Drilling fluid additive
View Patent ↗The present invention provides a drilling fluid additive comprising a specific cation-modified PVA-based resin and a drilling fluid containing the same. The drilling fluid additive can reduce hydration swelling of inorganic clay mineral such as bentonite, and provide a drilling fluid such as drilling mud capable of forming a thin and tough mud wall on the stratum during drilling operation.
1. A drilling fluid additive comprising polyvinyl alcohol-based resin containing a cationic structural unit represented by formula (1), a vinyl alcohol structural unit represented by formula (3a), and a vinyl ester structural unit represented by formula (3b), and excluding a carboxylic acid functional monomer unit,
wherein R 1 and R 2 are independently a hydrogen atom or an alkyl group having from 1 to 3 carbon atoms, and may be identical or different from each other, and R 3 and R 4 are independently an alkylene group having from 1 to 3 carbon atoms, and may be identical or different from each other, Y is a halogen, and R 5 is an alkyl group having from 1 to 18 carbons or an aromatic group,
wherein the content of the cationic structural unit is from 0.3 to 2 mol %, and wherein the polyvinyl alcohol-based resin has a saponification degree of 70 to less than 100 mol %.
2. The drilling fluid additive according to claim 1 , wherein the polyvinyl alcohol-based resin has a polymerization degree of 200 to 3000.
3. The drilling fluid additive according to claim 1 , further comprising a salt.
4. The drilling fluid additive according to claim 1 , wherein the content of the polyvinyl alcohol-based resin is in the range of 0.01 to 10% by weight based on the weight of drilling fluid.
5. The drilling fluid additive according to claim 1 , wherein each of R 3 and R 4 is a methylene group.
6. A drilling fluid comprising inorganic clay mineral, a medium, and polyvinyl alcohol-based resin containing a cationic structural unit represented by formula (1), a vinyl alcohol structural unit represented by formula (3a), and a vinyl ester structural unit represented by formula (3b), and excluding a carboxylic acid functional monomer unit,
wherein R 1 and R 2 are independently a hydrogen atom or an alkyl group having from 1 to 3 carbon atoms, and may be identical or different from each other, and R 3 and R 4 are independently an alkylene group having from 1 to 3 carbon atoms, and may be identical or different from each other, Y is a halogen, and R 5 is an alkyl group having from 1 to 18 carbons or an aromatic group,
wherein the content of the cationic structural unit is from 0.3 to 2.0 mol %, and wherein the polyvinyl alcohol-based resin has a saponification degree of 70 to less than 100 mol %.
7. The drilling fluid according to claim 6 , wherein the inorganic clay mineral is bentonite.
8. The drilling fluid according to claim 6 , wherein the medium is water.