmed to perform actions including:

estimating a carbon monoxide (CO) emissions level based on the estimated catalyst oxygen storage level; and

wherein the determining that the catalyst is deteriorated is performed in response to both the reference catalyst oxygen storage level exceeding the baseline catalyst oxygen storage level by a threshold difference and the estimated CO emissions level exceeding a reference CO emissions level by a second threshold difference.

5. The catalyst deterioration detection system of claim 1 , wherein the threshold difference is exceeded when there is at least a ten percent difference between the baseline catalyst gas storage level and the estimated catalyst gas storage level.

6. The catalyst deterioration detection system of claim 1 , wherein the baseline catalyst gas storage level is a catalyst gas storage level for one of a new catalyst or a degreened catalyst.

7. The catalyst deterioration detection system of claim 1 , wherein the at least one computing device is further programmed to perform processes including:

providing an instruction to a control unit to adapt an air flow ratio of an engine in response to a deviation in the catalyst deterioration level.

8. The catalyst deterioration detection system of claim 1 , wherein the estimating of the catalyst gas storage level is performed over a period of time using a plurality of differences between respective pre-catalytic converter gas levels and post-catalytic converter gas level levels.

9. The catalyst deterioration detection system of claim 1 , further comprising:

a model-based urea injection control system,

wherein the catalyst deterioration detection system is a selective catalytic reduction (SCR) catalytic converter system for use with an SCR catalytic converter,

wherein the pre-catalytic converter gas sensor includes a nitrogen oxide (NOx) sensor and the post-catalytic converter gas sensor includes a NOx sensor,

wherein the pre-catalytic converter gas level includes a pre-catalytic converter NOx level,

and wherein the post-catalytic converter gas level includes a post-catalytic converter NOx level,

wherein the estimated catalyst gas storage level includes an estimated catalyst NOx storage level, and

wherein the baseline catalyst gas storage level includes a baseline catalyst NOx storage level; and

wherein the at least one computing device is further programmed to perform actions including:

estimating a catalyst ammonia (NH3) storage level by analyzing the pre-catalytic converter NOx level and the post-catalytic converter NOx level; and

determining a NOx emission level by comparing the pre-catalytic converter NOx level to the post-catalytic converter NOx level,

wherein the determining that the catalyst is deteriorated is performed in response to both the determined catalyst NOx emissions exceeding the baseline NOx emissions level by a threshold difference and a baseline catalyst NH3 storage level exceeding the estimated catalyst NH3 storage level by a second threshold difference.

10. The catalyst deterioration detection system of claim 1 , further comprising:

a model-based urea injection control system,

wherein the catalyst deterioration detection system is a selective catalytic reduction (SCR) catalytic converter system for use with an SCR catalytic converter,

wherein the pre-catalytic converter gas sensor includes an ammonia (NH3) sensor and the post-catalytic converter gas sensor includes an NH3 sensor,

wherein the pre-catalytic converter gas level includes a pre-catalytic converter NH3 level,

wherein the post-catalytic converter gas level includes a post-catalytic converter NH3 level,

wherein the estimated catalyst gas storage level includes an estimated catalyst NH3 storage level,

wherein the baseline catalyst gas storage level includes a baseline catalyst NH3 storage level, and

wherein the at least one computing device is further programmed to perform actions including:

estimating a NOx emissions level by analyzing the pre-catalytic converter NH3 level and the post-catalytic converter NH3 level,

estimating an NH3 storage level by comparing the pre-catalytic converter NH3 level with the post-catalytic converter NH3 level, and

wherein the determining that the catalyst is deteriorated is performed in response to both the estimated NOx emissions level exceeding the baseline catalyst NOx storage level by a threshold difference and a baseline catalyst NH3 storage level exceeding the estimated catalyst NH3 storage level by a second threshold difference.

11. The catalyst deterioration detection system of claim 1 , further comprising:

a model-based urea injection control system,

wherein the catalyst deterioration detection system is a selective catalytic reduction (SCR) catalytic converter system for use with an SCR catalytic converter,

wherein the pre-catalytic converter gas sensor includes a nitrogen oxide (NOx) sensor and the post-catalytic converter gas sensor includes a NOx sensor and an ammonia (NH3) sensor,

wherein the pre-catalytic converter gas level includes a pre-catalytic converter NOx level,

wherein the post-catalytic converter gas level includes a post-catalytic converter NOx level and a post-catalytic converter NH3 level,

wherein the estimated catalyst gas storage level includes an estimated catalyst NOx storage level,

wherein the baseline catalyst gas storage level includes a baseline catalyst NOx storage level and a baseline catalyst NH3 storage level, and

wherein the at least one computing device is further programmed to perform actions including:

estimating a catalyst ammonia (NH3) storage level by analyzing the pre-catalytic converter NOx level, the post-catalytic converter NOx level and the post-catalytic converter NH3 level, and

wherein the determining that the catalyst is deteriorated is performed in response to both the estimated catalyst NOx storage level exceeding the baseline catalyst NOx storage level by a threshold difference and a baseline catalyst NH3 storage level exceeding the estimated catalyst NH3 storage level by a second threshold difference.

12. A catalyst deterioration detection system including a three-way catalytic converter system for use with a three-way catalytic converter, the catalyst deterioration detection system comprising:

a pre-catalytic converter gas sensor;

a post-catalytic converter gas sensor;

at least one computing device in communication with the pre-catalytic converter and post-catalytic converter gas sensors, the at least one computing device programmed to monitor catalyst deterioration by performing actions including:

estimating a catalyst gas storage level by comparing a difference between a pre-catalytic converter gas level from the pre-catalytic converter gas sensor and a post-catalytic converter gas level from the post-catalytic converter gas sensor, wherein the pre-catalytic converter gas level includes a pre-catalytic converter oxygen level, wherein the post-catalytic converter gas level includes a post-catalytic converter oxygen level, wherein the estimated catalyst gas storage level includes an estimated catalyst oxygen storage level;

comparing the estimated catalyst gas storage level to a baseline catalyst gas storage level, wherein the baseline catalyst gas storage level includes a baseline catalyst oxygen storage level;

determining that the catalyst is deteriorated in response to the baseline catalyst gas storage level exceeding the estimated gas s rage level by a threshold difference; and

estimating a carbon monoxide (CO) emissions level based on the estimated catalyst oxygen storage level; and

wherein the determining that the catalyst is deteriorated is performed in response to both the reference catalyst oxygen storage level exceeding the baseline catalyst oxygen storage level by a threshold difference and the estimated CO emissions level exceeding a reference CO emissions level by a second threshold difference.

13. A catalyst deterioration detection system comprising:

a pre-catalytic converter gas sensor;

a post-catalytic converter gas sensor;

at least one computing device in communication with the pre-catalytic converter and post-catalytic converter gas sensors, the at least one computing device programmed to monitor catalyst deterioration by performing actions including:

estimating a catalyst gas storage level by comparing a difference between a pre-catalytic converter gas level from the pre-catalytic converter gas sensor and a post-catalytic converter gas level from the post-catalytic converter gas sensor;

comparing the estimated catalyst gas storage level to a baseline catalyst gas storage level;

determining that the catalyst is deteriorated in response to the baseline catalyst gas storage level exceeding the estimated gas storage level by a threshold difference; and

providing an instruction to a control unit to adapt an air flow ratio of an engine in response to a deviation in the catalyst deterioration level.