Herbicidal fluridone compositions
View Patent ↗Described are preferred methods and compositions useful for controlling aquatic weeds that involve the use of fluridone. Preferred herbicidal compositions include fluridone in a formulation that also comprises an organic solvent and an emulsifying surfactant system.
1. A herbicidal composition, comprising:
fluridone, in an amount of about 5% to about 11% by weight of the composition;
one or more water-immiscible organic solvents, the one or more water-immiscible organic solvents constituting about 35% to about 55% by weight of the composition, and wherein said one or more water-immiscible organic solvents comprise N,N-dimethyloctamide and/or N,N-dimethyldecamide;
one or more water-miscible organic solvents, the one or more water-miscible organic solvents constituting about 20% to about 45% by weight of the composition, and where said one or more water-miscible organic solvents comprise propylene glycol;
an emulsifying surfactant system including at least one nonionic surfactant and at least one anionic surfactant, wherein said at least one nonionic surfactant comprises a butyl ethoxylate/propoxylate block copolymer and wherein said at least one anionic surfactant comprises dodecylbenzenesulfonic acid or a salt thereof.
2. The composition of claim 1 , wherein:
the fluridone is present in an amount of about 5% to about 9% by weight of the composition;
the one or more water-immiscible organic solvents constitute about 45% to about 55% by weight of the composition; and
the one or more water-miscible organic solvents constitute about 30% to about 40% by weight of the composition.
3. The composition of claim 1 , wherein the composition is substantially free from water.
4. The composition of claim 1 , wherein the composition is a substantially homogenous solution.
5. A herbicidal composition, comprising:
fluridone, in an amount of about 3% to about 15% by weight of the composition;
one or more water-immiscible organic solvents, wherein the one or more water-immiscible organic solvents include N,N-dimethyloctanamide and/or N,N-dimethyldecanamide, and wherein the one or more water-immisicible organic solvents constitute about 20% to about 60% of the composition by weight;
one or more water-miscible organic solvents, wherein the one or more water-miscible organic solvents constitute about 20% to about 60% of the composition by weight; and
an emulsifying surfactant system, wherein the emulsifying surfactant system includes at least one anionic surfactant and at least one nonionic surfactant; and
wherein said herbicidal composition remains clear without any phase separation for a period of greater than one day when maintained in a sealed-fluid tight inert container at 25° C.
6. The composition of claim 5 , wherein the fluridone constitutes about 3% to about 9% by weight of the composition.
7. The composition of claim 5 , which is substantially free from water.
8. The composition of claim 5 , wherein the composition is a substantially homogeneous solution.
9. A method for herbicidally treating a plant submersed in water or its supporting environment with fluridone, comprising applying to the submersed plant or its supporting environment (i) the composition of claim 1 , or (ii) a composition prepared by combining the composition of claim 1 with another substance, wherein said environment is a body of water.
10. A herbicidal composition, comprising:
fluridone, in an amount of about 5% to about 11% by weight of the composition;
N,N-dimethyloctanamide, N,N-dimethyldecanamide, or a mixture thereof, in an amount constituting at least 50% by weight of all water-immiscible solvents in the composition;
propylene glycol, in an amount constituting at least about 50% by weight of all water-miscible organic solvents in the composition;
an emulsifying surfactant system including at least one anionic surfactant and at least one nonionic surfactant; and
an antifoaming agent; and
wherein said herbicidal composition remains clear without any phase separation for a period of greater than one day when maintained in a sealed-fluid tight inert container at 25° C.
11. The herbicidal composition of claim 10 , wherein the at least one nonionic surfactant comprises a butyl ethoxylate/propoxylate block copolymer and wherein said at least one anionic surfactant comprises dodecylbenzenesulfonic acid or a salt thereof.
12. The herbicidal composition of claim 10 , wherein N,N-dimethyloctanamide, N,N-dimethyldecanamide, or a mixture of N,N-dimethyloctanamide and N,N-dimethyldecanamide, constitutes at least 75% by weight of all water-immiscible solvents in the composition.
13. The herbicidal composition of claim 12 , wherein N,N-dimethyloctanamide, N,N-dimethyldecanamide, or a mixture thereof, constitutes at least 90% by weight of all water-immiscible solvents in the composition.
14. The herbicidal composition of claim 10 , wherein propylene glycol constitutes at least 75% by weight of all water-miscible solvents in the composition.
15. The herbicidal composition of claim 14 , wherein propylene glycol constitutes at least 90% by weight of all water-miscible solvents in the composition.
16. The herbicidal composition of claim 15 , wherein the at least one nonionic surfactant comprises a butyl ethoxylate/propoxylate block copolymer and wherein said at least one anionic surfactant comprises dodecylbenzenesulfonic acid or a salt thereof.