IP Library Granted Patent US 8,933,617
Granted Patent B2
US 8,933,617 · App. 14/085,293 · Granted Jan 13, 2015

Spark plug with ceramic electrode tip

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Quick Facts
Patent No.
US 8,933,617
App. No.
14/085,293
Granted
Jan 13, 2015
Kind
B2
Abstract

A spark plug ( 20 ) for igniting a mixture of fuel and air of an internal combustion engine comprises a center electrode ( 22 ) and a ground electrode ( 24 ). At least one of the electrodes ( 22, 24 ) includes a body portion ( 28, 30 ) formed of thermally conductive material and a firing tip ( 32, 34 ) disposed on the body portion ( 28, 30 ). The firing tip ( 32, 34 ) includes a ceramic material, providing an exposed firing surface ( 36, 38 ). The ceramic material is an electrically conductive, monolithic ceramic material. Examples of preferred ceramic materials include titanium diboride, silicon carbide, ternary carbide, and ternary nitride. The ceramic material can also include oxides, borides, nitrides, carbides, silicides, or MAX phases.

Claims (103)

1. A spark plug for igniting a mixture of fuel and air of an internal combustion engine, comprising:

an electrode having a body portion including a thermally conductive material;

said electrode including a firing tip in direct contact with said body portion;

said firing tip having a composition different from the composition of said body portion and including a ceramic material, and said ceramic material including a silicide.

2. The spark plug of claim 1 , wherein said ceramic material is monolithic.

3. The spark plug of claim 1 , wherein said ceramic material is electrically conductive.

4. The spark plug of claim 1 , wherein said ceramic material of said firing tip provides a firing surface for emitting a spark to ignite the mixture of fuel and air.

5. A spark plug for igniting a mixture of fuel and air of an internal combustion engine, comprising:

an electrode having a body portion including a thermally conductive material and being free of a ceramic material, said body portion presenting a width extending perpendicular to a center axis;

said electrode including a firing tip in direct contact with said body portion, said firing tip presenting a width extending perpendicular to said center axis, said width of said firing tip being less than said width of said body portion at a location spaced axially outwardly from said width of said body portion; and

said firing tip including a ceramic material, and said ceramic material including at least one of a nitride and a carbide.

6. The spark plug of claim 5 , wherein said ceramic material includes a nitride having a chemical composition of the formula M x N y where M is a metallic element, N is nitride and x and y are 1.

7. The spark plug of claim 5 , wherein said ceramic material includes a carbide having a chemical composition of the formula M x C y , where M is a metallic element, C is carbon, and x and y are 1.

8. A spark plug for igniting a mixture of fuel and air of an internal combustion engine, comprising:

an electrode having a body portion including a thermally conductive material;

said electrode including a firing tip disposed on said body portion;

said firing tip having a composition different from the composition of said body portion and including a ceramic material, wherein said ceramic material includes a silicide having a chemical composition of the formula M x Si y , where M is a metallic element, Si is silicon and x is 1 and y is 2.

9. A spark plug for igniting a mixture of fuel and air of an internal combustion engine, comprising:

an electrode having a body portion including a thermally conductive material;

said electrode having a firing tip disposed on said body portion;

said firing tip including a ceramic material, wherein said ceramic material includes a conductive ceramic of the form M n+ AX n , where M is a transition metal; n is 1, 2, or 3; A is an element selected from a group IIIA element, a group IVA element, Al, Ga, In, Tl, Si, Ge, Sn, Pb, P, As and S; and X is nitrogen, or carbon, or both carbon and nitrogen.

10. The spark plug of claim 9 , where M is a transition metal selected from the group consisting of Ti, Nb, Ta, V, Cr, Mo, Sc, Zr and Hf; and A is selected from a group consisting of Al, Ga, In, Tl, Si, Ge, Sn, Pb, P, As and S.

11. The spark plug of claim 1 , wherein said firing tip comprises a composite including said ceramic material.

12. A spark plug for igniting a mixture of fuel and air of an internal combustion engine, comprising:

an electrode having a body portion including a thermally conductive material;

said electrode including a firing tip disposed on said body portion;

said firing tip having a composition different from the composition of said body portion and including a ceramic material,

said firing tip comprising a composite including said ceramic material, and wherein said ceramic material of said composite includes two different ceramic materials.

13. The spark plug of claim 11 , wherein said composite includes a metal material.

14. The spark plug of claim 1 , wherein said thermally conductive material of said body portion has a thermal conductivity of at least 20 W/m-K.

15. An electrode for an ignition device, comprising:

a body portion including a thermally conductive material;

a firing tip in direct contact with said body portion;

said firing tip having a composition different from the composition of said body portion and including a ceramic material, and said ceramic material including a silicide.

16. A spark plug for igniting a mixture of fuel and air of an internal combustion engine, comprising:

a center electrode comprising a center body portion extending longitudinally from a center electrode top end to a center firing end;

said center body portion including a thermally and electrically conductive material;

said center body portion having a thermal conductivity of at least 20 W/m-K;

said center body portion having an electrical conductivity of at least 9×10 5 S/m;

said center body portion formed of nickel or a nickel alloy;

said center body portion having a first diameter extending perpendicular to said longitudinal center body portion;

said center electrode including a center firing tip extending transversely from said center firing end;

said center firing tip formed of a ceramic material;

said firing tip comprising a composite including said ceramic material, and said ceramic material of said composite including two different ceramic materials;

said ceramic material including at least one of a boride, nitride, carbide, and silicide;

said ceramic material of said center firing tip being electrically conductive and having a thermal conductivity less than the thermal conductivity of said center body portion;

said ceramic material of said center firing tip having an electrical conductivity of at least 10 6 S/m;

said center firing tip having a second diameter being less than said first diameter of said center body portion;

said center firing tip having a rectangular cross-section;

said ceramic material of said center firing tip presenting a center firing surface being planar and facing outwardly for emitting a spark to ignite the mixture of fuel and air;

said center firing tip being brazed to said center body portion;

an insulator disposed annularly around said center electrode;

said insulator extending longitudinally from an insulator upper end along said center body portion toward said center firing end and to an insulator firing end such that said center firing end projects outwardly of said insulator firing end;

said insulator including an electrically insulating material;

said electrically insulating material including alumina;

said insulator having a permittivity capable of holding an electrical charge;

said insulator having an electrical conductivity less than the electrical conductivity of said center electrode;

said insulator having a thermal conductivity less than the thermal conductivity of said center electrode;

a terminal received in said insulator and extending from a first terminal end to a second terminal end electrically connected to said center electrode top end;

said terminal formed of an electrically conductive material;

a resistor layer disposed between and electrically connecting said second terminal end and said center electrode top end for transmitting energy from said terminal to said center electrode;

said resistor layer formed of an electrically conductive material;

said resistor layer comprising a glass seal;

a shell disposed annularly around and longitudinal along said insulator from an upper shell end to a lower shell end such that said insulator firing end and said center firing end project outwardly of said lower shell end;

said shell being formed of a metal material;

said metal material of said shell being steel;

a ground electrode comprising a ground body portion including a ground top end attached to said lower shell end and extending transversely from said lower shell end and curving toward said center electrode and presenting a ground firing end facing said center electrode;

said ground body portion including said thermally and electrically conductive material of said center body portion;

said ground electrode including a ground firing tip extending transversely from said ground firing end toward said center firing tip;

said ground firing tip including said ceramic material;

said ceramic material of said ground firing tip being the same as said ceramic material of said center firing tip;

said ceramic material of said ground firing tip presenting a ground firing surface facing said center firing surface;

said ground firing surface being spaced and parallel to said center firing surface to provide a spark gap therebetween;

said ground firing tip having a rectangular cross-section;

said ground firing tip being brazed to said ground body portion;

at least one packing element disposed between said insulator and said shell for providing a gas-tight seal between said shell and said insulator; and

said packing element being disposed between said insulator and said terminal.

17. A method of forming a spark plug for igniting a mixture of fuel and air of an internal combustion engine, comprising: providing an electrode by disposing a firing tip including a ceramic material directly on a body portion including a thermally conductive material, the firing tip having a composition different from the composition of the body portion and the ceramic material of the firing tip including a silicide.

18. A method of forming a spark plug for igniting a mixture of fuel and air of an internal combustion engine, comprising:

providing an electrode by disposing a firing tip including a ceramic material on a body portion including a thermally conductive material, the firing tip having a composition different from the composition of the body portion and the ceramic material of the firing tip including at least one of a nitride, carbide, and silicide; and

including laser welding the firing tip to the body portion of the electrode.

19. A method of forming a spark plug for igniting a mixture of fuel and air of an internal combustion engine, comprising:

providing an electrode by disposing a firing tip including a ceramic material on a body portion including a thermally conductive material, the firing tip having a composition different from the composition of the body portion and the ceramic material of the firing tip including at least one of a nitride, carbide, and silicide; and

including forming a hole facing outwardly in the body portion and disposing the firing tip in the hole.

20. The spark plug of claim 1 , wherein said body portion of said electrode includes nickel or a nickel alloy.

21. The spark plug of claim 15 , wherein said body portion of said electrode has a thermal conductivity greater than the thermal conductivity of said firing tip of said electrode.

22. The electrode of claim 15 , wherein said body portion of said electrode includes nickel or a nickel alloy.

23. An electrode for an ignition device, comprising:

a body portion including nickel or a nickel alloy;

a firing tip disposed on said body portion;

said firing tip including a ceramic material, and said ceramic material including a boride.

24. The electrode of claim 23 , wherein said boride includes at least one of Zirconium Boride; Hafnium Boride; Vanadium Boride; Tungsten Boride; Chromium Boride; Molybdenum Boride; Niobium Boride; Tantalum Boride; Lanthanum Hexaboride; Barium Hexaboride; Calcium Hexaboride; and Cerium Hexaboride.

25. An electrode for an ignition device, comprising:

a body portion including a thermally conductive material;

a firing tip disposed on said body portion;

said firing tip including a ceramic material, wherein said ceramic material includes a conductive ceramic of the form M n+ AX n , where M is a transition metal; n is 1, 2, or 3; A is an element selected from a group IIIA element, a group IVA element, Al, Ga, In, Tl, Si, Ge, Sn, Pb, P, As and S; and X is nitrogen, or carbon, or both carbon and nitrogen.

26. The spark plug of claim 5 , wherein said ceramic material includes at least one of one of silicon carbide, a ternary carbide, and a ternary nitride.

27. An electrode for an ignition device, comprising:

a body portion including a thermally conductive material and being free of a ceramic material, said body portion presenting a width extending perpendicular to a center axis;

a firing tip in direct contact with said body portion, said firing tip presenting a width extending perpendicular to said center axis, said width of said firing tip being less than said width of said body portion at a location spaced axially outwardly from said width of said body portion; and

said firing tip including a ceramic material, and said ceramic material including at least one of a nitride and a carbide.

28. A method of forming a spark plug for igniting a mixture of fuel and air of an internal combustion engine, comprising:

providing an electrode by disposing a firing tip including a ceramic material in direct contact with a body portion including a thermally conductive material and being free of a ceramic material, the body portion presenting a width extending perpendicular to a center axis, the firing tip presenting a width extending perpendicular to the center axis, the width of the firing tip being less than the width of the body portion at a location spaced axially outwardly from the width of the body portion, the firing tip including a ceramic material, and the ceramic material including at least one of a nitride and a carbide.

Assignments (19)
PATENT SECURITY AGREEMENT (ABL) Recorded Apr 7, 2023
From: TENNECO INC.; DRIV AUTOMOTIVE INC.; FEDERAL-MOGUL CHASSIS LLC; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL WORLD WIDE LLC; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; THE PULLMAN COMPANY
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 063268/0506 →
NOTICE OF GRANT OF SECURITY INTEREST IN PATENTS (FIRST LIEN) Recorded Nov 22, 2022
From: DRIV AUTOMOTIVE INC.; FEDERAL-MOGUL CHASSIS LLC; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL WORLD WIDE LLC; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; TENNECO INC.; THE PULLMAN COMPANY
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 061989/0689 →
RELEASE OF SECURITY INTEREST Recorded Nov 19, 2022
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: TENNECO INC.; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; THE PULLMAN COMPANY; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL PRODUCTS US LLC; FEDERAL-MOGUL WORLD WIDE LLC; FEDERAL-MOGUL CHASSIS LLC; DRIV AUTOMOTIVE INC.
Reel/Frame 061975/0031 →
RELEASE OF SECURITY INTEREST Recorded Nov 19, 2022
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: TENNECO INC.; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; TENNECO INTERNATIONAL HOLDING CORP.; THE PULLMAN COMPANY; TENNECO GLOBAL HOLDINGS INC.; CLEVITE INDUSTRIES INC.; TMC TEXAS INC.; CARTER AUTOMOTIVE COMPANY LLC; FEDERAL-MOGUL WORLD WIDE LLC; FELT PRODUCTS MFG. CO. LLC; MUZZY-LYON AUTO PARTS LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL POWERTRAIN IP LLC; FEDERAL-MOGUL PISTON RINGS, LLC; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL CHASSIS LLC; F-M MOTORPARTS TSC LLC; F-M TSC REAL ESTATE HOLDINGS LLC; FEDERAL-MOGUL VALVE TRAIN INTERNATIONAL LLC; FEDERAL-MOGUL SEVIERVILLE, LLC; BECK ARNLEY HOLDINGS LLC; FEDERAL-MOGUL FILTRATION LLC; FEDERAL-MOGUL FINANCING CORPORATION; FEDERAL-MOGUL PRODUCTS US LLC
Reel/Frame 061975/0218 →
RELEASE OF SECURITY INTEREST Recorded Nov 19, 2022
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: TENNECO INC.; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; THE PULLMAN COMPANY; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL PRODUCTS US LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL WORLD WIDE LLC; FEDERAL-MOGUL CHASSIS LLC; DRIV AUTOMOTIVE INC.
Reel/Frame 061971/0156 →
RELEASE OF SECURITY INTEREST Recorded Mar 18, 2021
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: FEDERAL-MOGUL PRODUCTS US, LLC, AS SUCCESSOR TO FEDERAL-MOGUL PRODUCTS, INC.; FEDERAL-MOGUL WORLD WIDE, INC., AS SUCCESSOR TO FEDERAL-MOGUL WORLD WIDE LLC; FEDERAL-MOGUL MOTORPARTS LLC, AS SUCCESSOR TO FEDERAL-MOGUL MOTORPARTS CORPORATION; FEDERAL-MOGUL IGNITION, LLC, AS SUCCESSOR TO FEDERAL-MOGUL IGNITION COMPANY; TENNECO INC., AS SUCCESSOR TO FEDERAL-MOGUL LLC; FEDERAL-MOGUL CHASSIS LLC; FEDERAL-MOGUL POWERTRAIN LLC; DRIV AUTOMOTIVE INC.
Reel/Frame 056886/0455 →
RELEASE OF SECURITY INTEREST Recorded Mar 18, 2021
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: FEDERAL-MOGUL PRODUCTS US, LLC, AS SUCCESSOR TO FEDERAL-MOGUL PRODUCTS, INC.; FEDERAL-MOGUL WORLD WIDE, INC., AS SUCCESSOR TO FEDERAL-MOGUL WORLD WIDE LLC; FEDERAL-MOGUL MOTORPARTS LLC, AS SUCCESSOR TO FEDERAL-MOGUL MOTORPARTS CORPORATION; FEDERAL-MOGUL IGNITION, LLC, AS SUCCESSOR TO FEDERAL-MOGUL IGNITION COMPANY; TENNECO INC., AS SUCCESSOR TO FEDERAL-MOGUL LLC; FEDERAL-MOGUL CHASSIS LLC; FEDERAL-MOGUL POWERTRAIN LLC; DRIV AUTOMOTIVE INC.
Reel/Frame 058392/0274 →
SECURITY AGREEMENT Recorded Mar 17, 2021
From: TENNECO INC.; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; THE PULLMAN COMPANY; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL PRODUCTS US LLC; FEDERAL-MOGUL WORLD WIDE LLC; FEDERAL-MOGUL CHASSIS LLC; DRIV AUTOMOTIVE INC.
To: WILMINGTON TRUST, NATIONAL ASSOCIATION
Reel/Frame 055626/0065 →
SECURITY AGREEMENT Recorded Dec 1, 2020
From: TENNECO INC.; THE PULLMAN COMPANY; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL PRODUCTS US LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL WORLD WIDE LLC; FEDERAL-MOGUL CHASSIS LLC; DRIV AUTOMOTIVE INC.; TENNECO AUTOMOTIVE OPERATING COMPANY INC.
To: WILMINGTON TRUST, NATIONAL ASSOCIATION
Reel/Frame 054555/0592 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 22, 2019
From: FEDERAL-MOGUL IGNITION COMPANY
To: FEDERAL-MOGUL IGNITION LLC
Reel/Frame 049821/0536 →
COLLATERAL TRUSTEE RESIGNATION AND APPOINTMENT, JOINDER, ASSUMPTION AND DESIGNATION AGREEMENT Recorded Oct 26, 2018
From: BANK OF AMERICA, N.A., AS CO-COLLATERAL TRUSTEE AND RESIGNING COLLATERAL TRUSTEE
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS CO-COLLATERAL TRUSTEE, SUCCESSOR COLLATERAL TRUSTEE
Reel/Frame 047630/0661 →
RELEASE OF SECURITY INTEREST Recorded Oct 22, 2018
From: BANK OF AMERICA, N.A., AS COLLATERAL TRUSTEE
To: FEDERAL-MOGUL LLC; FEDERAL-MOGUL WORLD WIDE LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL IGNITION COMPANY; FEDERAL-MOGUL CHASSIS LLC; FEDERAL MOGUL POWERTRAIN LLC; FEDERAL-MOGUL PRODUCTS, INC.
Reel/Frame 047276/0554 →
RELEASE OF SECURITY INTEREST Recorded Oct 22, 2018
From: BANK OF AMERICA, N.A., AS COLLATERAL TRUSTEE
To: FEDERAL-MOGUL LLC; FEDERAL-MOGUL WORLD WIDE LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL IGNITION COMPANY; FEDERAL-MOGUL CHASSIS LLC; FEDERAL MOGUL POWERTRAIN LLC; FEDERAL-MOGUL PRODUCTS, INC.
Reel/Frame 047276/0771 →
CONFIRMATORY GRANT OF SECURITY INTERESTS IN UNITED STATES PATENTS Recorded Oct 9, 2018
From: TENNECO INC.; TENNECO AUTOMOTIVE OPERATING COMPANY INC.; TENNECO INTERNATIONAL HOLDING CORP.; THE PULLMAN COMPANY; TENNECO GLOBAL HOLDINGS INC.; CLEVITE INDUSTRIES INC.; TMC TEXAS INC.; CARTER AUTOMOTIVE COMPANY LLC; FEDERAL-MOGUL WORLD WIDE LLC; FELT PRODUCTS MFG. CO. LLC; MUZZY-LYON AUTO PARTS LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL POWERTRAIN IP LLC; FEDERAL-MOGUL PISTON RINGS, LLC; FEDERAL-MOGUL IGNITION LLC; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL CHASSIS LLC; F-M MOTORPARTS TSC LLC; F-M TSC REAL ESTATE HOLDINGS LLC; FEDERAL-MOGUL VALVETRAIN INTERNATIONAL LLC; FEDERAL-MOGUL SEVIERVILLE, LLC; BECK ARNLEY HOLDINGS LLC; FEDERAL-MOGUL FILTRATION LLC; FEDERAL-MOGUL FINANCING CORPORATION; FEDERAL-MOGUL PRODUCTS US LLC
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS COLLATERAL TRUSTEE
Reel/Frame 047223/0001 →
COLLATERAL TRUSTEE RESIGNATION AND APPOINTMENT AGREEMENT Recorded Apr 3, 2018
From: CITIBANK, N.A., AS COLLATERAL TRUSTEE
To: BANK OF AMERICA, N.A., AS COLLATERAL TRUSTEE
Reel/Frame 045822/0765 →
GRANT OF SECURITY INTEREST IN UNITED STATES PATENTS Recorded Sep 26, 2017
From: FEDERAL-MOGUL LLC; FEDERAL-MOGUL PRODUCTS, INC.; FEDERAL-MOGUL MOTORPARTS LLC; FEDERAL-MOGUL CHASSIS LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL IGNITION COMPANY; FEDERAL-MOGUL WORLD WIDE, LLC
To: CITIBANK, N.A., AS COLLATERAL TRUSTEE
Reel/Frame 044013/0419 →
GRANT OF SECURITY INTEREST IN UNITED STATES PATENTS Recorded Jun 23, 2017
From: FEDERAL-MOGUL LLC; FEDERAL-MOGUL PRODUCTS, INC.; FEDERAL-MOGUL MOTORPARTS CORPORATION; FEDERAL-MOGUL CHASSIS LLC; FEDERAL-MOGUL POWERTRAIN LLC; FEDERAL-MOGUL IGNITION COMPANY; FEDERAL-MOGUL WORLD WIDE, INC.
To: CITIBANK, N.A., AS COLLATERAL TRUSTEE
Reel/Frame 042963/0662 →
SECURITY INTEREST Recorded Jun 20, 2014
From: FEDERAL-MOGUL CORPORATION, A DELAWARE CORPORATION; FEDERAL-MOGUL WORLD WIDE, INC., A MICHIGAN CORPORATION; FEDERAL-MOGUL IGNITION COMPANY, A DELAWARE CORPORATION; FEDERAL-MOGUL POWERTRAIN, INC., A MICHIGAN CORPORATION; FEDERAL-MOGUL PRODUCTS, INC. , A MISSORI CORPORATION; FEDERAL-MOGUL CHASSIS LLC, A DELAWARE LIMITED LIABILITY COMPANY
To: CITIBANK, N.A., AS COLLATERAL TRUSTEE
Reel/Frame 033204/0707 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 11, 2013
From: WALKER, WILLIAM J., JR.
To: FEDERAL-MOGUL IGNITION COMPANY
Reel/Frame 031755/0811 →