IP Library Granted Patent US 9,359,544
Granted Patent B2
US 9,359,544 · App. 14/102,532 · Granted Jun 7, 2016

Composition and method for treating subterranean formation

Inventors: Arthur William Milne (Mexico City, MX); Emilio Miquilena (Ciudad del Carmen, MX); Syed A. Ali (Sugar Land, TX)
Assignee: Schlumberger Technology Corporation
C09K8/602C09K8/74E21B43/283
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Quick Facts
Patent No.
US 9,359,544
App. No.
14/102,532
Granted
Jun 7, 2016
Kind
B2
Abstract

A composition and method for performing a treatment of a subterranean formation. The composition includes an emulsified acid and a sulfobetaine surfactant. The emulsified acid and the sulfobetaine surfactant may be mixed to form a treatment composition, which may be injected into a subterranean formation as part of an acid fracturing or hydraulic fracturing treatment.

Claims (22)

1. A composition for treatment of a subterranean formation, the composition comprising an emulsified acid system and a sulfobetaine surfactant comprising a cationic surfactant comprising an ammonium chloride derivative and a linear alkylbenzenesulfonate.

2. The composition according to claim 1 , wherein an emulsifier present in the emulsified acid system is present at about 0.1 to about 1.0 vol. % of the emulsified acid.

3. The composition according to claim 1 , wherein the emulsified acid includes an inhibitor aid.

4. The composition according to claim 3 , wherein the inhibitor aid is a formic acid.

5. The composition according to claim 3 , wherein the inhibitor aid is present from about 0.1 to about 1.0 vol. % of the emulsified acid.

6. The composition according to claim 1 , wherein the emulsified acid includes hydrochloric acid.

7. The composition according to claim 6 , wherein the hydrochloric acid is present from about 5 wt. % to about 32 wt. % of the emulsified acid.

8. The composition according to claim 7 , wherein the hydrochloric acid is present from about 10 wt. % to about 28 wt. % of the emulsified acid.

9. The composition according to claim 1 , further comprising diesel.

10. The composition according to claim 9 , further comprising an amount of diesel sufficient to make between a 90:10 (acid:diesel) and a 60:40 (acid:diesel) emulsion.

11. The composition according to claim 9 , further comprising an amount of diesel sufficient to make a 70:30 (acid:diesel) emulsion.

12. The composition according to claim 9 , further comprising an amount of diesel sufficient to make an 80:20 (acid:diesel) emulsion.

13. The composition according to claim 1 , further comprising ethyleneglycolmonobutylether-2-butoxyethanol.

14. A method for treating a subterranean formation, comprising:

adding a sulfobetaine surfactant to an emulsified acid, thereby forming a treatment composition, and

injecting the treatment composition to the subterranean formation; wherein the sulfobetaine surfactant comprises a cationic surfactant comprising an ammonium chloride derivative and a linear alkylbenzenesulfonate.

15. The method according to claim 14 , wherein the emulsified acid includes hydrochloric acid.

16. The method according to claim 14 , wherein the emulsified acid includes an emulsifier.

17. A method for performing an acidizing treatment in a subterranean formation, comprising:

adding a sulfobetaine surfactant to an emulsified acid, thereby forming a treatment composition, and

injecting the treatment composition to the subterranean formation to thereby induce a fracture at a portion of the subterranean formation; wherein the sulfobetaine surfactant comprises a cationic surfactant comprising an ammonium chloride derivative and a linear alkylbenzenesulfonate.

18. The method according to claim 17 , wherein the emulsified acid includes hydrochloric acid.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 27, 2014
From: MILNE, ARTHUR WILLIAM; MIQUILENA, EMILIO; ALI, SYED A.
To: SCHLUMBERGER TECHNOLOGY CORPORATION
Reel/Frame 032315/0471 →
Continuity (1)
Related Publication 20150159081A1 · Jun 11, 2015