Polycrystalline diamond compact, and related methods and applications
View Patent ↗Embodiments relate to polycrystalline diamond compacts (“PDCs”) including a polycrystalline diamond (“PCD”) table in which a metal-solvent catalyst is alloyed with at least one alloying element to improve thermal stability of the PCD table. In an embodiment, a PDC includes a substrate and a PCD table bonded to the substrate. The PCD table includes diamond grains defining interstitial regions. The PCD table includes an alloy comprising at least one Group VIII metal and at least one metallic alloying element that lowers a temperature at which melting of the at least one Group VIII metal begins. The alloy includes one or more solid solution phases comprising the at least one Group VIII metal and the at least one metallic alloying element and one or more intermediate compounds comprising the at least one Group VIII metal and the at least one metallic alloying element.
1. A polycrystalline diamond compact, comprising:
a substrate; and
a polycrystalline diamond table including an upper surface spaced from an interfacial surface that is bonded to the substrate, the polycrystalline diamond table including a plurality of diamond grains defining a plurality of interstitial regions, the polycrystalline diamond table further including an alloy comprising at least one Group VIII metal and at least one metallic alloying element that lowers a temperature at which melting of the at least one Group VIII metal begins, the alloy including one or more solid solution phases comprising the at least one Group VIII metal and the at least one metallic alloying element and one or more intermediate compounds comprising the at least one Group VIII metal and the at least one metallic alloying element, the alloy being disposed in at least a portion of the plurality of interstitial regions, the at least one metallic alloying element exhibiting a concentration gradient between the upper surface and the interfacial surface that generally decreases with distance from the upper surface, the plurality of diamond grains and the alloy of at least a portion of the polycrystalline diamond table collectively exhibiting a coercivity of about 115 Oersteds or more;
wherein the at least one metallic alloying element includes at least one element selected from the group consisting of silver, gold, aluminum, antimony, bismuth, boron, cerium, chromium, copper, dysprosium, erbium, gallium, germanium, gadolinium, hafnium, holmium, indium, lanthanum, magnesium, manganese, molybdenum, niobium, neodymium, praseodymium, platinum, ruthenium, sulfur, antimony, scandium, selenium, silicon, samarium, tin, tantalum, terbium, tellurium, thorium, titanium, vanadium, yttrium, zinc, and zirconium.
2. The polycrystalline diamond compact of claim 1 wherein the polycrystalline diamond table is integrally formed with the substrate.
3. The polycrystalline diamond compact of claim 1 wherein the at least one metallic alloying element is distributed substantially uniformly throughout the polycrystalline diamond table.
4. The polycrystalline diamond compact of claim 1 wherein the alloy exhibits a bulk modulus that is less than that of the at least one Group VIII metal alone.
5. The polycrystalline diamond compact of claim 1 wherein the at least one metallic alloying element includes at least one additional element selected from the group consisting of iron, and tungsten.
6. The polycrystalline diamond compact of claim 1 wherein the at least one element is selected from the group consisting of boron and copper.
7. The polycrystalline diamond compact of claim 1 wherein the at least one element is boron.
8. The polycrystalline diamond compact of claim 1 wherein the at least one is copper.
9. The polycrystalline diamond compact of claim 1 wherein the at least one metallic alloying element is present in the alloy in an amount of a eutectic composition, a hypo-eutectic composition, or a hyper-eutectic composition of the at least one Group VIII metal and the at least one alloying element.
10. The polycrystalline diamond compact of claim 1 wherein the at least one element is boron, and wherein the at least one Group VIII metal includes cobalt.
11. The polycrystalline diamond compact of claim 10 wherein the alloy includes Co 21 W 2 B 6 .
12. The polycrystalline diamond compact of claim 1 wherein the at least one element is boron and is substantially free of boron carbide.
13. The polycrystalline diamond compact of claim 1 wherein the one or more intermediate compounds are present in an amount of about 90 weight % to about 97 weight % of the alloy.
14. The polycrystalline diamond compact of claim 1 wherein the coercivity is about 115 Oersteds to about 250 Oersteds.
15. The polycrystalline diamond compact of claim 1 wherein the at least a portion of the polycrystalline diamond table exhibiting a specific magnetic saturation of about 15 Gauss cm 3 /grams or less.
16. The polycrystalline diamond compact of claim 1 wherein the plurality of diamond grains exhibit an average grain size of 30 μm or less, and wherein the alloy is present in an amount of 1 weight % to about 7.5 weight %.
17. The polycrystalline diamond compact of claim 1 wherein the plurality of diamond grains exhibit an average grain size of 20 μm or less, and wherein the alloy is present in an amount of 1 weight % to about 7.5 weight %.
18. The polycrystalline diamond compact of claim 1 wherein the substrate provides the at least one Group VIII metal to the PCD table as indicated by a depletion zone of the at least one Group VIII metal in the substrate adjacent to the PCD table.
19. A polycrystalline diamond compact, comprising:
a substrate; and
a polycrystalline diamond table including an upper surface spaced from an interfacial surface that is bonded to the substrate, the polycrystalline diamond table including a plurality of diamond grains defining a plurality of interstitial regions, the polycrystalline diamond table further including an alloy comprising at least one Group VIII metal and at least one Group V element, the alloy being disposed in at least a portion of the plurality of interstitial regions, the at least one Group V element exhibiting a concentration gradient between the upper surface and the interfacial surface that generally decreases with distance from the upper surface, the plurality of diamond grains and the alloy of at least a portion of the polycrystalline diamond table collectively exhibiting a coercivity of about 115 Oersteds or more.
20. The polycrystalline diamond compact of claim 19 wherein the polycrystalline diamond table is integrally formed with the substrate.
21. The polycrystalline diamond compact of claim 19 wherein the at least one Group V element is distributed substantially uniformly throughout the polycrystalline diamond table.
22. The polycrystalline diamond compact of claim 19 wherein the alloy exhibits a bulk modulus that is less than that of the at least one Group VIII metal alone.
23. The polycrystalline diamond compact of claim 19 wherein the at least one Group V element includes at least one element selected from the group consisting of antimony and bismuth.
24. The polycrystalline diamond compact of claim 23 wherein the at least one Group V element is antimony.
25. The polycrystalline diamond compact of claim 23 wherein the at least one Group V element is bismuth.
26. The polycrystalline diamond compact of claim 19 wherein the alloy includes one or more intermetallic compounds of the at least one Group VIII metal and the at least one Group V element.
27. The polycrystalline diamond compact of claim 26 wherein the one or more intermetallic compounds are present in an amount of about 90 weight % to about 97 weight % of the alloy.
28. The polycrystalline diamond compact of claim 19 wherein the coercivity is about 115 Oersteds to about 250 Oersteds.
29. The polycrystalline diamond compact of claim 19 wherein the at least a portion of the polycrystalline diamond table exhibiting a specific magnetic saturation of about 15 Gauss·cm 3 /grams or less.
30. The polycrystalline diamond compact of claim 19 wherein the plurality of diamond grains exhibit an average grain size of 30 μm or less, and wherein the alloy is present in an amount of 1 weight % to about 7.5 weight %.
31. The polycrystalline diamond compact of claim 19 wherein the plurality of diamond grains exhibit an average grain size of 20 μm or less, and wherein the alloy is present in an amount of 1 weight % to about 7.5 weight %.
32. The polycrystalline diamond compact of claim 19 wherein the at least one Group VIII metal includes at least one of iron, nickel, or cobalt.
33. A polycrystalline diamond compact, comprising:
a substrate; and
a polycrystalline diamond table including an upper surface spaced from an interfacial surface that is bonded to the substrate, the polycrystalline diamond table including a plurality of diamond grains defining a plurality of interstitial regions, the polycrystalline diamond table further including an alloy disposed in at least a portion of the plurality of interstitial regions, the alloy including:
one or more solid solution phases comprising cobalt and boron; and
one or more intermediate compounds comprising cobalt and boron;
wherein the boron exhibits a concentration gradient between the upper surface and the interfacial surface of the polycrystalline diamond table, wherein the concentration gradient of the boron decreases with distance from the upper surface;
wherein the plurality of diamond grains and the alloy of at least a portion of the polycrystalline diamond table collectively exhibit a coercivity of about 115 Oersteds or more.
34. The polycrystalline diamond compact of claim 33 wherein the alloy includes Co 21 W 2 B 6 .
35. The polycrystalline diamond compact of claim 33 wherein the alloy is substantially free of boron carbide.
36. The polycrystalline diamond compact of claim 33 wherein the one or more intermetallic compounds are present in an amount of about 90 weight % to about 97 weight % of the alloy.
37. A polycrystalline diamond compact, comprising:
a substrate; and
a polycrystalline diamond table including an upper surface spaced from an interfacial surface that is bonded to the substrate, the polycrystalline diamond table including a plurality of diamond grains defining a plurality of interstitial regions, the polycrystalline diamond table further including an alloy comprising at least one Group VIII metal and at least one metallic alloying element that lowers a temperature at which melting of the at least one Group VIII metal begins, the alloy including one or more solid solution phases comprising the at least one Group VIII metal and the at least one metallic alloying element and one or more intermediate compounds comprising the at least one Group VIII metal and the at least one metallic alloying element, the alloy being disposed in at least a portion of the plurality of interstitial regions, the plurality of diamond grains and the alloy of at least a portion of the polycrystalline diamond table collectively exhibiting a coercivity of about 115 Oersteds or more;
wherein the one or more intermediate compounds forms about 90 weight % to about 97 weight % of at least a portion of the alloy.